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We work out the non-equilibrium steady state properties of a harmonic lattice which is connected to heat reservoirs at different temperatures. The heat reservoirs are themselves modeled as harmonic systems. Our approach is to write quantum…

Mesoscale and Nanoscale Physics · Physics 2009-11-11 Abhishek Dhar , Dibyendu Roy

The theory of transport phenomena in multicomponent electrolyte solutions is presented here through the integration of continuum mechanics, electromagnetism, and non-equilibrium thermodynamics. The governing equations of irreversible…

Statistical Mechanics · Physics 2020-11-02 Kara D. Fong , Helen K. Bergstrom , Bryan D. McCloskey , Kranthi K. Mandadapu

The first non-empirical computation of lattice thermal conductivity has been performed for MgO using molecular dynamics (MD), a non-empirical ionic model (the Variationally Induced Breathing (VIB) model), and Green-Kubo theory. The…

Materials Science · Physics 2008-02-03 Ronald E. Cohen

The Green-Kubo (GK) method is a rigorous framework for heat transport simulations in materials. However, it requires an accurate description of the potential-energy surface and carefully converged statistics. Machine-learning potentials can…

Materials Science · Physics 2023-10-12 Marcel F. Langer , Florian Knoop , Christian Carbogno , Matthias Scheffler , Matthias Rupp

In this work we explicitly calculate the thermal conductivity for a general bidimensional dilute gas of neutral molecules by solving Boltzmann's equation. Chapman-Enskog's method is used in order to analytically obtain this transport…

Fluid Dynamics · Physics 2016-11-11 A. R. Méndez , A. L. Garcia-Perciante , E. S. Escobar-Aguilar

Among various possible routes to extend entropy and thermodynamics to nonequilibrium steady states (NESS), we take the one which is guided by operational thermodynamics and the Clausius relation. In our previous study, we derived the…

Statistical Mechanics · Physics 2013-02-13 Teruhisa S. Komatsu , Naoko Nakagawa , Shin-ichi Sasa , Hal Tasaki

Seemingly different interpretations or descriptions of Einstein's model for the heat capacity of a solid can be found in textbooks and the literature. The purpose of this note is to clarify the equivalence of the different descriptions,…

Statistical Mechanics · Physics 2021-02-09 Matt Beekman , Jonathan Fernsler , Thomas D. Gutierrez

Green-Kubo and Einstein expressions for the transport coefficients of a fluid in a nonequilibrium steady state can be derived using the Fluctuation Theorem and by assuming the probability distribution of the time-averaged dissipative flux…

Statistical Mechanics · Physics 2009-10-31 Debra J. Searles , Denis J. Evans

We present numerical results of electric conductivity $\sigma_{el}$ of a fluid obtained solving the Relativistic Transport Boltzmann equation in a box with periodic boundary conditions. We compute $\sigma_{el}$ using two methods: the…

High Energy Physics - Phenomenology · Physics 2014-12-10 A. Puglisi , S. Plumari , V. Greco

Using harmonic and anharmonic force constants extracted from density-functional calculations within a supercell, we have developed a relatively simple but general method to compute thermodynamic and thermal properties of any crystal. First,…

Materials Science · Physics 2015-05-28 Keivan Esfarjani , Gang Chen , Harold T. Stokes

We consider the problem of heat transport by vibrational modes (conduction) between Langevin thermostats connected by a central device. The latter is anharmonic and can be subject to large temperature differences and thus be out of…

Materials Science · Physics 2021-12-15 Keivan Esfarjani

The Einstein equation is derived from the proportionality of entropy and horizon area together with the fundamental relation $\delta Q=TdS$ connecting heat, entropy, and temperature. The key idea is to demand that this relation hold for all…

General Relativity and Quantum Cosmology · Physics 2010-11-01 Ted Jacobson

Chemical theories involving thermodynamical equilibrium states invariably utilize statistical mechanical equilibrium density distributions. Here, a definition of heat-work transformation termed thermo mechanical coherence is first made, and…

Chemical Physics · Physics 2007-05-23 Christopher G. Jesudason

We calculate the rate of energy flow between two macroscopic bodies, each in thermodynamic equilibrium at a different temperature, and joined by a weak mechanical link. The macroscopic solids are assumed to be electrically insulating, so…

Mesoscale and Nanoscale Physics · Physics 2009-11-07 Kelly R. Patton , Michael R. Geller

Equilibrium molecular dynamics simulations are used to calculate the thermal conductivity of the one component plasma (OCP) via the Green-Kubo formalism over a broad range of Coulomb coupling strength, $0.1\le\Gamma\le180$. These…

Plasma Physics · Physics 2019-10-30 Brett Scheiner , Scott D. Baalrud

Near field radiative heat transfer and dynamic Casimir forces are just two instances of topics of technological and fundamental interest studied via the formalism of fluctuational electrodynamics. From the perspective of experiment and…

Quantum Physics · Physics 2015-06-16 Vladyslav A. Golyk , Matthias Krüger , Mehran Kardar

This work is devoted to the \textit{ab initio} calculation of transport and optical properties of aluminum. The calculation is based on the quantum molecular dynamics simulation, density functional theory and the Kubo-Greenwood formula.…

Computational Physics · Physics 2013-10-16 D. V. Knyazev , P. R. Levashov

We show that vertex corrections to the quasi-harmonic Green-Kubo theory of heat transport in insulators naturally lead to a generalisation of the expression for the conductivity that could be derived from the linearized Boltzmann equation,…

Statistical Mechanics · Physics 2023-03-08 Alfredo Fiorentino , Stefano Baroni

The thermodynamic uncertainty relation expresses a universal trade-off between precision and entropy production, which applies in its original formulation to current observables in steady-state systems. We generalize this relation to…

Statistical Mechanics · Physics 2018-12-06 Timur Koyuk , Udo Seifert , Patrick Pietzonka

A recently introduced particle-based model for fluid flow, called Stochastic Rotation Dynamics, can be made Galilean invariant by introducing a random shift of the computational grid before collisions. In this paper, it is shown how the…

Soft Condensed Matter · Physics 2009-11-11 Thomas Ihle , Erkan Tuzel , Daniel M. Kroll