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The nuclear many-body problem for medium-mass systems is commonly addressed using wave-function expansion methods that build upon a second-quantized representation of many-body operators with respect to a chosen computational basis. While…

Nuclear Theory · Physics 2021-02-02 J. Hoppe , A. Tichai , M. Heinz , K. Hebeler , A. Schwenk

Implicit electron-density solvation models based on joint density-functional theory offer a computationally efficient solution to the problem of calculating thermodynamic quantities of solvated systems from firstprinciples quantum…

Chemical Physics · Physics 2015-02-12 Deniz Gunceler , T. A. Arias

Electronic charge delocalization on the molecular backbones of ionic liquid-forming ions substantially impacts their molecular polarizabilities. Density functional theory calculations of polarizabilities and volumes of many cations and…

Soft Condensed Matter · Physics 2024-01-31 C. D. Rodriguez-Fernandez , E. Lopez Lago , C. Schroder , L. M. Varela

Dephasing is the loss of phase coherence due to the interaction of an electron with the environment. The most common approach to model dephasing in light-matter interaction is the relaxation time approximation. Surprisingly, its use in…

The Many-Body Expansion (MBE) is a useful tool to simulate condensed phase chemical systems, often avoiding the steep computational cost of usual electronic structure methods. However, it often requires higher than 2-body terms to achieve…

Chemical Physics · Physics 2019-11-21 Srimukh Prasad Veccham , Joonho Lee , Martin Head-Gordon

In this work we provide a comprehensive review of theoretical and experimental studies of the properties of polarons formed by mobile impurities strongly interacting with quantum many-body systems. We present a unified perspective on the…

By explicitly including fractionally ionic contributions to the polarizability of a many-component system we are able to significantly improve on previous atom-wise many-body van der Waals approaches with essentially no extra numerical…

Chemical Physics · Physics 2017-03-28 Tim Gould , Sébastien Lebègue , János G. Ángyán , Tomáš Bučko

An extended Designed regression analysis of experimental data on density and refractive indices of several classes of ionic liquids yielded statistically averaged atomic volumes and polarizabilities of the constituting atoms. These values…

Modeling the couplings between active particles often neglects the possible many-body effects that control the propulsion mechanism. Accounting for such effects requires the explicit modeling of the molecular details at the origin of…

Soft Condensed Matter · Physics 2023-09-18 Jeanne Decayeux , Jacques Fries , Vincent Dahirel , Marie Jardat , Pierre Illien

The numerous combinations of cations and anions turn out possible to produce ionic liquids with fine-tuned properties once the correlation with the molecular structure is known. In this sense, computer simulations are useful tools to…

The presence of strong interactions in a many-body quantum system can lead to a variety of exotic effects. Here we show that even in a comparatively simple setup consisting of a charged impurity in a weakly interacting bosonic medium the…

Quantum Gases · Physics 2021-05-13 G. E. Astrakharchik , L. A. Peña Ardila , R. Schmidt , K. Jachymski , A. Negretti

The ion-electron coupling properties for a ion impurity in an electron gas and for a two component plasma are carried out on the basis of a regularized electron-ion potential removing the short-range Coulomb divergence. This work is largely…

Statistical Mechanics · Physics 2009-11-07 B Talin , E Dufour , A Calisti , M A Gigosos , M A Gonzalez , T del Rio Gaztelurrutia , J Dufty

We propose a novel method to describe realistically ionization processes with absorbing boundary conditions in basis expansion within the formalism of the so-called Non-Adiabatic Quantum Molecular Dynamics. This theory couples…

Quantum Physics · Physics 2015-06-26 Mathias Uhlmann , Thomas Kunert , Ruediger Schmidt

Ion-mediated interaction is important for the properties of polyelectrolytes such as colloids and nucleic acids. The effective pair interactions between two polyelectrolytes have been investigated extensively, but the many-body effect for…

Soft Condensed Matter · Physics 2016-08-19 Xi Zhang , Jin-Si Zhang , Ya-Zhou Shi , Xiao-Long Zhu , Zhi-Jie Tan

We study the impact of many-body effects on the fundamental precision limits in quantum metrology. On the one hand such effects may lead to non-linear Hamiltonians, studied in the field of non-linear quantum metrology, while on the other…

Quantum Physics · Physics 2019-06-25 Jan Czajkowski , Krzysztof Pawłowski , Rafał Demkowicz-Dobrzański

In this article, we outline the modeling of a realistic dynamical model for comprehensive description of high energy heavy ion collisions. Comparing theoretical calculations and experimental data at RHIC, we give detailed discussions on the…

Nuclear Theory · Physics 2012-07-10 Chiho Nonaka , Masayuki Asakawa

Direct experimental access to some of the most intriguing quantum phenomena is not granted due to the lack of precise control of the relevant parameters in their naturally intricate environment. Their simulation on conventional computers is…

Quantum Physics · Physics 2011-06-15 Christian Schneider , Diego Porras , Tobias Schaetz

We present a new methodology to analyze complicated multi-physics simulations by introducing a fictitious parameter. Using the method, we study quantum mechanical aspects of an organic molecule in water. The simulation is variationally…

Chaotic Dynamics · Physics 2007-05-23 Toshiya Takami , Jun Maki , Jun-ichi Ooba , Taizo Kobayashi , Rie Nogita , Mutsumi Aoyagi

Recent molecular simulation and integral equation results alkali-halide ion pair potentials-of-mean-force in water are discussed. Dielectric model calculations are implemented to check that these models produce that characteristic structure…

chem-ph · Physics 2008-02-03 Lawrence R. Pratt , Gerhard Hummer , Angel E. Garcia

Basic problems of the semiclassical microscopic modelling of strongly interactingsystems are discussed within the framework of Quantum Molecular Dynamics (QMD). This model allows to study the influence of several types of nucleonic…

Nuclear Theory · Physics 2014-11-18 C. Hartnack , Rajeev K. Puri , J. Aichelin , J. Konopka , S. A. Bass , H. Stoecker , W. Greiner