English
Related papers

Related papers: Decoding Pure Rotational Molecular Spectra for Asy…

200 papers

Parameterizing radiative transfer in means navigating trade-offs between physical accuracy and conceptual clarity. However, currently available schemes sit at the extremes of this spectrum: correlated-k schemes are fast and accurate but…

Atmospheric and Oceanic Physics · Physics 2025-08-14 Andrew I. L. Williams

We solve the inverse spectral problem for rotationally symmetric manifolds, which include the class of surfaces of revolution, by giving an analytic isomorphism from the space of spectral data onto the space of functions describing the…

Mathematical Physics · Physics 2016-05-18 Hiroshi Isozaki , Evgeny L. Korotyaev

In this study, we explore the potential of machine learning for modeling molecular electronic spectral intensities as a continuous function in a given wavelength range. Since presently available chemical space datasets provide excitation…

Chemical Physics · Physics 2022-08-02 Prakriti Kayastha , Sabyasachi Chakraborty , Raghunathan Ramakrishnan

An attempt is made to bypass spectral analysis and fit internal coordinates of radicals directly to experimental liquid- and solid-state electron spin resonance (ESR) spectra. We take advantage of the recently introduced large-scale spin…

Chemical Physics · Physics 2014-07-16 G. T. P. Charnock , M. Krzystyniak , Ilya Kuprov

The predictive accuracy of Machine Learning (ML) models of molecular properties depends on the choice of the molecular representation. Based on the postulates of quantum mechanics, we introduce a hierarchy of representations which meet…

Chemical Physics · Physics 2016-11-23 Bing Huang , O. Anatole von Lilienfeld

Extremely flat and inverted radio spectra as observed in galactic nuclei and BL Lac sources are still a challenge for fast particle acceleration models. Continuous acceleration by electric fields in reconnection regions can result in almost…

Astrophysics · Physics 2009-11-06 G. T. Birk , A. R. Crusius--Waetzel , H. Lesch

Molecular representation learning plays a crucial role in AI-assisted drug discovery research. Encoding 3D molecular structures through Euclidean neural networks has become the prevailing method in the geometric deep learning community.…

Machine Learning · Computer Science 2023-03-29 Yiqun Wang , Yuning Shen , Shi Chen , Lihao Wang , Fei Ye , Hao Zhou

We examine the impact of the combination of a static electric field and a non resonant linearly polarized laser field on an asymmetric top molecule. Within the rigid rotor approximation, we analyze the symmetries of the Hamiltonian for all…

Chemical Physics · Physics 2015-05-28 J. J. Omiste , R. González-Férez , P. Schmelcher

A beam of rotating dipolar particles (molecules or clusters) will broaden when passed through an electric or magnetic field gradient region. This broadening, which is a common experimental observable, can be expressed in terms of the…

Atomic and Molecular Clusters · Physics 2012-01-05 Jaap Bulthuis , Vitaly V. Kresin

Developing robust representations of chemical structures that enable models to learn topological inductive biases is challenging. In this manuscript, we present a representation of atomistic systems. We begin by proving that our…

Machine Learning · Computer Science 2024-09-27 Rahul Khorana , Marcus Noack , Jin Qian

Quantitative thermodynamical, dynamical and magnetic properties of the solar and stellar plasmas are obtained by interpreting their emergent non-polarized and polarized spectrum. This inference requires the selection of a set of spectral…

Solar and Stellar Astrophysics · Physics 2016-05-25 A. Asensio Ramos , J. de la Cruz Rodriguez , M. J. Martinez Gonzalez , A. Pastor Yabar

In this paper we provide further spectral analysis of the general asymptotic scattering resonances formula of small high contrast 3D dielectrics of arbitrary shape, initially derived to a first order approximation. To investigate the…

Mathematical Physics · Physics 2022-04-22 Taoufik Meklachi , Kevin Li , Brian Adams

An introductory review, suitable for the beginning student of high-energy physics or professionals from other fields who may desire familiarity with subatomic-particle detection techniques. Subatomic-particle fundamentals and the basics of…

Instrumentation and Detectors · Physics 2015-07-20 Daniel M. Kaplan , Charles. E. Lane , Kenneth S. Nelson

The first step in the construction of a regression model or a data-driven analysis, aiming to predict or elucidate the relationship between the atomic scale structure of matter and its properties, involves transforming the Cartesian…

Deep learning is transforming many areas in science, and it has great potential in modeling molecular systems. However, unlike the mature deployment of deep learning in computer vision and natural language processing, its development in…

Computational Physics · Physics 2021-03-19 Jun Zhang , Yao-Kun Lei , Zhen Zhang , Junhan Chang , Maodong Li , Xu Han , Lijiang Yang , Yi Isaac Yang , Yi Qin Gao

The problem of correlation between quantum states of four-atomic molecules in different geometrical configurations is reviewed in detail. A general, still simple rule is obtained which allows one to correlate states of a linear four-atomic…

Condensed Matter · Physics 2009-10-22 N. Manini , S. Oss

We compute spectra of symmetric random matrices defined on graphs exhibiting a modular structure. Modules are initially introduced as fully connected sub-units of a graph. By contrast, inter-module connectivity is taken to be incomplete.…

Disordered Systems and Neural Networks · Physics 2009-08-24 G. Ergun , R. Kuehn

Encoding the electronic structure of molecules using 2-electron reduced density matrices (2RDMs) as opposed to many-body wave functions has been a decades-long quest as the 2RDM contains sufficient information to compute the exact molecular…

Chemical Physics · Physics 2022-08-11 David Pekker , Chungwen Liang , Sankha Pattanayak , Swagatam Mukhopadhyay

A rigorous quantum description of molecular dynamics with a particular emphasis on internal observables is developed accounting explicitly for kinetic couplings between nuclei and electrons. Rotational modes are treated in a genuinely…

Chemical Physics · Physics 2015-07-07 Sylvain D. Brechet , Francois A. Reuse , Klaus Maschke , Jean-Philippe Ansermet

Molecule representation learning is crucial for understanding and predicting molecular properties. However, conventional atom-centric models, which treat chemical bonds merely as pairwise interactions, often overlook complex bond-level…

Machine Learning · Computer Science 2026-03-03 Yunqing Liu , Yi Zhou , Wenqi Fan