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Thermodynamics allows the application of Statistical Mechanics to finite and even small systems. As surface effects cannot be scaled away, one has to be careful with the standard arguments of splitting a system into two or bringing two…

Statistical Mechanics · Physics 2007-05-23 D. H. E. Gross

Microcanonical Thermodynamics allows the application of Statistical Mechanics on one hand to closed finite and even small systems and on the other to the largest,self-gravitating ones. However, one has to reconsider the fundamental…

Statistical Mechanics · Physics 2007-05-23 D. H. E. Gross

Microcanonical thermodynamics allows the application of statistical mechanics both to finite and even small systems and also to the largest, self-gravitating ones. However, one must reconsider the fundamental principles of statistical…

Statistical Mechanics · Physics 2009-11-11 D. H. E. Gross , J. F. Kenney

Heat spontaneously flows from hot to cold in standard thermodynamics. However, the latter theory presupposes the absence of initial correlations between interacting systems. We here experimentally demonstrate the reversal of heat flow for…

Equilibrium statistics of finite Hamiltonian systems is fundamentally described by the microcanonical ensemble (ME). Canonical, or grand-canonical partition functions are deduced from this by Laplace transform. Only in the thermodynamic…

Nuclear Theory · Physics 2008-11-26 D. H. E. Gross

In classical thermodynamics, heat must spontaneously flow from hot to cold systems. In quantum thermodynamics, the same law applies when considering multipartite product thermal states evolving unitarily. If initial correlations are…

Quantum Physics · Physics 2026-04-22 Naim Elias Comar , Danilo Cius , Luis Felipe Santos , Rafael Wagner , Bárbara Amaral

We consider a situation where an $N$-level system (NLS) is coupled successively to two heat baths with different temperatures without being necessarily thermalized and approaches a steady state. For this situation we apply a general…

Statistical Mechanics · Physics 2021-08-09 Heinz-Jürgen Schmidt , Jochen Gemmer

Equilibrium statistics of Hamiltonian systems is correctly described by the microcanonical ensemble, whereas canonical ones fail in the most interesting, mostly inhomogeneous, situations like phase separations or away from the thermodynamic…

Statistical Mechanics · Physics 2007-05-23 D. H. E. Gross

We present a fluctuation relation for heat dissipation in a nonequilibrium system. A nonequilibrium work is known to obey the fluctuation theorem in any time interval $t$. A heat, which differs from a work by an energy change, is shown to…

Statistical Mechanics · Physics 2012-06-19 Jae Dong Noh , Jong-Min Park

Fluctuation theorems are fundamental extensions of the second law of thermodynamics for small nonequilibrium systems. While work and heat are equally important forms of energy exchange, fluctuation relations have not been experimentally…

Statistical Mechanics · Physics 2022-02-24 Markus Rademacher , Michael Konopik , Maxime Debiossac , David Grass , Eric Lutz , Nikolai Kiesel

Equilibrium thermodynamics is grounded in the law of energy conservation, with a specific focus on how systems exchange energy with their environment during transitions between equilibrium states. These transitions are typically…

Statistical Mechanics · Physics 2024-08-19 Karol Makuch

It has long been known that, fundamentally different from a large body of rarefied gas, when a Knudsen gas is immersed in a thermal bath, it may never reach thermal equilibrium. The root cause is nonchaoticity: as the particle-particle…

Statistical Mechanics · Physics 2024-11-15 Yu Qiao , Zhaoru Shang

We study the warming process of a semi-infinite cylindrical Ising lattice initially ordered and coupled at the boundary to a heat reservoir. The adoption of a proper microcanonical dynamics allows a detailed study of the time evolution of…

Statistical Mechanics · Physics 2015-06-03 Elena Agliari , Mario Casartelli , Alessandro Vezzani

In classical thermodynamics energy always flows from the hotter system to the colder one. However, if these systems are initially correlated, the energy flow can reverse, making the cold system colder and the hot system hotter. This…

The principle that heat spontaneously flows from higher temperature to lower temperature is a cornerstone of classical thermodynamics, often assumed to be independent of the sequence of interactions. While this holds true for macroscopic…

The classical thermodynamic laws fail to capture the behavior of systems with energy Hamiltonian which is an explicit function of the temperature. Such Hamiltonian arises, for example, in modeling information processing systems, like…

Statistical Mechanics · Physics 2009-11-13 Ori Shental , Ido Kanter

Ability of dynamical systems to relax to equilibrium has been investigated since the invention of statistical mechanics, which establishes the connection between dynamics of many-body Hamiltonian systems and phenomenological thermodynamics.…

Statistical Mechanics · Physics 2019-07-01 K. S. Glavatskiy , V. L. Kulinskii

We study the dynamic and thermodynamic origin of non-canonical equilibria, and we discuss their connection with the generalized central limit theorem and the micro-canonical Boltzmann principle. We reach the conclusion that the zeroth law…

Statistical Mechanics · Physics 2010-12-16 Mauro Bologna , Michele Campisi , Paolo Grigolini

We consider a situation where an $N$-level system (NLS) is coupled to a heat bath without being necessarily thermalized. For this situation we derive general Jarzinski-type equations and conclude that heat and entropy is flowing from the…

Quantum Physics · Physics 2021-08-25 Heinz-Jürgen Schmidt , Jürgen Schnack , Jochen Gemmer

The understanding of the underlying dynamical mechanisms which determine the macroscopic laws of heat conduction is a long standing task of non-equilibrium statistical mechanics. A better understanding of the mechanism of heat conduction…

Statistical Mechanics · Physics 2011-09-08 Giulio Casati , Carlos Mejia-Monasterio
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