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This comment addresses several issues in the paper by Sepioni et al., where it is stated that the ferromagnetism in pristine highly oriented pyrolytic graphite (HOPG) reported by several groups in the previous years is most likely due to…

Strongly Correlated Electrons · Physics 2012-06-13 D. Spemann , M. Rothermel , P. Esquinazi , M. Ramos , Y. Kopelevich , H. Ohldag

We have studied the magnetization of various, well characterized samples of highly oriented pyrolitic graphite (HOPG), Kish graphite and natural graphite to investigate the recently reported ferromagnetic-like signal and its possible…

Strongly Correlated Electrons · Physics 2009-11-07 P. Esquinazi , A. Setzer , R. Hoehne , C. Semmelhack , Y. Kopelevich , D. Spemann , T. Butz , B. Kohlstrunk , M. Loesche

Ferromagnetism in carbon-based materials is appealing for both applications and fundamental science purposes because carbon is a light and bio-compatible material that contains only s and p electrons in contrast to traditional ferromagnets…

Materials Science · Physics 2009-10-13 J. Cervenka , M. I. Katsnelson , C. F. J. Flipse

In this study, the impurity concentration and magnetic response of nine highly oriented pyrolytic graphite (HOPG) samples with different grades and from different providers were determined using ion beam microscopy and SQUID magnetometry.…

Materials Science · Physics 2014-06-23 D. Spemann , P. Esquinazi , A. Setzer , W. Böhlmann

Carbon materials are attracting increasing attention due to the novelty of the associated physical properties and the potential applications in high-tech devices. The possibility to achieve outstanding properties in macroscopic carbon…

We demonstrate direct evidence for ferromagnetic order at defect structures in highly oriented pyrolytic graphite with magnetic force microscopy at room temperature. Magnetic impurities have been excluded as the origin of the magnetic…

Materials Science · Physics 2008-11-03 J. Cervenka , C. F. J. Flipse

We have investigated the variation in the magnetization of highly ordered pyrolytic graphite (HOPG) after neutron irradiation, which introduces defects in the bulk sample and consequently gives rise to a large magnetic signal. We observe…

We present a x-ray dichroism study of graphite surfaces that addresses the origin and magnitude of ferromagnetism in metal-free carbon. We find that, in addition to carbon $\pi$ states, also hydrogen-mediated electronic states exhibit a net…

Materials Science · Physics 2015-05-13 H. Ohldag , P. Esquinazi , E. Arenholz , D. Spemann , M. Rothermel , A. Setzer , T. Butz

We report $\beta$-detected nuclear magnetic resonance of ultra-dilute $^{8}$Li$^{+}$ implanted in highly oriented pyrolytic graphite (HOPG). The absence of motional narrowing and diffusional spin-lattice relaxation implies Li$^+$ is not…

We show that a superstructure of antiferromagnetically interacting Fe$^{3+}$ ($S=5/2$) ions in double perovskites AFe$_{1/2}$M$_{1/2}$O$_{3}$ exhibits a ferrimagnetic ordering below $T_{fe} \approx 5.6J_1$ ($J_1/k_B \sim 50$~K), which is…

Materials Science · Physics 2015-01-16 R. O. Kuzian , V. V. Laguta , J. Richter

There have recently been various reports of weak ferromagnetism in graphite (1,2) and synthetic carbon materials (3) such as rhombohedral C60 (4), as well as a theoretical prediction of a ferromagnetic instability in graphene sheets (5).…

Condensed Matter · Physics 2009-11-07 J. M. D. Coey , M. Venkatesan , C. B. Fitzgerald , A. P. Douvalis , I. S. Sanders

We have identified ferromagnetic- and superconducting-like magnetization hysteresis loops in highly oriented pyrolytic graphite samples below and above room temperature. We also found that both behaviors are very sensitive to…

Strongly Correlated Electrons · Physics 2007-05-23 Y. Kopelevich , P. Esquinazi , J. H. S. Torres , S. Moehlecke

Recently, magnetic order in highly oriented pyrolytic graphite (HOPG) induced by proton broad- and microbeam irradiation was discovered. Theoretical models propose that hydrogen could play a major role in the magnetism mechanism. We…

Magnetic 3d-ions doped into wide-gap oxides show signatures of room temperature ferromagnetism, although their concentration is two orders of magnitude smaller than that in conventional magnets. The prototype of these exceptional materials…

Materials Science · Physics 2009-11-13 C. D. Pemmaraju , R. Hanafin , T. Archer , H. B. Braun , S. Sanvito

High resolution magnetoresistance data in highly oriented pyrolytic graphite thin samples manifest non-homogenous superconductivity with critical temperature $T_c \sim 25 $K. These data exhibit: i) hysteretic loops of resistance versus…

The search for macroscopic magnetic ordering phenomena in organic materials, in particular in pure graphite, has been one of the more exciting scientific activities working in the frontiers of physics, chemistry, and materials science. In…

Materials Science · Physics 2007-05-23 H. Pardo , R. Faccio , A. W. Mombru , F. M. Araujo-Moreira , O. F. de Lima

Since 2000, the intensive effort in materials research to develop a diluted magnetic semiconductor exhibiting high-temperature (HT) ferromagnetism above room temperature was not successful. Here, the possible first bulk diluted…

We have studied the magnetic response of two bulk highly oriented pyrolytic graphite (HOPG) samples with different internal microstructure. For the sample with well defined interfaces, parallel to the graphene layers, the temperature and…

Superconductivity · Physics 2013-07-09 T. Scheike , P. Esquinazi , A. Setzer , W. Böhlmann

The high temperature ferromagnetism in Sr3YCo4O10+delta perovskite, whose origin has been the subject of a considerable debate, has been studied by neutron powder diffraction and synchrotron X-ray diffraction measurements. Oxygen vacancy…

Half-metallic ferromagnetism (HMFM) occurs rarely in materials and yet offers great potential for spintronic devices. Recent experiments suggest a class of compounds with the `ThCr$_{2}$Si$_{2}$' (122) structure -- isostructural and…

Materials Science · Physics 2020-08-18 Sinead M. Griffin , Jeffrey B. Neaton
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