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We present our theoretical results on the mechanism of two transitions in vanadium spinel oxides $A$V$_2$O$_4$ ($A$=Zn, Mg, or Cd) in which magnetic V cations constitute a geometrically-frustrated pyrochlore structure. We have derived an…

Strongly Correlated Electrons · Physics 2007-05-23 Yukitoshi Motome , Hirokazu Tsunetsugu

We present our theoretical and numerical results on thermodynamic properties and the microscopic mechanism of two successive transitions in vanadium spinel oxides $A$V$_2$O$_4$ ($A$=Zn, Mg, or Cd) obtained by Monte Carlo calculations of an…

Strongly Correlated Electrons · Physics 2007-05-23 Yukitoshi Motome , Hirokazu Tsunetsugu

Vanadium spinels (ZnV_2O_4, MgV_2O_4, and CdV_2O_4) exhibit a sequence of structural and magnetic phase transitions, reflecting the interplay of lattice, orbital, and spin degrees of freedom. We offer a theoretical model taking into account…

Strongly Correlated Electrons · Physics 2007-05-23 O. Tchernyshyov

The spinel vanadates have become a model family for exploring orbital order on the frustrated pyrochlore lattice, and recent debate has focused on the symmetry of local crystal fields at the cation sites. Here, we present neutron scattering…

Strongly Correlated Electrons · Physics 2014-06-10 G. J. MacDougall , I. Brodsky , A. A. Aczel , V. O. Garlea , G. E. Granroth , A. D. Christianson , T. Hong , H. D. Zhou , S. E. Nagler

We study magnetic excitations in vanadium spinel oxides AV$_2$O$_4$ (A=Zn, Mg, Cd) using two models: first one is a superexchange model for vanadium S=1 spins, second one includes in addition spin-orbit coupling, and crystal anisotropy. We…

Strongly Correlated Electrons · Physics 2014-09-03 N. B. Perkins , O. Sikora

Motivated by recent experimental progress in transition metal oxides with the K$_2$NiF$_4$ structure, we investigate the magnetic and orbital ordering in $\alpha$-Sr$_2$CrO$_4$. Using first principles calculations, first we derive a…

Strongly Correlated Electrons · Physics 2021-01-20 Bradraj Pandey , Yang Zhang , Nitin Kaushal , Rahul Soni , Ling-Fang Lin , Wen-Jun Hu , Gonzalo Alvarez , Elbio Dagotto

We present an analytical model of orbital ordering in vanadium spinel MnV2O4. The model is based on recent first-principles calculation indicating a strong trigonal distortion at the vanadium sites of this compound [Phys. Rev. Lett. 102,…

Strongly Correlated Electrons · Physics 2010-07-13 Gia-Wei Chern , Natalia Perkins , Zhihao Hao

Motivated by recent experiments on vanadium spinels, $A$V$_2$O$_4$, that show an increasing degree of electronic delocalization for smaller cation sizes, we study the evolution of orbital ordering (OO) between the strong and…

Strongly Correlated Electrons · Physics 2012-08-13 Yasuyuki Kato , Gia-Wei Chern , K. A. Al-Hassanieh , Natalia B. Perkins , C. D. Batista

We present the results of our theoretical study on the effects of geometrical frustration and the interplay between spin and orbital degrees of freedom in vanadium spinel oxides $A$V$_2$O$_4$ ($A$ = Zn, Mg or Cd). Introducing an effective…

Strongly Correlated Electrons · Physics 2015-06-24 Yukitoshi Motome , Hirokazu Tsunetsugu

Quantum Monte Carlo simulations are used to study the magnetic and transport properties of the Hubbard Model, and its strong coupling Heisenberg limit, on a one-third depleted square lattice. This is the geometry occupied, after charge…

Strongly Correlated Electrons · Physics 2017-01-25 H. -M. Guo , T. Mendes-Santos , W. E. Pickett , R. T. Scalettar

We study the electronic orders at the lower van Hove filling in the kagome lattice. In the weak limit of the Hubbard interaction $U$ versus the hopping parameter $t$, we find that the system develops itinerant ferromagnetism; In the…

Strongly Correlated Electrons · Physics 2024-02-19 Yi-Qun Liu , Yan-Bin Liu , Wan-Sheng Wang , Da Wang , Qiang-Hua Wang

Recent measurements on MgV$_2$O$_4$ single crystal have reignited the debate on the role of spin-orbit (SO) coupling in dictating the orbital order in Vanadium spinel systems. Density functional theory calculations were performed using the…

Strongly Correlated Electrons · Physics 2015-06-05 Ramandeep Kaur , T. Maitra , T. Nautiyal

The spinel MnV_2O_4 is a two-sublattice ferrimagnet, with site A occupied by the Mn^{2+} ion and site B by the V^{3+} ion. The magnon of the system, the transversal fluctuation of the total magnetization, is a complicated mixture of the…

Strongly Correlated Electrons · Physics 2009-11-13 Naoum Karchev

We present calculations of electronic and magnetic structures of vanadium-benzene multidecker clusters V$_{n}$Bz$_{n+1}$ ($n$ = 1 - 3) using advanced quantum Monte Carlo methods. These and related systems have been identified as prospective…

Chemical Physics · Physics 2015-06-19 L. Horváthová , R. Derian , L. Mitas , I. Štich

Using the quantum Monte Carlo method, we investigate the spin dynamics of itinerant electrons in the one-dimensional Hubbard system. Based on the model calculation, we have studied the spin-fluctuations in the quarter-filled metallic…

Strongly Correlated Electrons · Physics 2009-11-07 J. D. Lee

The five-band Hubbard model for a $d$ band with one electron per site is a model which has very interesting properties when the relevant ions are located at sites with high (e. g. cubic) symmetry. In that case, if the crystal field…

Strongly Correlated Electrons · Physics 2009-11-10 A. B. Harris , T. Yildirim , A. Aharony , O. Entin-Wohlman , I. Ya. Korenblit

We report detailed 51V NMR spectra in a single crystal of MnV2O4. The vanadium spectrum reveals two peaks in the orbitally ordered state, which arise from different internal hyperfine fields at two different V sublattices. These internal…

Strongly Correlated Electrons · Physics 2009-10-09 S. -H. Baek , N. J. Curro , K. -Y. Choi , A. P. Reyes , P. L. Kuhns , H. D. Zhou , C. R. Wiebe

We present a neutron diffraction study of FeV2O4, which is rare in exhibiting spin and orbital degrees of freedom on both cation sublattices of the spinel structure. Our data confirm the existence of three structural phase transitions…

Strongly Correlated Electrons · Physics 2012-09-03 G. J. MacDougall , V. O. Garlea , A. A. Aczel , H. D. Zhou , S. E. Nagler

We present a unique study of the frustrated spinel MgV2O4 which possesses highly coupled spin, lattice and orbital degrees of freedom. Using large single-crystal and powder samples, we find a distortion from spinel at room temperature…

Strongly Correlated Electrons · Physics 2010-10-14 Elisa M. Wheeler , Bella Lake , A. T. M. Nazmul Islam , Manfred Reehuis , Paul Steffens , Tatiana Guidi , Adrian H. Hill

We study the exchange constants of MnV$_2$O$_4$ using magnetic force theorem and local spin density approximation of density functional theory supplemented with a correction due to on-site Hubbard interaction U. We obtain the exchanges for…

Materials Science · Physics 2013-08-13 R. Nanguneri , S. Y. Savrasov
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