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Despite the use of glasses for thousands of years, the nature of the glass transition is still mysterious. On approaching the glass transition, the growth of dynamic heterogeneity has long been thought to play a key role in explaining the…

Soft Condensed Matter · Physics 2018-03-23 Lijin Wang , Ning Xu , W. H. Wang , Pengfei Guan

The point-to-set correlation function has proved to be a very valuable tool to probe structural correlations in disordered systems, but more than that, its detailed behavior has been used to try to draw information on the mechanisms leading…

Disordered Systems and Neural Networks · Physics 2016-06-29 Giacomo Gradenigo , Roberto Trozzo , Andrea Cavagna , Tomas S. Grigera

We show that the various crossovers between dynamical regimes observed in experiments and simulations of supercooled liquids can be explained in simple terms from the existence and statistical properties of dynamical heterogeneities. We…

Statistical Mechanics · Physics 2009-11-10 Ludovic Berthier , Juan P. Garrahan

We discuss some generic features of the dynamics of glass-forming liquids close to the glass transition singularity of the idealized mode-coupling theory (MCT). The analysis is based on a recent model by one of the authors for the…

Statistical Mechanics · Physics 2015-10-07 Tommaso Rizzo , Thomas Voigtmann

The interrelation of dynamic processes active on separated time-scales in glasses and viscous liquids is investigated using a model displaying two time-scale bifurcations both between fast and secondary relaxation and between secondary and…

Disordered Systems and Neural Networks · Physics 2015-03-19 Andrea Crisanti , Luca Leuzzi , Matteo Paoluzzi

The connectivity of the potential energy landscape in supercooled atomic liquids is investigated through the calculation of the instantaneous normal modes spectrum and a detailed analysis of the unstable directions in configuration space.…

Soft Condensed Matter · Physics 2009-10-31 Claudio Donati , Francesco Sciortino , Piero Tartaglia

We provide extended evidence that mode-coupling theory (MCT) of supercooled liquids for the ${\mathsf F}_{12}$ schematic model admits a microscopic realization based on facilitated spin models with tunable facilitation. Depending on the…

Disordered Systems and Neural Networks · Physics 2012-08-24 Jeferson J. Arenzon , Mauro Sellitto

Within the framework of the effective potential theory of the structural glass transition, we calculate for the p-spin model a static nonlinear susceptibility related to a four-point density correlation function, and show that it grows and…

Disordered Systems and Neural Networks · Physics 2009-10-13 Claudio Donati , Silvio Franz , Giorgio Parisi , Sharon C. Glotzer

Computer simulations are used to study a three-dimensional polydisperse model glassformer in a replica-coupling setup where an attractive field $\propto - \varepsilon Q$ of strength $\varepsilon$ can adjust the similarity of the system to a…

Soft Condensed Matter · Physics 2024-02-07 Niklas Küchler , Jürgen Horbach

Mode coupling theory (MCT) has been successful in explaining the observed sequence of time relaxations in dense fluids. Previous expositions of this theory showing this sequence have required the existence of an ideal glass transition…

Condensed Matter · Physics 2009-10-22 Gene F. Mazenko , Joonhyun Yeo

We study theoretically the non-linear response properties of glass formers. We establish several general results which, together with the assumption of Time-Temperature Superposition, lead to a relation between the non-linear response and…

Statistical Mechanics · Physics 2009-12-19 Marco Tarzia , Giulio Biroli , Jean-Philippe Bouchaud , Alexandre Lefèvre

We present mode-coupling equations for the description of the slow dynamics observed in supercooled molecular liquids close to the glass transition. The mode-coupling theory (MCT) originally formulated to study the slow relaxation in simple…

Soft Condensed Matter · Physics 2009-10-31 L. Fabbian , A. Latz , R. Schilling , F. Sciortino , P. Tartaglia , C. Theis

We present an extensive treatment of the generalized mode-coupling theory (GMCT) of the glass transition, which seeks to describe the dynamics of glass-forming liquids using only static structural information as input. This theory amounts…

Statistical Mechanics · Physics 2016-07-05 Liesbeth M. C. Janssen , Peter Mayer , David R. Reichman

The effects of randomly pinning particles in a model glass-forming fluid are studied, with a focus on the dynamically heterogeneous relaxation in the presence of pinning. We show how four-point dynamical correlations can be analysed in real…

Statistical Mechanics · Physics 2013-10-30 Robert L. Jack , Christopher J. Fullerton

The goal of this chapter is to review recent analytical results about the growth of a (static) correlation length in glassy systems, and the connection that can be made between this length scale and the equilibrium correlation time of its…

Statistical Mechanics · Physics 2010-09-28 Silvio Franz , Guilhem Semerjian

Characterizing the glass state remains elusive since its distinction from a liquid state is not obvious. Glasses are liquids whose viscosity has increased so much that they cannot flow. Accordingly there have been many attempts to define a…

Statistical Mechanics · Physics 2015-05-27 Smarajit Karmakar , Edan Lerner , Itamar Procaccia

We give a brief introduction to the mode-coupling theory of the glass transition, a theory which was proposed a while ago to describe the dynamics of supercooled liquids. After presenting the basic equations of the theory, we review some of…

Statistical Mechanics · Physics 2008-02-03 W. Kob

The mode-coupling theory of the glass transition predicts the time evolution of the intermediate scattering functions in viscous liquids on the sole basis of the structural information encoded in two-point density correlations. We provide a…

Statistical Mechanics · Physics 2010-10-01 Ludovic Berthier , Gilles Tarjus

Glass-forming liquids have only a modest tendency to crystallize and hence their dynamics can be studied even below the melting temperature. The relaxation dynamics of most of these liquids shows at a temperature $T_c$, somewhat above the…

Soft Condensed Matter · Physics 2025-01-17 Francesco Rusciano , Raffaele Pastore , Francesco Greco , Walter Kob

The phenomenology of glass-forming liquids is often described in terms of their underlying, high-dimensional potential energy surface. In particular, the statistics of stationary points sampled as a function of temperature provides useful…

Statistical Mechanics · Physics 2021-01-06 Masanari Shimada , Daniele Coslovich , Hideyuki Mizuno , Atsushi Ikeda