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We study the origin of the cubic to tetragonal and tetragonal to monoclinic structural transitions in KCrF3, and the associated change in orbital order, paying particular attention to the relevance of super-exchange in both phases. We show…

Strongly Correlated Electrons · Physics 2014-04-28 Carmine Autieri , Erik Koch , Eva Pavarini

We report a combined experimental and theoretical study of the PdSe2-xTex system. With increasing Te fraction, structural evolutions, first from an orthorhombic phase (space group Pbca) to a monoclinic phase (space group C2/c) and then to a…

We report synthesis of under doped non-superconducting parent compound of iron chalcogenide, i.e FeTe1-xSex (x=0.0, 0.01, 0.03, 0.05) single crystals by flux free method. These FeTe1-xSex (x=0.0, 0.01, 0.03, 0.05) single crystals are…

Superconductivity · Physics 2016-06-17 P. K. Maheshwari , Rajveer Jha , Bhasker Gahtori , V. P. S. Awana

We performed polarized Raman spectroscopy on mechanically exfoliated few-layer MoTe2 samples and observed both 1T' and Td phases at room temperature. Few-layer 1T' and Td MoTe2 exhibited a significant difference especially in interlayer…

Mesoscale and Nanoscale Physics · Physics 2021-01-25 Yeryun Cheon , Soo Yeon Lim , Kangwon Kim , Hyeonsik Cheong

The crystallographic and magnetic properties of the cleavable 4d3 transition metal compound a-MoCl3 are reported, with a focus on the behavior above room temperature. Crystals were grown by chemical vapor transport and characterized using…

This article reviews recent experimental investigations on two binary Fe-chalcogenides: FeSe and Fe$_{1+y}$Te. The main focus is on synthesis, single crystal growth, chemical composition, as well as on the effect of excess iron on…

Superconductivity · Physics 2016-06-06 Sahana Rößler , Cevriye Koz , Steffen Wirth , Ulrich Schwarz

We propose a phase diagram for FexBi2Te3 (0 < x < 0.1) single crystals, which belong to a class of magnetically bulk-doped topological insulators. The evolution of magnetic correlations from ferromagnetic- to antiferromagnetic- gives rise…

We performed systematic measurements of magnetic susceptibility on single crystals of La$_{1.875}$Ba$_{0.125-x}$Sr$_x$CuO$_4$. The dependence of the superconducting transition temperature on Sr-concentration demonstrates a step-like pattern…

Superconductivity · Physics 2009-10-31 M. Fujita , H. Goka , K. Yamada

Crystal structures and microstructural features, such as structural phase transitions, defect structures, chemical and structural inhomogeneities, are known to have profound effects on the physical properties of superconducting materials.…

Superconductivity · Physics 2013-07-22 Wang Zhen , Cai Yao , Yang Huai-Xin , Tian Huan-Fang , Wang Zhi-Wei , Ma Chao , Chen Zhen , Li Jian-Qi

Neutron powder diffraction studies of the crystal and magnetic structures of the magnetocaloric compound Mn1.1Fe0.9(P0.8Ge0.2) have been carried out as a function of temperature, applied magnetic field, and pressure. The data reveal that…

Materials Science · Physics 2009-11-30 D. M. Liu , Q. Huang , M. Yue , J. W. Lynn , L. J. Liu , Y. Chen , Z. H. Wu , J. X. Zhang

In this work we have investigated the orthorhombic to tetragonal phase transition in the Ba2Cu3O4Cl2 compound. This transition was observed by X-ray powder diffractometry carried out in samples heat treated between 700 and 750OC and also in…

Materials Science · Physics 2007-05-23 M. S. da Luz , C. A. M. dos Santos , B. Ferreira , A. J. S. Machado

Two-dimensional (2D) transition metal dichalcogenides MX2 (M = Mo, W, X = S, Se, Te) attracts enormous research interests in recent years. Its 2H phase possesses an indirect to direct bandgap transition in 2D limit, and thus shows great…

Layered transition metal dichalcogenides MoTe$_2$ and WTe$_2$ share almost similar lattice constants as well as topological electronic properties except their structural phase transitions. While the former shows a first-order phase…

Mesoscale and Nanoscale Physics · Physics 2017-05-10 Hyun-Jung Kim , Seoung-Hun Kang , Ikutaro Hamada , Young-Woo Son

We have investigated the crystal structure and magnetic properties for polycrystalline samples of LaMn1-xFexO3+y, in the whole range x=0.0 to x=1.0, prepared by solid state reaction in air. All samples show the ORT-2 orthorhombic structure…

Strongly Correlated Electrons · Physics 2009-11-13 O. F. de Lima , J. A. H. Coaquira , R. L. de Almeida , L. B. de Carvalho , S. K. Malik

We use a combination of Raman spectroscopy and transport measurements to study thin flakes of the type-II Weyl semimetal candidate MoTe2 protected from oxidation. In contrast to bulk crystals, which undergo a phase transition from…

We study the antiferromagnetic (AFM) and structural phase transitions in single crystal $BaFe_2(As_{1-x}P_x)_2$ $(x=0, 0.3)$ at temperatures $T_N$ and $T_S$, respectively, by high resolution ac microcalorimetry and SQUID magnetometry. The…

We report a study of the Ca$_{0.73}$La$_{0.27}$FeAs$_2$ single crystals. We unravel a monoclinic to triclinic phase transition at 58 K, and a paramagnetic to stripe antiferromagnetic (AFM) phase transition at 54 K, below which spins order…

We review neutron scattering investigations of the crystal structures, magnetic structures, and spin dynamics of the iron-based RFe(As,P)O (R=La, Ce, Pr, Nd), (Ba,Sr,Ca)Fe2As2, and Fe1+x(Te-Se) systems. On cooling from room temperature all…

Superconductivity · Physics 2009-05-20 Jeffrey W. Lynn , Pengcheng Dai

The magnetic structure of superconducting Eu(Fe0.82Co0.18)2As2 is unambiguously determined by single-crystal neutron diffraction. A long-range ferromagnetic order of the Eu2+ moments along the c-direction is revealed below the magnetic…

Superconductivity · Physics 2014-05-06 W. T. Jin , S. Nandi , Y. Xiao , Y. Su , O. Zaharko , Z. Guguchia , Z. Bukowski , S. Price , W. H. Jiao , G. H. Cao , Th. Brueckel

The structural and magnetic phase transitions have been studied on NdFeAsO single crystals by neutron and x-ray diffraction complemented by resistivity and specific heat measurements. Two low-temperature phase transitions have been observed…

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