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Density functional theory (DFT) underpins modern atomistic simulations of transition-metal surfaces. It can predict key properties linked to catalytic performance, such as adsorption energies and barrier heights, enabling new paradigms in…

Materials Science · Physics 2026-03-23 Benjamin X. Shi , Timothy C. Berkelbach

The stationary functional of the all-electron density functional plus dynamical mean field theory (DFT+DMFT) formalism to perform free energy calculations and structural relaxations is implemented for the first time. Here, the first order…

Strongly Correlated Electrons · Physics 2015-12-23 Kristjan Haule , Turan Birol

The stability and formation mechanism of the defects relevant to silicon and carbon vacancies at the 4H-SiC(000$\bar{1}$)/SiO$_2$ interface after wet oxidation are investigated by first-principles calculation based on the density functional…

Materials Science · Physics 2024-01-09 Mukai Tsunasaki , Tomoya Ono , Mitsuharu Uemoto

Density functional theory (DFT) calculations are carried out to study the structure and electronic structure of amorphous zinc oxide (a-ZnO). The models were prepared by the "melt-quench" method. The models are chemically ordered with some…

Materials Science · Physics 2016-12-21 Anup Pandey , Heath Scherich , D. A. Drabold

Expanding the pool of stable halide perovskites with attractive optoelectronic properties is crucial to addressing current limitations in their performance as photovoltaic (PV) absorbers. In this article, we demonstrate how a…

Materials Science · Physics 2023-10-23 Jiaqi Yang , Panayotis Manganaris , Arun Mannodi-Kanakkithodi

We give a fairly comprehensive review of wavelets and of their application to density-functional theory (DFT) and to our recent application of a wavelet-based version of linear-response time-dependent DFT (LR-TD-DFT). Our intended audience…

Other Condensed Matter · Physics 2011-10-24 Bhaarathi Natarajan , Mark E. Casida , Luigi Genovese , Thierry Deutsch

Understanding radiation-induced defect formation in carbon materials is crucial for nuclear technology and for the manufacturing of nanostructures with desired properties. Using first principles molecular dynamics, we perform a systematic…

Materials Science · Physics 2007-05-23 Oleg V. Yazyev , Ivano Tavernelli , Ursula Rothlisberger , Lothar Helm

A comparative study of wurtzite ZnO doped by rare earth elements (Tm, Yb, Ce) have been investigated using density functional theory (DFT) based on the full-potential linearized augmented plane wave orbital (FP-LAPW) method, as implemented…

Materials Science · Physics 2020-04-23 M. Khuili , N. Fazouan , H. Abou El Makarim , E. H. Atmani , D. P. Rai , M. Houmad

We have performed a first-principles study of the structural and vibrational properties of the three low-pressure (cubic, tetragonal, and especially monoclinic) phases of ZrO2, with special attention to the computation of the zone-center…

Materials Science · Physics 2009-11-07 Xinyuan Zhao , David Vanderbilt

We report a comprehensive first-principles study of the thermodynamics and transport of intrinsic point defects in layered oxide cathode materials LiMO$_2$ (M=Co, Ni), using density-functional theory and the Heyd-Scuseria-Ernzerhof screened…

Materials Science · Physics 2014-12-17 Khang Hoang , Michelle D. Johannes

A system of soft ellipsoid molecules confined between two planar walls is studied using classical Density Functional Theory (DFT). Both the isotropic and nematic phases are considered. The excess free energy is evaluated using two different…

Materials Science · Physics 2009-11-10 David Cheung , Friederike Schmid

Structural defects are important for both solid-state chemistry and physics, as they can have a significant impact on chemical stability and physical properties. Here, we identify a vacancyinduced pseudo-gap formation in antiferromagnetic…

Thermodynamic, structural and electronic properties of isolated copper and iron atoms as well as their complexes with oxygen vacancies in tetragonal lead titanate are investigated by means of first principles calculations. Both dopants…

Materials Science · Physics 2010-09-06 Paul Erhart , Rüdiger-Albert Eichel , Petra Träskelin , Karsten Albe

Defects in the rutile TiO${}_2$ structures have been extensively studied, but the intrinsic defects of the oxygen deficient Ti${}_n$O${}_{2n-1}$ phases have not been given the same amount of consideration. Those structures, known as…

Materials Science · Physics 2014-08-04 A. C. M. Padilha , J. M. Osório-Guillen , A. R. Rocha , G. M. Dalpian

We study the optical properties of hydrogen passivated silicon, germanium and mixed Ge/Si core/shell quantum dots (QDs) using high accuracy Density Functional Theory (DFT) and time-dependent DFT (TDFT). We employ the hybrid DFT functional…

Mesoscale and Nanoscale Physics · Physics 2016-04-19 Shanawer Niaz , Aristides D. Zdetsis , Manzoor Ahmad Badar , Safdar Hussain , Imran Sadiq , Muhammad Aslam Khan

We present a detailed first principles density functional theory study of intrinsic and extrinsic point defects in monolayer (ML) WSe2. Among the intrinsic point defects, Se vacancies (Sevac) have the lowest formation energy (disregarding…

Materials Science · Physics 2019-01-17 Yu Jie Zheng , Su Ying Quek

The need to immobilize low-level nuclear waste, in particular 137Cs-bearing waste, has led to a growing interest in geopolymer-based waste matrices, in addition to optimization attempts of cement matrix compositions for this specific…

Chemical Physics · Physics 2025-05-21 Nurit Manukovsky , Noy Vaisleib , Michal Arbel-Haddad , Amir Goldbourt

Nuclear density functional theory (DFT) is one of the main theoretical tools used to study the properties of heavy and superheavy elements, or to describe the structure of nuclei far from stability. While on-going efforts seek to better…

Nuclear Theory · Physics 2015-12-23 N. Schunck , J. D. McDonnell , D. Higdon , J. Sarich , S. M. Wild

The development of quantitative models for radiation damage effects in iron, iron alloys and steels, particularly for the high temperature properties of the alloys, requires understanding of magnetic interactions, which control the phase…

Materials Science · Physics 2015-06-17 D. Nguyen-Manh , Pui-Wai Ma , M. Yu. Lavrentiev , S. L. Dudarev

The Skyrme nuclear energy density functional theory (DFT) is used to model neutron-induced fission in actinides. This paper focuses on the numerical implementation of the theory. In particular, it reports recent advances in DFT code…

Nuclear Theory · Physics 2015-06-12 N. Schunck
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