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We study the interplay of intrinsic-electronic and environmental factors on long-range charge transport across molecular chains with up to $N\sim 80$ monomers. We describe the molecular electronic structure of the chain with a tight-binding…

Mesoscale and Nanoscale Physics · Physics 2022-09-21 Francisco Lai Liang , Dvira Segal

Transport phenomena at the nanoscale are of interest due to the presence of both quantum and classical behavior. In this work, we demonstrate that quantum transport efficiency can be enhanced by a dynamical interplay of the system…

Quantum Physics · Physics 2009-05-22 Patrick Rebentrost , Masoud Mohseni , Ivan Kassal , Seth Lloyd , Alán Aspuru-Guzik

Electron transmission through molecules and molecular interfaces has been a subject of intensive research due to recent interest in electron transfer phenomena underlying the operation of the scanning tunneling microscope (STM) on one hand,…

Condensed Matter · Physics 2015-06-24 Abraham Nitzan

We investigate on the same footing the time-dependent electronic transport properties and vibrational dynamics of a molecular junction. We show that fluctuations of both the molecular vibron displacement and the electronic current across…

Mesoscale and Nanoscale Physics · Physics 2019-03-27 Rémi Avriller , R Souto , A. Martin-Rodero , A Yeyati

The electron transport properties of a four-terminal molecular device are computed within the framework of density functional theory and non-equilibrium Keldysh theory. The additional two terminals lead to new properties, including a…

Mesoscale and Nanoscale Physics · Physics 2009-09-01 Kamal K. Saha , Wenchang Lu , J. Bernholc , Vincent Meunier

We study the electrical conductance $G$ and the thermopower $S$ of single-molecule junctions, and reveal signatures of different transport mechanisms: off-resonant tunneling, on-resonant coherent (ballistic) motion, and multi-step hopping.…

Mesoscale and Nanoscale Physics · Physics 2017-04-12 Roman Korol , Michael Kilgour , Dvira Segal

Computer simulation of the hopping charge transport in disordered organic materials has been carried out explicitly taking into account charge-charge interactions. This approach provides a possibility to take into account dynamic…

Disordered Systems and Neural Networks · Physics 2015-05-13 Sergey V. Novikov

We investigate the influence of a dissipative environment which effectively comprises the effects of counterions and hydration shells, on the transport properties of short \DNA wires. Their electronic structure is captured by a…

Soft Condensed Matter · Physics 2007-05-23 R. Gutierrez , S. Mandal , G. Cuniberti

We present a detailed study of the conduction properties of a molecular wire where hopping processes between electronic sites are coupled to a vibrational mode of the molecule. The latter is sandwiched between two electronic leads at finite…

Mesoscale and Nanoscale Physics · Physics 2017-05-24 Simon Pigeon , Lorenzo Fusco , Gabriele De Chiara , Mauro Paternostro

We study the variation of electron transmission through Au-S-benzene-S-Au junctions and related systems as a function of the structure of the Au:S contacts. For junctions with semi-infinite flat Au(111) electrodes, the highly coordinated…

Mesoscale and Nanoscale Physics · Physics 2009-11-11 A. Grigoriev , J. Skoeldberg , G. Wendin , Z. Crljen

We consider a polaron model where molecular \emph{rotations} are important. Here, the usual hopping between neighboring sites is affected directly by the electron-phonon interaction via a {\em twist-dependent} hopping amplitude. This model…

Mesoscale and Nanoscale Physics · Physics 2009-11-07 Wei Zhang , Alexander O. Govorov , Sergio E. Ulloa

Charge and heat transport through a single molecule tunnel-coupled to external normal electrodes have been studied. The molecule with sufficiently strong interaction between lectrons and vibrational internal degrees of freedom can be…

Mesoscale and Nanoscale Physics · Physics 2012-04-16 Karol Izydor Wysokinski

Excitation transfer through interacting systems plays an important role in many areas of physics, chemistry, and biology. The uncontrollable interaction of the transmission network with a noisy environment is usually assumed to deteriorate…

Quantum Physics · Physics 2009-09-12 Filippo Caruso , Alex W. Chin , Animesh Datta , Susana F. Huelga , Martin B. Plenio

We investigate effects of Coulomb interaction and hopping transport in the insulator phase of granular metals and quantum dot arrays. We consider a spatially periodic as well as an irregular array, including disorder in a form of a random…

Mesoscale and Nanoscale Physics · Physics 2009-11-11 I. S. Beloborodov , A. V. Lopatin , V. M. Vinokur

We study the electronic transport in a molecular junction in which each site is coupled to a local phonon bath using the non-equilibrium Green's function method. We observe the length period of the oscillatory conductance in odd-numbered…

Strongly Correlated Electrons · Physics 2011-08-12 Ya-Lin Lo , Shih-Jye Sun , Ying-Jer Kao

Quantum transport in a non-equilibrium setting plays a fundamental role in understanding the properties of systems ranging from quantum devices to biological systems. Dephasing -- a key aspect of out-of-equilibrium systems -- arises from…

Quantum Physics · Physics 2024-04-15 Subhajit Sarkar , Bijay Kumar Agarwalla , Devendra Singh Bhakuni

We consider tunneling transport through a Mn$_{12}$ molecular magnet using spin density functional theory. A tractable methodology for constructing many-body wavefunctions from Kohn-Sham orbitals allows for the determination of…

Mesoscale and Nanoscale Physics · Physics 2010-02-08 L. Michalak , C. M. Canali , M. R. Pederson , M. Paulsson , V. G. Benza

Inspired by the work of Kamenev and Kohn, we present a general discussion of the two-terminal dc conductance of molecular devices within the framework of Time Dependent Current-Density Functional Theory. We derive a formally exact…

Materials Science · Physics 2008-06-10 E. Prodan , R. Car

We investigate charge transport in C$_{60}$-based single-molecule junctions with graphene electrodes employing a combination of density functional theory (DFT) electronic structure calculations and Landauer transport theory. In particular,…

Mesoscale and Nanoscale Physics · Physics 2017-01-12 Susanne Leitherer , Pedro B. Coto , Konrad Ullmann , Heiko B. Weber , Michael Thoss

The influence of electron-phonon interaction on the transmission phase shift of an electron passing through a quantum dot is investigated by using the scattering theory. The transmission phase versus the intra-dot level shows a serial of…

Mesoscale and Nanoscale Physics · Physics 2009-11-13 Juntao Song , Qing-feng Sun , Hua Jiang , X. C. Xie