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Quantum interference effects and decoherence mechanisms in single-molecule junctions are analyzed employing a nonequilibrium Green's function approach. Electrons tunneling through quasi-degenerate states of a nanoscale molecular junction…

Mesoscale and Nanoscale Physics · Physics 2011-07-25 R. Härtle , M. Butzin , O. Rubio-Pons , M. Thoss

We investigate the interplay of quantum interference effects and electronic-vibrational coupling in electron transport through single-molecule junctions, employing a nonequilibrium Green's function approach. Our findings show that inelastic…

Mesoscale and Nanoscale Physics · Physics 2013-02-18 R. Härtle , M. Butzin , M. Thoss

We study the transport through a molecular junction exhibiting interference effects. We show that these effects can still be observed in the presence of molecular vibrations if Coulomb repulsion is taken into account. In the Kondo regime,…

Strongly Correlated Electrons · Physics 2019-09-04 P. Roura-Bas , F. Güller , L. Tosi , A. A. Aligia

Molecular electronics offers unique scientific and technological possibilities, resulting from both the nanometre scale of the devices and their reproducible chemical complexity. Two fundamental yet different effects, with no classical…

Mesoscale and Nanoscale Physics · Physics 2017-05-12 Andrew K. Mitchell , Kim G. L. Pedersen , Per Hedegaard , Jens Paaske

Recent observations of destructive quantum interference in single-molecule junctions confirm the role played by quantum effects in the electronic conductance properties of molecular systems. We show here that the destructive interference…

Mesoscale and Nanoscale Physics · Physics 2017-09-25 Riccardo Frisenda , Vera Jansen , Ferdinand C. Grozema , Herre S. J. van der Zant , Nicolas Renaud

We look for manifestations of quantum interference effects in the Seebeck coefficient of a molecular junction, when the electronic conductance exhibits pronounced destructive interference features due to the presence of quasi-degenerate…

Mesoscale and Nanoscale Physics · Physics 2015-06-11 Lena Simine , Wei Jia Chen , Dvira Segal

Quantum states are described by wave functions whose phases cannot be directly measured, but which play a vital role in quantum effects such as interference and entanglement. The loss of the relative phase information, termed decoherence,…

Chemical Physics · Physics 2019-12-20 Jia Chen , Cong Hu , John F. Stanton , Stephen Hill , Hai-Ping Cheng , Xiao-Guang Zhang

The influence of multiple vibrational modes on current fluctuations in electron transport through single-molecule junctions is investigated. Our analysis is based on a generic model of a molecular junction, which comprises a single…

Mesoscale and Nanoscale Physics · Physics 2014-09-26 C. Schinabeck , R. Härtle , H. B. Weber , M. Thoss

Vibronic effects in resonant electron transport through single-molecule junctions are analyzed. The study is based on generic models for molecular junctions, which include electronic states on the molecular bridge that are vibrationally…

Mesoscale and Nanoscale Physics · Physics 2011-03-15 R. Härtle , M. Thoss

We discuss the various manifestations of quantum decoherence in the forms of dephasing, entanglement with the environment, and revelation of "which-path" information. As a specific example, we consider an electron interference experiment.…

Quantum Physics · Physics 2015-05-13 Jen-Tsung Hsiang , L. H. Ford

Coherent electronic transport through individual molecules is crucially sensitive to quantum interference. Using exact diagonalization techniques, we investigate the zero-bias and zero-temperature conductance through $\pi$-conjugated…

Strongly Correlated Electrons · Physics 2015-05-14 Julian Rincon , K. Hallberg , S. Ramasesha

The performance of modern quantum devices in communication, metrology or microscopy relies on the quantum-classical interaction which is generally described by the theory of decoherence. Despite the high relevance for long coherence times…

Quantum Physics · Physics 2020-08-26 Nicole Kerker , Robin Röpke , Lea-Marina Steinert , Andreas Pooch , Alexander Stibor

The decoherence of quantum states defines the transition between the quantum world and classical physics. Decoherence or, analogously, quantum mechanical collapse events pose fundamental questions regarding the interpretation of quantum…

Mesoscale and Nanoscale Physics · Physics 2021-09-24 P. Bredol , H. Boschker , D. Braak , J. Mannhart

We consider electronic transport through a single-molecule junction where the molecule has a degenerate spectrum. Unlike previous transport models, and theories a rate-equations description is no longer possible, and the quantum coherences…

Mesoscale and Nanoscale Physics · Physics 2013-05-29 Maximilian G. Schultz

Quantum interference can profoundly affect charge transport in single molecules, but experiments can usually measure only the conductance at the Fermi energy. Because in general the most pronounced features of the quantum interference are…

We theoretically examine the effect of the coupling of the transport electrons to a vibrational mode of the molecule on the ac linear-response conductance of molecular junctions. Representing the molecule by a single electronic state, we…

Mesoscale and Nanoscale Physics · Physics 2015-05-27 A. Ueda , O. Entin-Wohlman , A. Aharony

We propose a mechanism which allows one to control the transmission of single electrons through a molecular junction. The principle utilizes the emergence of transmission sidebands when molecular vibrational modes are coupled to the…

Mesoscale and Nanoscale Physics · Physics 2010-03-26 Thomas Olsen , Jakob Schiøtz

We investigate the role of electronic-vibrational coupling in resonant electron transport through single-molecule junctions, taking into account that the corresponding coupling strengths may depend on the charge and excitation state of the…

Mesoscale and Nanoscale Physics · Physics 2016-03-23 Andre Erpenbeck , Rainer Härtle , Michel Bockstedte , Michael Thoss

Understanding current-induced bond rupture in single-molecule junctions is both of fundamental interest and a prerequisite for the design of molecular junctions, which are stable at higher bias voltages. In this work, we use a fully quantum…

Mesoscale and Nanoscale Physics · Physics 2021-06-30 Yaling Ke , André Erpenbeck , Uri Peskin , Michael Thoss

Emergent quantum technologies have led to increasing interest in decoherence - the processes that limit the appearance of quantum effects and turn them into classical phenomena. One important cause of decoherence is the interaction of a…

Quantum Physics · Physics 2007-05-23 Lucia Hackermueller , Klaus Hornberger , Bjoern Brezger , Anton Zeilinger , Markus Arndt
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