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The wetting and filling properties of a fluid adsorbed on a solid grooved substrate are studied by means of a microscopic density functional theory. The grooved substrates are modelled using a solid slab, interacting with the fluid…

Mesoscale and Nanoscale Physics · Physics 2015-06-17 Alexandr Malijevsky

Experimental methods allow the shape and chemical composition of solid surfaces to be controlled at a mesoscopic level. Exposing such structured substrates to a gas close to coexistence with its liquid can produce quite distinct adsorption…

Condensed Matter · Physics 2009-10-31 C. Rascon , A. O. Parry

For one-component volatile fluids governed by dispersion forces an effective interface Hamiltonian, derived from a microscopic density functional theory, is used to study complete wetting of geometrically structured substrates. Also the…

Statistical Mechanics · Physics 2009-11-13 M. Tasinkevych , S. Dietrich

Mean field analysis of the effective interfacial Hamiltonian shows that with increasing temperature the adsorption on a periodically corrugated substrate can proceed in two steps: first, there is the filling transition in which the…

Statistical Mechanics · Physics 2009-10-31 K. Rejmer , M. Napiorkowski

Complete wetting of geometrically structured substrates by one-component fluids with long-ranged interactions is studied. We consider periodic arrays of rectangular or parabolic grooves and lattices of cylindrical or parabolic pits. We show…

Statistical Mechanics · Physics 2009-11-11 M. Tasinkevych , S. Dietrich

In this letter, we investigate the geometrically tailorable elasticity in the twisting behavior of biomimetic scale-covered slender soft substrate. Motivated by our qualitative experiments showing a significant torsional rigidity increase,…

Soft Condensed Matter · Physics 2019-09-04 Hossein Ebrahimi , Hessein Ali , Ryan Alexander Horton , Jonathan Galvez , Ali Gordon , Ranajay Ghosh

Recent experiments by Kavousanakis et al., Langmuir, 2018 [1], showed that reversible electrowetting on superhydrophobic surfaces can be achieved by using a thick solid dielectric layer (e.g. tens of micrometers). It has also been shown,…

Soft Condensed Matter · Physics 2018-07-30 Nikolaos T. Chamakos , George Karapetsas , Athanasios G. Papathanasiou

We investigate theoretically the wetting properties of cholesteric liquid crystals at a planar substrate. If the properties of substrate and of the interface are such that the cholesteric layers are not distorted the wetting properties are…

The wetting properties of solid substrates with customary (i.e., macroscopic) random roughness are considered as a function of the microscopic contact angle of the wetting liquid and its partial pressure in the surrounding gas phase.…

Soft Condensed Matter · Physics 2015-03-19 S. Herminghaus

We study a $d=2$ discrete solid--on--solid model of complete wetting of a rough substrate with random self--affine boundary, having roughness exponent $\zeta_s$. A suitable transfer matrix approach allows to discuss adsorption isotherms, as…

Condensed Matter · Physics 2009-10-22 G. Giugliarelli , A. L. Stella

We consider fluid adsorption near a rectangular edge of a solid substrate that interacts with the fluid atoms via long range (dispersion) forces. The curved geometry of the liquid-vapour interface dictates that the local height of the…

Statistical Mechanics · Physics 2014-06-20 Alexandr Malijevsky

Computer simulations are employed to investigate the adsorption mechanisms of ethane on both homogeneous and inhomogeneous substrates. For homogeneous surfaces, the full range of surface phase transitions - from incomplete to complete…

Soft Condensed Matter · Physics 2026-04-01 Ł. Baran , D. Tarasewicz , W. Rżysko

On the basis of the information theory approach we propose a novel statistical scheme for analyzing the evolution of coupled adsorbate-substrate systems, in which the substrate undergoes the adsorbate-induced transformations. A relation…

Statistical Mechanics · Physics 2009-11-10 E. V. Vakarin , J. P. Badiali

Anisotropically wetting substrates enable useful control of droplet behavior across a range of applications. Usually, these involve chemically or physically patterning the substrate surface, or applying gradients in properties like…

Soft Condensed Matter · Physics 2021-04-21 Katrina Smith-Mannschott , Qin Xu , Stefanie Heyden , Nicolas Bain , Eric R. Dufresne , Robert W. Style

Based on a microscopic density functional theory we investigate the morphology of thin liquidlike wetting films adsorbed on substrates endowed with well-defined chemical heterogeneities. As paradigmatic cases we focus on a single chemical…

Soft Condensed Matter · Physics 2009-10-31 C. Bauer , S. Dietrich

We investigate critical wetting transitions for fluids adsorbed in wedge-like geometries where the substrate height varies as a power-law, $z(x,y) \sim |x| ^\gamma$, in one direction. As $\gamma$ is increased from 0 to 1, the substrate…

Soft Condensed Matter · Physics 2009-11-07 A. Sartori , A. O. Parry

The wetting of soft polymer substrates brings in multiple complexities as compared to the wetting on rigid substrates. The contact angle of the liquid is no longer governed by Young's law, but is affected by the substrate's bulk and surface…

Soft Condensed Matter · Physics 2023-08-11 C. Henkel , M. H. Essink , Tuong Hoang , G. J. van Zwieten , E. H. van Brummelen , U. Thiele , J. H. Snoeijer

We investigate theoretically the possibility of a wetting transition induced by geometric roughness of a solid substrate for the case where the flat substrate does not show a wetting layer. Our approach makes use of a novel closed-form…

Soft Condensed Matter · Physics 2009-10-31 R. R. Netz , D. Andelman

We consider fluid wetting on a corrugated substrate using effective interfacial Hamiltonian theory and show that breaking the translational invariance along the wall can induce an 'unbending' phase transition in addition to unbinding. Both…

Soft Condensed Matter · Physics 2009-10-31 C. Rascon , A. O. Parry , A. Sartori

A partially-wetting liquid can deform the underlying elastic substrate upon which it rests. This situation requires the development of theoretical models to describe the wetting forces imparted by the drop onto the solid substrate,…

Soft Condensed Matter · Physics 2014-05-02 Joshua B. Bostwick , Michael Shearer , Karen E. Daniels
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