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The exploration of topological phases in carbon allotropes offers a fascinating avenue to realize topological devices based on carbon materials. Here, using first-principles calculations, we propose a novel metastable carbon allotrope,…

Materials Science · Physics 2021-08-17 Chao Zhang , Xian-Yong Ding , Li-Yong Gan , Yu Cao , Bing-Sheng Li , Xiaozhi Wu , Rui Wang

Recently a stable monolayer of antimony in buckled honeycomb structure called antimonene was successfully grown on 3D topological insulator Bi$_2$Te$_3$ and Sb$_2$Te$_3$, which displays semiconducting properties. By first principle…

Materials Science · Physics 2017-03-22 Yuanfeng Xu , Bo Peng , Hao Zhang , Hezhu Shao , Rongjun Zhang , Hongliang Lu , David Wei Zhang , Heyuan Zhu

Graphite may be viewed as a low-surface-energy carbon allotrope with little layer-layer interaction. Other low-surface-energy allotropes but with much stronger layer-layer interaction may also exist. Here, we report a first-principles…

Materials Science · Physics 2016-01-12 Wen-Jin Yin , Yuan-Ping Chen , Yue-E. Xie , Li-Min Liu , S. B. Zhang

A new set of lattice-models based on the hexagonal $\sqrt{N}\times\sqrt{N}$ super-cells of the well-known honeycomb lattice with single-hole defect (HL-D-1/2N) are proposed to realize the nontrivial isolated flat-bands. Through performing…

Materials Science · Physics 2022-08-15 Chaoyu He , Yujie Liao , Tao Ouyang , Huimin Zhang , Hongjun Xiang , Jianxin Zhong

Exploring the chemistry of materials at high pressures has lead to the discovery of previously unknown exotic compounds. Here, we systematically search for all thermodynamically stable Sr-C compounds under pressure (up to 100 GPa) using the…

Materials Science · Physics 2025-06-30 Nikita Rybin , Evgeny Moerman , Pranab Gain , Artem R. Oganov , Alexander Shapeev

Boron carbon compounds have been shown to have feasible superconductivity. In our earlier paper [Zheng et al., Phys. Rev. B 107, 014508 (2023)], we identified a new conventional superconductor of LiB3C at 100 GPa. Here, we aim to extend the…

Super-hard C5 with lon topology (lon: Lonsdaleite hexagonal diamond) and characterized by the presence of sp3 and sp2 -like carbon sites is devised from crystal chemistry and used as template matrix structure for identifying original…

Materials Science · Physics 2024-04-03 Samir F Matar

Carbon allotropes have a large family of materials with varieties of crystal structures and properties and can realize different topological phases. Using first principles calculations, we predict a new two-dimensional (2D) carbon…

Materials Science · Physics 2019-12-06 Heng Gao , Wei Ren

In this work a systematic approach to the search for all-$sp^2$ bonded carbon allotropes with low density is presented. In particular, we obtain a number of novel energetically stable crystal structures, whose arrangement is closely related…

Carbon at extreme conditions is the focus of intensive scientific inquiry due to its importance for applications in inertial confinement fusion experiments and for understanding the interior structure of carbon-rich exoplanets. The extreme…

Materials Science · Physics 2022-11-21 Ashley S. Williams , Kien Nguyen-Cong , Jonathan T. Willman , Ivan I. Oleynik

Using the density functional theory we investigate a quasi-two dimensional carbon allotrope, ZzC, formed by square carbon lattice buckled in zigzag manner. By analyzing the Kohn-Sham energy and phonon dispersion obtained by lattice…

Materials Science · Physics 2012-08-07 Andrey Tokarev , Bhalchandra S. Pujari

We present a study of mechanical, electronic and magnetic properties of two dimensional (2D), monolayer of silicon carbide (SiC) in honeycomb structure and its quasi 1D armchair nanoribbons using first-principles plane wave method. In order…

Materials Science · Physics 2010-03-08 E. Bekaroglu , M. Topsakal , S. Cahangirov , S. Ciraci

Noting the structural relationships between phases of carbon and boron carbide with phases of boron nitride and boron subnitride, we investigate their mutual solubilities using a combination of first principles total energies supplemented…

Materials Science · Physics 2016-04-13 Hantao Zhang , Sanxi Yao , Michael Widom

We analyze the effects of sp^2/sp^3 bond-aspect ratio on the transport properties of amorphous carbon quasi-1D structures where structural disorder varies in a very non-linear manner with the effective bandgap. Using a tight-binding…

Mesoscale and Nanoscale Physics · Physics 2015-06-05 Mikhail V. Katkov , Somnath Bhattacharyya

Anthracyne (2DDA). 2DDA consists of chains of Dewar-anthracenes connected by acetylenic linkages. DFT-based simulations show that 2DDA is thermally stable and exhibits no imaginary phonon modes, confirming its dynamic stability. 2DDA is…

The thriving area of synthetic carbon allotropes witnesses theoretic proposals and experimental syntheses of many new two-dimensional ultrathin structures, which are often achieved by careful arrangement of non-hexagon $\mathrm{sp^2}$…

Mesoscale and Nanoscale Physics · Physics 2020-08-26 Guohui Zheng , Xiaosi Qi

In the search for MgB2-like phonon-mediated superconductors we have carried out a systematic density functional theory study of the Ca-B system, isoelectronic to Mg-B, at ambient and gigapascal pressures. A remarkable variety of candidate…

Materials Science · Physics 2015-06-16 Sheena Shah , Aleksey N. Kolmogorov

Kagome metals $A$V$_3$Sb$_5$ ($A=$ K, Rb, Cs) provide a compelling platform to explore the interplay between superconductivity (SC) and charge-density-wave (CDW) orders. While distinct CDW orders have been identified in K/RbV$_3$Sb$_5$…

Ab initio density functional theory calculations are carried out to predict the electronic properties and relative stability of gallium sulfide nanoribbons (Ga2S2-NRs) with either zigzag- or armchair-terminated edges. It is found that the…

Mesoscale and Nanoscale Physics · Physics 2016-10-12 Bao-Ji Wang , Xiao-Hua Li , Li-Wei Zhang , Guo-Dong Wang , San-Huang Ke
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