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Motivated by recent experiments, we present here an ab initio study of the impact of the phonon transport on the thermal conductance and thermoelectric figure of merit of C$_{60}$-based single-molecule junctions. To be precise, we combine…

Mesoscale and Nanoscale Physics · Physics 2017-08-22 Jan Christopher Klöckner , Robert Siebler , Juan Carlos Cuevas , Fabian Pauly

We investigate charge transport in C$_{60}$-based single-molecule junctions with graphene electrodes employing a combination of density functional theory (DFT) electronic structure calculations and Landauer transport theory. In particular,…

Mesoscale and Nanoscale Physics · Physics 2017-01-12 Susanne Leitherer , Pedro B. Coto , Konrad Ullmann , Heiko B. Weber , Michael Thoss

C60 fullerene has been studied extensively, as it is considered to be a good candidate for building single-molecule junctions. Here, we theoretically demonstrate that the conductance of single-molecule junctions based on a newly discovered…

Mesoscale and Nanoscale Physics · Physics 2015-11-19 Chengbo Zhu , Xiaolin Wang

The charge flow from a single C60 molecule to another one has been probed. The conformation and electronic states of both molecules on the contacting electrodes have been characterized using a cryogenic scanning tunneling microscope. While…

Mesoscale and Nanoscale Physics · Physics 2009-11-11 Guillaume Schull , Thomas Frederiksen , Mads Brandbyge , Richard Berndt

A comprehensive review is presented of single molecule junction conductance measurements across families of molecules measured while breaking a gold point contact in a solution of molecules with amine end groups. A theoretical framework…

Mesoscale and Nanoscale Physics · Physics 2009-11-13 Mark S. Hybertsen , Latha Venkataraman , Jennifer E. Klare , Adam C. Whalley , Michael L. Steigerwald , Colin Nuckolls

Electrical and thermal transport properties of C60 molecules are investigated with density-functional-theory based calculations. These calculations suggest that the optimum contact geometry for an electrode terminated with a single-Au atom…

Mesoscale and Nanoscale Physics · Physics 2015-06-05 G. Géranton , C. Seiler , A. Bagrets , L. Venkataraman , F. Evers

We present a theoretical study of the transport characteristics of molecular junctions, where first-row diatomic molecules are attached to (001) gold and platinum electrodes. We find that the conductance of all of these junctions is of the…

Mesoscale and Nanoscale Physics · Physics 2015-05-13 J. Ferrer , V. M. Garcia-Suarez

We report on the single-molecule electronic and thermoelectric properties of strategically chosen anthracene-based molecules with anchor groups capable of binding to noble metal substrates, such as gold and platinum. Specifically, we study…

We consider transport through a single N@C60 molecule, weakly coupled to metallic leads. Employing a density-matrix formalism we derive rate equations for the occupation probabilities of many-particle states of the molecule. We calculate…

Mesoscale and Nanoscale Physics · Physics 2007-05-23 Florian Elste , Carsten Timm

We report the first concurrent determination of conductance (G) and thermopower (S) of single-molecule junctions via direct measurement of electrical and thermoelectric currents using a scanning tunneling microscope-based break-junction…

Mesoscale and Nanoscale Physics · Physics 2012-01-10 J. R. Widawsky , P. Darancet , J. B. Neaton , L. Venkataraman

Electron transport properties of C$_{20}$ molecules suspended between gold electrodes are investigated using first-principles calculations. Our study reveals that the conductances are quite sensitive to the number of C$_{20}$ molecules…

Condensed Matter · Physics 2009-11-10 Megumi Otani , Tomoya Ono , Kikuji Hirose

We report on inelastic electron tunneling spectroscopy measurements carried out on single molecules incorporated into a mechanically controllable break-junction of Au and Pt electrodes at low temperature. Here we establish a correlation…

Mesoscale and Nanoscale Physics · Physics 2010-11-16 Youngsang Kim , Hyunwook Song , Florian Strigl , Hans-Fridtjof Pernau , Takhee Lee , Elke Scheer

Thermoelectric properties of a C60 molecular transistor are studied using Green function formalism in linear response regime. A tight-binding model is used to investigate the effect of the dimerization and coupling geometry on the…

Mesoscale and Nanoscale Physics · Physics 2013-07-04 M. Bagheri Tagani , Z. Golsanamlou , S. Izadi , H. Rahimpour Soleimani

We present electronic transport measurements through thiolated C$_{60}$ molecules in liquid environment. The molecules were placed within a mechanically controllable break junction using a single anchoring group per molecule. When varying…

The effect of anchoring group on the electrical conductance of a single molecule bridging two Au electrodes was studied using di-substituted (isocyanide (CN-), thiol (S-) or cyanide (NC-)) benzene. The conductance of a single…

Materials Science · Physics 2009-11-11 Manabu Kiguchi , Shinichi Miura , Kenji Hara , Masaya Sawamura , Kei Murakoshi

The simplicity of single-molecule junctions based on direct bonding of a small molecule between two metallic electrodes make them an ideal system for the study of fundamental questions related to molecular electronics. Here we study the…

Mesoscale and Nanoscale Physics · Physics 2015-05-13 O. Tal , M. Kiguchi , W. H. A. Thijssen , D. Djukic , C. Untiedt , R. H. M. Smit , J. M. van Ruitenbeek

The measured conductance distribution for single molecule benzenediamine-gold junctions, based on 59,000 individual conductance traces recorded while breaking a gold point contact in solution, has a clear peak at 0.0064 G$_{0}$ with a width…

We present an experimental and theoretical study of a magnetic single-molecule transistor based on N@C60 connected to gold electrodes. Particular attention is paid to the regime of intermediate molecule-lead coupling, where cotunneling…

Mesoscale and Nanoscale Physics · Physics 2015-05-27 Nicolas Roch , Romain Vincent , Florian Elste , Wolfgang Harneit , Wolfgang Wernsdorfer , Carsten Timm , Franck Balestro

The conductance of C60 on Cu(100) is investigated with a low-temperature scanning tunneling microscope. At the transition from tunneling to the contact regime the conductance of C60 adsorbed with a pentagon-hexagon bond rises rapidly to…

Materials Science · Physics 2011-12-12 N. Neel , J. Kroger , L. Limot , T. Frederiksen , M. Brandbyge , R. Berndt

We present a systematic ab-initio study of the length dependence of the thermopower in molecular junctions. The systems under consideration are small saturated and conjugated molecular chains of varying length attached to gold electrodes…

Mesoscale and Nanoscale Physics · Physics 2015-12-15 Falco Hüser , Gemma C. Solomon
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