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Cooperative Jahn-Teller ordering is well-known to drive the cubic $Fd\overline{3}m$ to tetragonal $I$4$_1$/$amd$ structural distortion in Mn$_3$O$_4$ at 1170 $^{\circ}$C. Further structural distortion occurs in Mn$_3$O$_4$ upon magnetic…

Materials Science · Physics 2014-08-26 Moureen C. Kemei , Jaye K. Harada , Ram Seshadri , Matthew R. Suchomel

Using {\it ab initio} molecular dynamics we investigate the electronic and lattice structure of $A$Fe$_2$As$_2$ ($A$=Ca, Sr, Ba) under pressure. We find that the structural phase transition (orthorhombic to tetragonal symmetry) is always…

Superconductivity · Physics 2009-10-13 Yu-Zhong Zhang , Hem C. Kandpal , Ingo Opahle , Harald O. Jeschke , Roser Valenti

We report a high-resolution angle-resolved photo-emission spectroscopy study of the evolution of the electronic structure of FeSe1-xSx single crystals. Isovalent S substitution onto the Se site constitutes a chemical pressure which subtly…

Superconductivity · Physics 2015-09-23 M. D. Watson , T. K. Kim , A. A. Haghighirad , S. F. Blake , N. R. Davies , M. Hoesch , T. Wolf , A. I. Coldea

We present thermodynamic, structural and transport measurements on Ba(Fe0.973Cr0.027)2As2 single crystals. All measurements reveal sharp anomalies at ~ 112 K. Single crystal x-ray diffraction identifies the structural transition as a first…

Materials Science · Physics 2009-07-28 S. L. Bud'ko , S. Nandi , N. Ni , A. Thaler , A. Kreyssig , A. Kracher , J. -Q. Yan , A. I. Goldman , P. C. Canfield

Neutron and X-ray diffraction, magnetic susceptibility, and specific heat measurements have been used to investigate the magnetic and structural phase transitions of the spinel system Fe1+xCr2-xO4(0.0<=x<=1.0). The temperature versus Fe…

The structural and magnetic properties of the hexagonal four-layer form of SrMnO$_3$ have been investigated by combining magnetization measurements, electron diffraction and high-resolution synchrotron X-ray and neutron powder diffraction.…

Strongly Correlated Electrons · Physics 2007-05-23 A. Daoud-Aladine , C. Martin , L. C. Chapon , M. Hervieu , K. S. Knight , M. Brunelli , P. G. Radaelli

The structural and magnetic phase transitions have been studied on NdFeAsO single crystals by neutron and x-ray diffraction complemented by resistivity and specific heat measurements. Two low-temperature phase transitions have been observed…

We attribute the structural phase transition (SPT) in the parent compounds of the iron pnictides to orbital ordering. Due to the anisotropy of the $d_{xz}$ and $d_{yz}$ orbitals in the $xy$ plane, a ferro-orbital ordering makes the…

Strongly Correlated Electrons · Physics 2013-05-29 Weicheng Lv , Jiansheng Wu , Philip Phillips

The effect of pressure on the crystalline structure and superconducting transition temperature (Tc) of the 111-type Na1-xFeAs system using in situ high pressure synchrotron x-ray powder diffraction and diamond anvil cell techniques is…

The fluorine-doped rare-earth iron oxyarsenides, REFeAsO1-xFx (RE =rare earth) have recently emerged as a new family of high-temperature superconductors with transition temperatures (Tc) as high as 55 K (refs 1-4). Early work has provided…

Electrical resistivity measurements of detwinned single crystals of the representative iron arsenide Ba(Fe$_{1-x}$Co$_x$)$_2$As$_2$ reveal a dramatic in-plane anisotropy associated with the tetragonal-to-orthorhombic structural transition…

Resistivity, magnetic susceptibility, neutron scattering and x-ray crystallography measurements were used to study the evolution of magnetic order and crystallographic structure in single-crystal samples of the Ba1-xSrxFe2As2 and…

Superconductivity · Physics 2012-09-06 K. Kirshenbaum , N. P. Butch , S. R. Saha , P. Y. Zavalij , B. G. Ueland , J. W. Lynn , J. Paglione

The main features in iron-pnictide superconductors are summarized as (i) the orthorhombic transition accompanied by remarkable softening of shear modulus, (ii) high-Tc superconductivity close to the orthorhombic phase, and (iii) stripe-type…

Superconductivity · Physics 2015-03-19 Hiroshi Kontani , Tetsuro Saito , Seiichiro Onari

In this Letter we report high-resolution synchrotron X-ray powder diffraction and transmission electron microscope analysis of Mn-substituted LaFeAsO samples, demonstrating that a static incommensurate modulated structure develops across…

Superconductivity · Physics 2017-02-08 A. Martinelli , P. Manfrinetti , A. Provino , A. Genovese , F. Caglieris , G. Lamura , C. Ritter , M. Putti

Microstructure properties, phase transitions, and charge ordering in the LuFe2O4 materials have been extensively investigated by means of transmission electron microscopy (TEM). The (001) twins as a common defect frequently appear in the…

Strongly Correlated Electrons · Physics 2007-05-23 Y. Zhang , H. X. Yang , C. Ma , H. F. Tian , J. Q. Li *

We study a spin $S$ quantum Heisenberg model on the Fe lattice of the rare-earth oxypnictide superconductors. Using both large $S$ and large $N$ methods, we show that this model exhibits a sequence of two phase transitions: from a high…

Strongly Correlated Electrons · Physics 2009-11-13 Chen Fang , Hong Yao , Wei-Feng Tsai , JiangPing Hu , Steven A. Kivelson

The common phase diagrams of superconducting iron pnictides show interesting material specificities in the structural and magnetic phase transitions. In some cases the two transitions are separate and second order, while in others they…

Strongly Correlated Electrons · Physics 2012-02-14 Ryan Applegate , Rajiv R. P. Singh , Cheng-Chien Chen , Thomas P. Devereaux

We introduce structural heterogeneity, a new topological characteristic for semi-ordered materials that captures their degree of organisation at a mesoscopic level and tracks their time-evolution, ultimately detecting the order-disorder…

Fluorite-type $\mathrm{HfO_2}$-based ferroelectric (FE) oxides have rekindled interest in FE memories due to their compatibility with silicon processing and potential for high-density integration. The polarization characteristics of FE…

We use powder neutron diffraction to study the spin and lattice structures of polycrystalline samples of nonsuperconducting PrFeAsO and superconducting PrFeAsO0.85F0.15 and PrFeAsO0.85. We find that PrFeAsO exhibits an abrupt structural…