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The crystal and magnetic structure of La_{1-x}Sr_{1+x}MnO_4 (0<x<0.7) has been studied by diffraction techniques and high resolution capacitance dilatometry. There is no evidence for a structural phase transition like those found in…

Materials Science · Physics 2009-11-10 D. Senff , P. Reutler , M. Braden , O. Friedt , D. Bruns , A. Cousson , F. Bouree , M. Merz , B. Buechner , A. Revcolevschi

We have performed $^{119}$Sn-NMR measurements on the antiperovskite oxide superconductor Sr$_{3-x}$SnO to investigate how its normal state changes with the Sr deficiency. A two-peak structure was observed in the NMR spectra of all the…

Surfaces and interfaces offer new possibilities for tailoring the many-body interactions that dominate the electrical and thermal properties of transition metal oxides. Here, we use the prototypical two-dimensional electron liquid (2DEL) at…

Low temperature susceptibility and specific heat for single crystals of Pr$_{1-x}$La$_x$Os$_4$Sb$_{12}$ (0 $\leq x$ $\leq 1$) are reported. La-doping leaves CEF energies of Pr essentially unchanged. The average $T_c$ is only weakly affected…

Superconductivity · Physics 2007-05-23 C. R. Rotundu , P. Kumar , B. Andraka

Pyrochlore $\rm Pr^{3+}_{2+x}Zr^{4+}_{2-x}O_{7-x/2}$ samples in the form of both powders $(-0.02 \le x \le 0.02)$ and bulk single crystals have been studied to elucidate the dependence of their magnetic, compositional and structural…

Materials Science · Physics 2014-07-08 S. M. Koohpayeh , J. -J. Wen , B. A. Trump , C. L. Broholm , T. M. McQueen

Ti-substituted perovskites, La0.7Sr0.3Mn1-xTixO3, with x between 0 to 0.20, were investigated by neutron diffraction, magnetization, electric resistivity, and magnetoresistance (MR) measurements. All samples show a rhombohedral structure…

Materials Science · Physics 2009-11-11 M. S. Kim , J. B. Yang , Q. Cai , X. D. Zhou , W. J. James , W. B. Yelon , P. E. Parris , D. Buddhikot , S. K. Malik

Recently, it was established that a two-dimensional electron system can arise at the interface between two oxide insulators LaAlO3 and SrTiO3. This paradigmatic example exhibits metallic behaviour and magnetic properties between…

Strongly Correlated Electrons · Physics 2016-11-28 I. I. Piyanzina , Yu. V. Lysogorskiy , I. I. Varlamova , A. G. Kiiamov , T. Kopp , V. Eyert , O. V. Nedopekin , D. A. Tayurskii

We present a first-principles investigation of structural and elastic properties of experimentally observed phases of bulk SrRuO$_3$ - namely orthorhombic, tetragonal, and cubic - by applying density functional theory (DFT) approximations.…

Materials Science · Physics 2016-10-11 Š. Masys , V. Jonauskas

The intermetallic $\tau_{11}$ Al$_4$Fe$_{1.7}$Si phase is of interest for high-temperature structural application due to its combination of low density and high strength. We determine the crystal structure of the $\tau_{11}$ phase through a…

The structural, dielectric and ferroelectric properties of lead-free (Na0.5-xKxBi0.5-xLax)TiO3 powders synthesized by sol-gel self-combustion method were investigated. Rietveld refinement of Synchrotron x-ray diffraction data confirms pure…

Temperature dependence of the X-ray absorption near-edge structure (XANES) spectra at the Pr $L_{3}$- and Tb $L_{3}$-edges was measured for the (Pr$_{1-y}$Tb$_{y})_{0.7}$Ca$_{0.3}$CoO$_{3}$ system, in which a metal-insulator (MI) and…

Materials Science · Physics 2013-05-01 H. Fujishiro , T. Naito , D. Takeda , N. Yoshida , T. Watanabe , K. Nitta , J. Hejtmanek , K. Knizek , Z. Jirak

We report the growth of thin films of Sr1-xCaxRuO3 on SrTiO3 and MgO substrates by metalorganic aerosol deposition. The structure and microstructure is characterized by X-ray diffraction and room-temperature scanning tunnelling microscopy…

Strongly Correlated Electrons · Physics 2010-03-03 M. Schneider , V. Moshnyaga , P. Gegenwart

The effect of epitaxial strain on the phonon spectra, crystal structure, spontaneous polarization, dielectric, piezoelectric, and elastic properties of (001)-oriented ferroelectric (BaTiO$_3$)$_m$/(SrTiO$_3$)$_n$ superlattices ($m = n =…

Materials Science · Physics 2016-07-11 Alexander I. Lebedev

The complex dielectric constant $\hat{\epsilon} = \epsilon_1 + i \epsilon_2$ of SrTiO$_3$ reaches high values $\epsilon_1 \approx 2*10^{4}$ at cryogenic temperatures, while the dielectric losses ($\epsilon_2$) are much stronger than for…

Superconductivity · Physics 2019-11-27 Vincent T. Engl , Nikolaj G. Ebensperger , Lars Wendel , Marc Scheffler

In all archetypical reported (001)-oriented perovskite heterostructures, it has been deduced that the preferential occupation of two-dimensional electron gases is in-plane $d_\textrm{xy}$ state. In sharp contrast to this, the investigated…

ABO3 oxides with the perovskite-related structures are attracting significant interest due to their promising physical and chemical properties for many applications requiring tunable chemistry, including fuel cells, catalysis, and…

Materials Science · Physics 2021-07-13 Su Jeong Heo , Andriy Zakutayev

Perovskites like LaAlO3 (or SrTiO3) undergo displacive structural phase transitions from a cubic crystal to a trigonal (or tetragonal) structure. For many years, the critical exponents in both these types of transitions have been fitted to…

Statistical Mechanics · Physics 2022-03-14 A. Aharony , O. Entin-Wohlman , A. Kudlis

Motivated by the variation in reported lattice parameters of floating-zone-grown Nd$_{2}$Zr$_{2}$O$_{7}$ crystals, we have performed a detailed study of the relationship between synthesis environment, structural disorder, and magnetic…

Heteroepitaxial growth of BaSnO$_3$ (BSO) and Ba$_{1-x}$La$_x$SnO$_3$ (x = 7 %) (LBSO) thin films on different perovskite single crystal (SrTiO$_3$ (001) and SmScO$_3$ (110)) substrates has been achieved by Pulsed Laser Deposition (PLD)…

The surfaces of perovskite oxides affect their functional properties, and while a bulk-truncated (1$\times$1) termination is generally assumed, its existence and stability is controversial. Here, such a surface is created by cleaving the…

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