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Progress on the numerical modeling of a prototype fuel cell is reported. Some known limitations of the previously published Alpha model are addressed, and the numerical uncertainty due to discretization of the improved model, Beta, was…

Computational Engineering, Finance, and Science · Computer Science 2020-11-16 O. Beruski , I. Korkischko , T. Lopes , F. C. Fonseca

The adiabatic self-consistent collective coordinate (ASCC) method is used to determine the optimum reaction path and to calculate the potential and the inertial functions of the reaction model. The properties of the inertial functions are…

Nuclear Theory · Physics 2024-05-09 Chisato Ruike , Kai Wen , Nobuo Hinohara , Takashi Nakatsukasa

Due to several attractive features, the meta-generalized-gradient approximations (meta-GGAs) are considered to be the most advanced and potentially accurate semilocal exchange-correlation functionals in the rungs of the Jacob's ladder of…

Atomic and Molecular Clusters · Physics 2020-04-28 Abhilash Patra , Subrata Jana , Lucian A. Constantin , Prasanjit Samal

An exchange-correlation energy functional $ E_{\mathrm xc} $ and the resultant exchange-correlation potential $ v_{\mathrm xc}({\bf r}) $ in density-functional theory are proposed using orbital-dependent coupling-constant-averaged pair…

Strongly Correlated Electrons · Physics 2007-05-23 Hiroshi Yasuhara , Masahiko Higuchi , Yoshiyuki Kawazoe

Density functional theory has been an essential analysis tool for both theoretical and experimental chemists since accurate hybrid functionals were developed. Here we propose a local hybrid method derived from the optimized effective…

Chemical Physics · Physics 2017-03-24 Jaewook Kim , Kwangwoo Hong , Sang-Yeon Hwang , Seongok Ryu , Sunghwan Choi , Woo Youn Kim

Radioactive decay of nuclei via emission of $\alpha$ particles has been studied theoretically in the framework of a superasymmetric fission model using the double folding (DF) procedure for obtaining the $\alpha$-nucleus interaction…

Nuclear Theory · Physics 2008-11-26 D. N. Basu

The computational study of conformational transitions in RNA and proteins with atomistic molecular dynamics often requires suitable enhanced sampling techniques. We here introduce a novel method where concurrent metadynamics are integrated…

Computational Physics · Physics 2015-09-01 Alejandro Gil-Ley , Giovanni Bussi

In this comprehensive and detailed study, vacancy-mediated self-diffusion of A- and B-elements in 'triple-defect' B2-ordered ASB(1-S) binaries is simulated by means of a kinetic Monte Carlo (KMC) algorithm involving atomic jumps to…

Materials Science · Physics 2019-10-16 Jan Betlej , Piotr Sowa , Rafal Kozubski , Graeme E. Murch , Irina V. Belova

We develop an improved stochastic formalism for the Bethe-Salpeter equation, based on an exact separation of the effective-interaction $W$ to two parts, $W=(W-v_W)+v_W$ where the latter is formally any translationally-invariant interaction…

Chemical Physics · Physics 2023-05-03 Nadine C. Bradbury , Tucker Allen , Minh Nguyen , Khaled Ibrahim , Daniel Neuhauser

A new anisotropic t-J model in one dimension is proposed which has long-range hopping and exchange. This t-J model is only partially solvable in contrast to known integrable models with long-range interaction. In the high-density limit the…

Condensed Matter · Physics 2009-10-28 Yasuhiro Saiga , Yusuke Kato , Yoshio Kuramoto

We examine the performance of our recently developed LFAs-PBE exchange-correlation (XC) potential [C.-R. Pan, P.-T. Fang, and J.-D. Chai, Phys. Rev. A, 2013, 87, 052510] for the high-order harmonic generation (HHG) spectra and related…

Chemical Physics · Physics 2016-06-14 Hsiao-Ling Sun , Wei-Tao Peng , Jeng-Da Chai

The accuracy of effective masses predicted by density functional theory depends on the exchange-correlation functional employed, with nonlocal hybrid functionals giving more accurate results than semilocal functionals. In this article, we…

Materials Science · Physics 2022-08-03 Magdalena Laurien , Oleg Rubel

Density functional theory (DFT) and beyond-DFT methods are often used in combination with photoelectron spectroscopy to obtain physical insights into the electronic structure of molecules and solids. The Kohn-Sham eigenvalues are not…

Aiming to remedy the incorrect asymptotic behavior of conventional semilocal exchange-correlation (XC) density functionals for finite systems, we propose an asymptotic correction scheme, wherein an exchange density functional whose…

Chemical Physics · Physics 2013-05-17 Chi-Ruei Pan , Po-Tung Fang , Jeng-Da Chai

This paper presents a tractable model for analyzing non-coherent joint transmission base station (BS) cooperation, taking into account the irregular BS deployment typically encountered in practice. Besides cellular-network specific aspects…

Information Theory · Computer Science 2014-09-22 Ralph Tanbourgi , Sarabjot Singh , Jeffrey G. Andrews , Friedrich K. Jondral

Certain excitations, especially ones of long-range charge transfer character, are poorly described by time-dependent density functional theory (TDDFT) when typical (semi-)local functionals are used. A proper description of these excitations…

Chemical Physics · Physics 2018-08-01 J. Garhammer , F. Hofmann , R. Armiento , S. Kümmel

We propose a new multi-scale molecular dynamics simulation method which can achieve high accuracy and high sampling efficiency simultaneously without aforehand knowledge of the coarse grained (CG) potential and test it for a biomolecular…

Biological Physics · Physics 2009-08-05 Wenfei Li , Shoji Takada

Most approximate exchange-correlation functionals used within density functional theory are constructed as the sum of two distinct contributions for exchange and correlation. Separating the exchange component from the entire functional is…

Condensed Matter · Physics 2009-10-28 Claudia Filippi , C. J. Umrigar , Xavier Gonze

Free-energy-based adaptive biasing methods, such as Metadynamics, the Adaptive Biasing Force (ABF) and their variants, are enhanced sampling algorithms widely used in molecular simulations. Although their efficiency has been empirically…

Probability · Mathematics 2026-01-29 Tony Lelièvre , Xuyang Lin , Pierre Monmarché

We present and test a new approximation for the exchange-correlation (xc) energy of Kohn-Sham density functional theory. It combines exact exchange with a compatible non-local correlation functional. The functional is by construction free…

Chemical Physics · Physics 2014-05-23 Tobias Schmidt , Eli Kraisler , Adi Makmal , Leeor Kronik , Stephan Kümmel