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L\"owdin's symmetry dilemma is an ubiquitous issue in approximate quantum chemistry. In the context of Hartree-Fock (HF) theory, the use of Slater determinants with some imposed constraints to preserve symmetries of the exact problem may…

Chemical Physics · Physics 2021-07-22 Leonardo A. Cunha , Joonho Lee , Diptarka Hait , C. William McCurdy , Martin Head-Gordon

We analyzed the Hartree-Fock approximation for an electron system. The interaction between particles is modeled by a non-Coulombian potential. We analyzed both the three-dimensional and two-dimensional systems. We obtained accurate…

Quantum Gases · Physics 2024-08-28 Vlad-Mihai Ene , Ilinca Lianu , Ioan Grosu

We discuss the stochastic mean-field theory (SMFT) method which is a new approach for describing disordered Bose systems in the thermodynamic limit including localization and dimensional effects. We explicate the method in detail and apply…

Disordered Systems and Neural Networks · Physics 2010-07-09 Ulf Bissbort , Ronny Thomale , Walter Hofstetter

A resonant level strongly coupled to a local phonon under nonequilibrium conditions is investigated. The nonequilibrium Hartree-Fock approximation is shown to correspond to approximating the steady state density matrix by delta functions at…

Mesoscale and Nanoscale Physics · Physics 2009-11-10 A. Mitra , I. Aleiner , A. J. Millis

Special solutions of the Hartree-Fock (HF) problem for Coulomb interacting electrons, being described by a simple model of the Cu-O planes in La2CuO4, are presented. One of the mean field states obtained, is able to predict some of the…

Strongly Correlated Electrons · Physics 2015-05-13 Alejandro Cabo-Bizet , Alejandro Cabo-Montes-de-Oca

We study the quantum many-body ground states of electrons on the half-filled honeycomb lattice with short- and long-ranged density-density interactions as a model for graphene. To this end, we employ the recently developed truncated-unity…

Strongly Correlated Electrons · Physics 2017-12-06 David Sánchez de la Peña , Julian Lichtenstein , Carsten Honerkamp , Michael M. Scherer

It is well-known from unrestricted Hartree-Fock computations that the 2D Hubbard model does not have homogeneous mean field states in significant regions of parameter space away from half filling. This is incompatible with standard mean…

Strongly Correlated Electrons · Physics 2015-06-24 Edwin Langmann , Mats Wallin

The two-dimensional extended Hubbard model that includes a nearest- neighbor Heisenberg interaction is studied using a mean-field theory where quasiparticles are defined by an U(8) group of canonical transformations. The theory is a…

Condensed Matter · Physics 2009-10-22 A. B. Eriksson , T. Einarsson , S. Ostlund

We study the Hartree-Fock model for pseudorelativistic atoms, that is, atoms where the kinetic energy of the electrons is given by the pseudorelativistic operator \sqrt{(pc)^2+(mc^2)^2}-mc^2. We prove the existence of a Hartree-Fock…

Mathematical Physics · Physics 2013-10-30 Anna Dall'Acqua , Thomas Østergaard Sørensen , Edgardo Stockmeyer

At low densities, electrons confined to two dimensions in a delta-doped heterostructure can arrange themselves into self-consistent droplets due to disorder and screening effects. We use this observation to show that at low temperatures,…

Strongly Correlated Electrons · Physics 2007-10-10 V. Tripathi , M. P. Kennett

Precise solutions of the Hartree-Fock equations for the ground state of the hydrogen molecule are obtained for a wide range of internuclear distances R by means of a two-dimensional fully numerical mesh computational method. The spatial…

Atomic Physics · Physics 2007-05-23 Mikhail V. Ivanov

In this paper we motivate, formulate and analyze the Multi-Configuration Time-Dependent Hartree-Fock (MCTDHF) equations for molecular systems under Coulomb interaction. They consist in approximating the N-particle Schrodinger wavefunction…

Mathematical Physics · Physics 2015-05-13 C. Bardos , I. Catto , N. Mauser , S. Trabelsi

We provide a review of recently-develop dynamical mean-field theory (DMFT) approaches to the general problem of strongly correlated electronic systems with disorder. We first describe the standard DMFT approach, which is exact in the limit…

Strongly Correlated Electrons · Physics 2023-02-16 E. Miranda , V. Dobrosavljevic

We study the dynamical properties of the canonical ordered phase of the Hamiltonian mean-field (HMF) model, in which $N$ particles, globally-coupled via pairwise attractive interactions, form a rotating cluster. Using a combination of…

We search for the uniform Hartree-Fock ground state of the two-dimensional electron gas formed in semiconductor heterostructures including the Rashba spin-orbit interaction. We identify two competing quantum phases: a ferromagnetic one with…

Mesoscale and Nanoscale Physics · Physics 2008-07-10 L. O. Juri , P. I. Tamborenea

Density functional theory (DFT) can run into serious difficulties with localized states in elements such as transition metals with occupied-d states and oxygen. In contrast, Hartree-Fock (HF) method can be a better approach for such…

Materials Science · Physics 2018-08-01 Hengxin Tan , Yuanchang Li , S. B. Zhang , Wenhui Duan

Hartree-Fock theory predicted stripe or bubble phase in the third and higher Landau levels for two-dimensional electrons, and experimental evidences has been accumulated. In this paper theoretical confirmation of the stripe phase and bubble…

Mesoscale and Nanoscale Physics · Physics 2009-11-07 Daijiro Yoshioka , Naokazu Shibata

Twisted bilayer transition metal dichalcogenides have emerged as important model systems for the investigation of correlated electron physics because their interaction strength, carrier concentration, band structure, and inversion symmetry…

Strongly Correlated Electrons · Physics 2021-09-01 Jiawei Zang , Jie Wang , Jennifer Cano , Andrew J. Millis

The stretching of closed-shell molecules is a qualitative problem for restricted Hartree-Fock that is usually circumvented by the use of unrestricted Hartree-Fock (UHF). UHF is well known to break the spin symmetry at the Coulson-Fischer…

Chemical Physics · Physics 2015-06-23 Paula Mori-Sánchez , Aron J. Cohen

We study the dynamics of a Fermi gas with a Coulomb interaction potential, and show that, in a mean-field limiting regime, the dynamics is described by the Hartree-Fock equation. This extends previous work of Bardos et al. to the case of…

Mathematical Physics · Physics 2011-08-30 Juerg Froehlich , Antti Knowles