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We present a systematic study for understanding the relation between electronic correlation and superconductivity in C60 and aromatic compounds. We derived, from first principles, extended Hubbard models for twelve compounds; fcc K3C60,…

Superconductivity · Physics 2012-04-27 Yusuke Nomura , Kazuma Nakamura , Ryotaro Arita

We investigate the competition between the electron-vibron interaction (interaction with the Jahn-Teller phonons) and the Coulomb repulsion in a system with the local pairing of electrons on the 3-fold degenerate lowest unoccupied molecular…

Superconductivity · Physics 2019-05-14 Konstantin V. Grigorishin

The alkali-doped fullerides A$_3$C$_{60}$ are half-filled three-orbital Hubbard systems which exhibit an unconventional superconducting phase next to a Mott insulator. While the pairing is understood to arise from an effectively negative…

Strongly Correlated Electrons · Physics 2017-05-03 Shintaro Hoshino , Philipp Werner

Material with metallic $\sigma$-bonding bands is expected to be a high-temperature superconductor, due to the sensitivity of $\sigma$ electrons to lattice vibration. Based on the first-principles calculations, electronic structures of…

Superconductivity · Physics 2026-03-03 Guo Chen , Ru Zheng , Jin-Hua Sun , Fengjie Ma , Xun-Wang Yan , Miao Gao , Tian Cui , Zhong-Yi Lu

Alkali-fulleride superconductors with a maximum critical temperature Tc of 40 K exhibit similar electronic phase diagram with unconventional high-Tc superconductors where the superconductivity resides proximate to a magnetic Mott-insulating…

Superconductivity · Physics 2020-05-13 Ming-Qiang Ren , Sha Han , Shu-Ze Wang , Jia-Qi Fan , Can-Li Song , Xu-Cun Ma , Qi-Kun Xue

It has been recently shown that under pressure trilayer Ruddlesden-Popper nickelate La$_4$Ni$_3$O$_{10}$ (LNO) becomes superconducting below a critical temperature $\sim$20 K, in addition to the infinite-layer and bilayer systems. Motivated…

Strongly Correlated Electrons · Physics 2024-06-12 I. V. Leonov

We investigate the ${\rm H_3S}$ phase of sulphur hydride under high pressure $\simeq$ 200 GPa by means of {\it ab-initio} calculations within the framework of the density-functional theory (DFT) with the PBE0 hybrid exchange-correlation…

Superconductivity · Physics 2015-11-30 Matej Komelj , Henry Krakauer

The nature of the correlated phases found in some graphene heterostructures is under debate. We use dynamical mean-field theory (DMFT) to analyze the effect of local correlations close to half-filling on one of such systems, the ABC…

Strongly Correlated Electrons · Physics 2022-08-30 M. J. Calderón , A. Camjayi , E. Bascones

Experimental studies of superconductivity properties of fullerides are briefly reviewed. Theoretical calculations of the electron-phonon coupling, in particular for the intramolecular phonons, are discussed extensively. The calculations are…

Superconductivity · Physics 2009-10-28 Olle Gunnarsson

The low-temperature structure of A1C60 (A=K, Rb) is an ordered array of polymerized C60 chains, with magnetic properties that suggest a non-metallic ground state. We study the paramagnetic state of this phase using first-principles…

mtrl-th · Physics 2008-02-03 S. C. Erwin , G. V. Krishna , E. J. Mele

The low-temperature structure of A1C60 (A=K, Rb) is an ordered array of polymerized C60 chains, with magnetic properties that suggest a non-metallic ground state. We study the paramagnetic state of this phase using first-principles…

Condensed Matter · Physics 2009-10-22 S. C. Erwin , G. V. Krishna , E. J. Mele

We present a comprehensive computational investigation of electron-phonon interactions in MXH$_3$ hydride compounds, where $M$ represents alkali and post-transition metals, and $X$ denotes 3$d$, 4$d$, and 5$d$ transition metals. Our density…

Superconductivity · Physics 2024-12-23 Bin Li , Cong Zhu , Junjie Zhai , Chuanhui Yin , Yuxiang Fan , Jie Cheng , Shengli Liu , Zhixiang Shi

Motivated by the recently experimental reported signatures of the tunable Mott insulating state and superconductivity in an ABC graphene trilayer superlattice, we investigate the charge compressibility, the spin correlation, and the…

Strongly Correlated Electrons · Physics 2021-07-09 Huijia Dai , Junchen Hou , Xiao Zhang , Ying Liang , Tianxing Ma

We present 13C NMR spin-lattice relaxation measurements (1/T1) in Na2CsC60 and Rb3C60 from 10 to 700K. The large temperature range of this measurement allow to define unambiguously an increase of 1/T1T with increasing temperature, which is…

Strongly Correlated Electrons · Physics 2009-11-07 V. Brouet , H. Alloul , S. Garaj , L. Forro

Assessing the effective relevance of multiband effects in the fullerides is of fundamental importance to understand the complex superconducting and transport properties of these compounds. In this paper we investigate in particular the role…

Superconductivity · Physics 2009-11-10 E. Cappelluti , P. Paci , C. Grimaldi , L. Pietronero

We report observation of strong magnetic proximity coupling in a heterostructured superconductor Sr$_2$VO$_3$FeAs, determined by the upper critical fields $H_{c2}(T)$ measurements up to 65 T. Using the resistivity and the radio-frequency…

The dynamical Jahn--Teller effect on fullerene sites in insulating Cs$_3$C$_{60}$ is investigated fully ab initio. The vibronic excitations of rotational type are at $\ge$65 cm$^{-1}$ while the net kinetic contribution to the Jahn--Teller…

Strongly Correlated Electrons · Physics 2015-04-06 Naoya Iwahara , Liviu F. Chibotaru

It is widely perceived that the correlation effect may play an important role in several unconventional superconducting families, such as cuprate, iron-based and heavy-fermion superconductors. The application of high pressure can tune the…

Superconductivity · Physics 2019-02-15 Enyu Wang , Jing Si , Xiyu Zhu , Guan-Yu Chen , Hai Lin , Hai-Hu Wen

The superconducting parameters are the key for building or identifying the theory responsible for the mechanism of superconductivity. Such parameters for fulleride superconductors have not been well established despite the tremendous…

Superconductivity · Physics 2022-08-09 Ren-Shu Wang , Di Peng , Li-Na Zong , Zeng-Wei Zhu , Xiao-Jia Chen

We study the electron-phonon coupling in the C60 fullerene within the first-principles GW approach, focusing on the lowest unoccupied t1u three-fold electronic state which is relevant for the superconducting transition in electron doped…

Materials Science · Physics 2015-05-30 Carina Faber , Jonathan Laflamme Janssen , Michel Côté , E. Runge , X. Blase