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Several monolayer transition metal dichalcogenides (TMDs) are direct band gap semiconductors and potentially efficient emitters in light emitting devices. Photons are emitted when strongly bound excitons decay radiatively, and accurate…

The quantum-dynamical mechanism of photoinduced subpicosecond exciton dissociation and the concomitant formation of a charge-separated state at a TFB:F8BT polymer heterojunction is elucidated. The analysis is based upon a two-state vibronic…

Materials Science · Physics 2009-11-11 Hiroyuki Tamura , Eric R. Bittner , Irene Burghardt

The energy band structure of excitons is studied in periodic potentials produced by the short-range interaction between the exciton and electrons of Wigner or Moir\'{e} lattices. Treating the exciton as a point-like dipole that interacts…

Materials Science · Physics 2023-08-16 Dinh Van Tuan , Hanan Dery

In their famous paper Kohn and Sham formulated a formally exact density-functional theory (DFT) for the ground-state energy and density of a system of $N$ interacting electrons, albeit limited at the time by certain troubling…

Mesoscale and Nanoscale Physics · Physics 2015-06-16 Miquel Huix-Rotllant , Mark E. Casida

The cornerstone of time-dependent (TD) density functional theory (DFT), the Runge-Gross theorem, proves a one-to-one correspondence between TD potentials and TD densities of continuum Hamiltonians. In all practical implementations, however,…

Mesoscale and Nanoscale Physics · Physics 2015-05-20 S. Kurth , G. Stefanucci

Exciton-phonon dynamics on a 1D lattice with long-range exciton-exciton interaction have been introduced and elaborated. Long-range interaction leads to a nonlocal integral term in the motion equation of the exciton subsystem if we go from…

Mathematical Physics · Physics 2011-04-08 Nick Laskin

Time-Dependent Density Functional Theory (TDDFT) has recently been extended to describe many-body open quantum systems (OQS) evolving under non-unitary dynamics according to a quantum master equation. In the master equation approach,…

Chemical Physics · Physics 2015-05-18 David G. Tempel , Mark A. Watson , Roberto Olivares-Amaya , Alán Aspuru-Guzik

The concept of an exciton as a quasiparticle that represents collective excited states was originally adapted from solid-state physics and has been successfully applied to molecular aggregates by relying on the well-established limits of…

Chemical Physics · Physics 2026-01-01 Seogjoo J. Jang , Irene Burghardt , Chao-Ping Hsu , Christopher J. Bardeen

The existence of strongly bound excitons is one of the hallmarks of the newly discovered atomically thin semi-conductors. While it is understood that the large binding energy is mainly due to the weak dielectric screening in two dimensions…

Materials Science · Physics 2016-01-20 Simone Latini , Thomas Olsen , Kristian S. Thygesen

Photo-active systems are characterized by their capacity of absorbing light energy and transforming it. Usually, more than one chromophore is involved in the light absorption and excitation transport processes in complex systems.…

Materials Science · Physics 2019-05-21 Joaquim Jornet-Somoza , Irina Lebedeva

A diagrammatic expansion for the dynamic exchange-correlation kernel f_xc of time dependent density functional theory is formulated. It is shown that f_xc has no singularities at Kohn-Sham transition energies in every order of the…

Condensed Matter · Physics 2009-11-07 I. V. Tokatly , R. Stubner , O. Pankratov

We formulate equations of time-dependent density functional theory (TDDFT) in the co-moving Lagrangian reference frame. The main advantage of the Lagrangian description of many-body dynamics is that in the co-moving frame the current…

Strongly Correlated Electrons · Physics 2009-11-10 I. V. Tokatly

The asymmetric Hubbard dimer is used to study the density-dependence of the exact frequency-dependent kernel of linear-response time-dependent density functional theory. The exact form of the kernel is given, and the limitations of the…

Strongly Correlated Electrons · Physics 2018-07-17 D. J. Carrascal , J. Ferrer , N. Maitra , K. Burke

We show that by nullifying the short-wave response to the long-wave excitation (local-field-effects), the adiabatic time-dependent density-functional theory (TDDFT) of optics of semiconductors and insulators can be brought into excellent…

Materials Science · Physics 2013-08-15 V. U. Nazarov , S. Kais

Strong light-matter interactions in layered transition metal dichalcogenides (TMDs) open up vivid possibilities for novel exciton-based devices. The optical properties of TMDs are dominated mostly by the tightly bound excitons and more…

We propose a computationally efficient approach to the nonadiabatic time-dependent density functional theory (TDDFT) which is based on a representation of the frequency-dependent exchange correlation kernel as a response of a set of damped…

Mesoscale and Nanoscale Physics · Physics 2019-12-18 Dmitry R. Gulevich , Yaroslav V. Zhumagulov , Alexei V. Vagov , Vasili Perebeinos

Charge-transfer excitons possessing long radiative lifetime and net permanent dipole moment are highly appealing for quantum dot (QD) based energy harvesting and photodetecting devices, in which the efficiency of charge separation after…

Mesoscale and Nanoscale Physics · Physics 2022-07-13 Yamei Zhou , Christos S. Garoufalis , Zaiping Zeng , Sotirios Baskoutas , Yu Jia , Zuliang Du

The equilibrium and non-equilibrium optical properties of single-layer transition metal dichalcogenides (TMDs) are determined by strongly bound excitons. Exciton relaxation dynamics in TMDs have been extensively studied by time-domain…

Transition--metal dichalcogenides (TMDs) uniquely combine topological electronic states realized without external magnetic fields with a strong optical response arising from long--lived excitons. Motivated by this confluence, we investigate…

Strongly Correlated Electrons · Physics 2026-04-28 Tianhong Lu , Luiz H. Santos

State-of-the-art methods for calculating neutral excitation energies are typically demanding and limited to single electron-hole pairs and their composite plasmons. Here we introduce excitonic density-functional theory (XDFT) a…

Chemical Physics · Physics 2023-01-09 Subhayan Roychoudhury , Stefano Sanvito , David D. O'Regan
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