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This work is concerned with a simple model for a polar fluid, a Gaussian field model based on the excess density and on the polarization. It is a convenient framework to implement the dielectric properties of correlated liquids that stem…

Chemical Physics · Physics 2018-04-04 Hélène Berthoumieux

The dielectric properties of molecules or nanostructures are usually modified in a complex manner, when assembled into a condensed phase. We propose a first-principles method to compute polarizabilities of sub-entities of solids and…

Chemical Physics · Physics 2018-09-10 Ding Pan , Marco Govoni , Giulia Galli

The structure of polar liquids and electrolytic solutions, such as water and aqueous electrolytes, at interfaces underlies numerous phenomena in physics, chemistry, biology, and engineering. In this work, we develop a continuum theory that…

Soft Condensed Matter · Physics 2022-07-13 J. Pedro de Souza , Alexei A. Kornyshev , Martin Z. Bazant

The existing polar continuum theory contains unresolved indeterminacies in the spherical part of the couple-stress tensor. This severely restricts its applicability in the study of micro and nano-scale solid and fluid mechanics and, perhaps…

Fluid Dynamics · Physics 2010-09-17 Ali R. Hadjesfandiari , Gary F. Dargush

The basic continuum model for polar fluids is deceptively simple. The free energy integral consists of four terms: The coupling of polarization to an external field, the electrostatic energy of the induced electric field interacting with…

Soft Condensed Matter · Physics 2021-12-22 Michiel Sprik

We study a two-dimensional fluid of dipolar hard disks by Monte Carlo simulations in a square with periodic boundary conditions and on the surface of a sphere. The theory of the dielectric constant and the asymptotic behaviour of the…

Soft Condensed Matter · Physics 2015-10-28 Jean-Michel Caillol , Jean-Jacques Weis

These are pedagogical lecture notes on hydrodynamic fluctuations in normal relativistic fluids. The lectures discuss correlation functions of conserved densities in thermal equilibrium, interactions of the hydrodynamic modes, an effective…

High Energy Physics - Theory · Physics 2015-06-05 Pavel Kovtun

An overview of some analytical approaches to the computation of the structural and thermodynamic properties of single component and multicomponent hard-sphere fluids is provided. For the structural properties, they yield a thermodynamically…

Statistical Mechanics · Physics 2008-07-18 M. Lopez de Haro , S. B. Yuste , A. Santos

Equations governing the flow of a polar fluid, with pressure-dependent Newtonian viscosity, through a variable-porosity medium are developed. Averaged equations are obtained using intrinsic volume averaging. A drag function is introduced to…

Fluid Dynamics · Physics 2025-12-04 M. H. Hamdan , D. C. Roach

The strengths and short-comings of the point-dipole model for polar fluids of spherical molecules are illustrated by considering the physically more relevant case of extended dipoles formed by two opposite charges $\pm q$ separated by a…

Statistical Mechanics · Physics 2009-11-10 V. Ballenegger , J. P. Hansen

This Perspective article provides an overview of some of our analytical approaches to the computation of the structural and thermodynamic properties of single-component and multicomponent hard-sphere fluids. For the structural properties,…

Soft Condensed Matter · Physics 2020-09-28 Andrés Santos , Santos B. Yuste , Mariano López de Haro

In this letter, we analyze the dipole-dipole correlations obtained from the molecular dynamics simulations for strongly- and weakly-polar model liquids. As a result, we found that cross-correlations contribution to the systems total dipole…

Soft Condensed Matter · Physics 2022-07-07 Kajetan Koperwas , Marian Paluch

We discuss some interesting physical features stemming from our previous analytical study of a simple model of a fluid with dipolar-like interactions of very short range in addition to the usual isotropic Baxter potential for adhesive…

Soft Condensed Matter · Physics 2015-05-14 Domenico Gazzillo , Riccardo Fantoni , Achille Giacometti

We consider a certain simplification of the two-dimensional thermomicropolar fluids equations. We prove the existence of certain solutions to these equations depending on the regularity of the intial data. We investigate the uniqueness of…

Analysis of PDEs · Mathematics 2016-09-29 Łukaszewicz Grzegorz , Siemianowski Jakub

We present a new method for Monte Carlo or Molecular Dynamics numerical simulations of three dimensional polar fluids. The simulation cell is defined to be the surface of the northern hemisphere of a four-dimensional (hyper)sphere. The…

Soft Condensed Matter · Physics 2014-09-29 Jean-Michel Caillol , Martin Trulsson

The thermodynamics of an electrically charged, multicomponent fluid with spontaneous electric dipoles and magnetic moments is analysed in the presence of electromagnetic fields. Taking into account the chemical composition of the current…

Statistical Mechanics · Physics 2015-06-15 Sylvain D. Brechet , Jean-Philippe Ansermet

This paper summarizes the properties of strongly correlating liquids, i.e., liquids with strong correlations between virial and potential energy equilibrium fluctuations at constant volume. We proceed to focus on the experimental…

Soft Condensed Matter · Physics 2015-03-14 Ulf R. Pedersen , Nicoletta Gnan , Nicholas P. Bailey , Thomas B. Schröder , Jeppe C. Dyre

These lecture notes present an overview of equilibrium statistical mechanics of classical fluids, with special applications to the structural and thermodynamic properties of systems made of particles interacting via the hard-sphere…

Soft Condensed Matter · Physics 2014-06-24 Andrés Santos

A thermodynamic framework that predicts the thermal conductivity $\lambda$ of simple fluids beyond the dilute-gas limit is introduced. By generalizing the transition-rate approach of particles on a lattice to conserved quantities in…

Statistical Mechanics · Physics 2025-12-03 Miguel Hoyuelos

An analytical model of non-Gaussian energy landscape of low-temperature fluids is developed based on the thermodynamics of the fluid of dipolar hard spheres. The entire excitation profile of the liquid, from the high temperatures to the…

Soft Condensed Matter · Physics 2009-11-13 Dmitry V. Matyushov
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