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Graphene nanoribbons are the counterpart of carbon nanotubes in graphene-based nanoelectronics. We investigate the electronic properties of chemically modified ribbons by means of density functional theory. We observe that chemical…

Materials Science · Physics 2009-09-29 F. Cervantes-Sodi , G. Csányi , S. Piscanec , A. C. Ferrari

Flat electronic bands with tunable structures offer opportunities for the exploitation and manipulation of exotic interacting quantum states. Here, we present a controllable route to construct easily tunable flat bands in folded graphene,…

Nonlinear optical processes rely on the intrinsically weak interactions between photons enabled by their coupling with matter. Unfortunately, many applications in nonlinear optics are severely hindered by the small response of conventional…

Materials Science · Physics 2014-12-15 Joel D. Cox , F. J. Garcia de Abajo

It is shown, by DFT calculations, that the uniform functionalization of upper layer of graphite by hydrogen or fluorine does not change essentially its bonding energy with the underlying layers, whereas the functionalization by phenyl…

Mesoscale and Nanoscale Physics · Physics 2015-05-18 D. W. Boukhvalov , M. I. Katsnelson

Graphene nanoribbons (GNRs) produced by means of bottom-up chemical self-assembly are considered promising candidates for the next-generation nanoelectronic devices. We address the electronic transport properties of angled two-terminal GNR…

Mesoscale and Nanoscale Physics · Physics 2024-02-28 Kristiāns Čerņevičs , Oleg V. Yazyev

The paper presents a computational study of the ground-state magnetic phases of a selected bilayer graphene nanoflake in external electric field and magnetic field. The electric field has parallel and perpendicular component while the…

Materials Science · Physics 2017-05-02 Karol Szałowski

Theoretical study of graphite (graphene) edge is done. The most stable edge orientation is calculated to be a zigzag [110] edge. Possible applications of the result to the formation of different graphitic structures are discussed.

Materials Science · Physics 2007-05-23 Slava V. Rotkin

Spatially-resolved organic functionalization of monolayer graphene is successfully achieved by combining low-energy electron beam irradiation with 1,3-dipolar cycloaddition of azomethine ylide. Indeed, the modification of the graphene…

Modern nanotechnology allows producing, depending on application, various quantum nanostructures with the desired properties. These properties are strongly influenced by the confinement potential which can be modified, e.g., by electrical…

Mesoscale and Nanoscale Physics · Physics 2012-09-19 Elzbieta Zipper , Marcin Kurpas , Maciej M. Maska

We present an ab-initio analysis of the impact of edge shape and graphene-molecule anchor coupling on the electronic and transport functionalities of graphene-based molecular electronics devices. We analyze how Fano-like resonances, spin…

Mesoscale and Nanoscale Physics · Physics 2015-06-04 D. Carrascal , V. M. García-Suárez , J. Ferrer

We investigate theoretically the electronic structure of graphene and boron nitride (BN) lateral heterostructures, which were fabricated in recent experiments. The first-principles density functional calculation demonstrates that a huge…

Mesoscale and Nanoscale Physics · Physics 2016-07-04 Dong Zhang , Maosheng Miao , Fuhua Yang , Haiqing Lin , Kai Chang

The configuration of graphene (GE) sheet conforming to the spherical surface substrate is studied through theoretical model and molecular simulations. Two basic configurations are observed: fully conformation and wrinkling. The final…

Mesoscale and Nanoscale Physics · Physics 2015-12-15 Yanguang Zhou , Yuli Chen , Bin Liu , Zhenyu Yang , Ming Hu , Shengtao Wang , Zeshuai Yuan

Developing graphene-based nanoelectronics hinges on opening a band gap in the electronic structure of graphene, which is commonly achieved by breaking the inversion symmetry of the graphene lattice via an electric field (gate bias) or…

Materials Science · Physics 2014-06-11 Liangzhi Kou , Feiming Hu , Binghai Yan , Thomas Frauenheim , Changfeng Chen

The energy of arbitrary graphene edge is derived in analytical form. It contains a "chemical phase shift", determined by the chemical conditions at the edge. Direct atomistic computations support the universal nature of the relationship.…

Mesoscale and Nanoscale Physics · Physics 2010-12-06 Yuanyue Liu , Alex Dobrinsky , Boris I. Yakobson

Quantum confined devices that manipulate single electrons in graphene are emerging as attractive candidates for nanoelectronics applications. Previous experiments have employed etched graphene nanostructures, but edge and substrate disorder…

Mesoscale and Nanoscale Physics · Physics 2015-06-04 Monica T. Allen , Jens Martin , Amir Yacoby

We investigate charge transport in pentacene-graphene nanojunctions employing density functional theory (DFT) electronic structure calculations and the Landauer transport formalism. The results show that the unique electronic properties of…

Mesoscale and Nanoscale Physics · Physics 2013-02-26 Ivan A. Pshenichnyuk , Pedro B. Coto , Susanne Leitherer , Michael Thoss

In this paper, we apply the first-principle theory to explore how the electronic structures of armchair graphene nanoribbons (AGNRs) are affected by chemical modifications. The edge addends include H, F, N, NH$_{2}$, and NO$_{2}$. Our…

Materials Science · Physics 2007-11-13 Hao Ren , Qunxiang Li , Haibin Su , Q. W. Shi , Jie Chen , Jinlong Yang

We achieve fine tuning of graphene effective doping by applying ultrahigh pressures (> 10 GPa) using Atomic Force Microscopy (AFM) diamond tips. Specific areas in graphene flakes are irreversibly flattened against a SiO2 substrate. Our work…

Intense efforts have been made in recent years to realize nonlinear optical interactions at the single-photon level. Much of this work has focused on achieving strong third-order nonlinearities, such as by using single atoms or other…

Mesoscale and Nanoscale Physics · Physics 2015-08-25 Marco T. Manzoni , Iván Silveiro , F. Javier García de Abajo , Darrick E. Chang

The interaction between graphene and substrates provides a viable routes to enhance functionality of both materials. Depending on the nature of electronic interaction at the interface, the electron band structure of graphene is strongly…