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In the real world, one almost never knows the parameters of a thermodynamic process to infinite precision. Reflecting this, here we investigate how to extend stochastic thermodynamics to systems with uncertain parameters, including…

Statistical Mechanics · Physics 2021-03-17 Jan Korbel , David H. Wolpert

An extended Hamiltonian approach to conduct isothermal-isobaric molecular dynamics simulations with full cell flexibility is presented. The components of the metric tensor are used as the fictitious degrees of freedom for the cell, thus…

Chemical Physics · Physics 2009-11-07 E. Hernandez

In this paper, we identify a class of time-varying port-Hamiltonian systems that is suitable for studying problems at the intersection of statistical mechanics and control of physical systems. Those port-Hamiltonian systems are able to…

Statistical Mechanics · Physics 2015-06-16 Jean-Charles Delvenne , Henrik Sandberg

We develop a continuum theory for thermoelectric bodies following the framework of continuum mechanics and conforming to general principles of thermodynamics. For steady states, the governing equations for local fields are intrinsically…

Materials Science · Physics 2012-03-05 Liping Liu

Active matter is rapidly becoming a key paradigm of out-of-equilibrium soft matter exhibiting complex collective phenomena, yet the thermodynamics of such systems remain poorly understood. In this letter we study the nonequilbrium…

Statistical Mechanics · Physics 2019-10-30 Emanuele Crosato , Mikhail Prokopenko , Richard E. Spinney

We investigate variational problems in quantum thermodynamics at positive temperature, in which admissible states are constrained by prescribed outcomes of a finite set of measurements. We solve a problem raised by the recent work [Liu,…

Mathematical Physics · Physics 2026-03-09 Emanuele Caputo , Augusto Gerolin , Nataliia Monina , Pavlo Pelikh , Lorenzo Portinale

Fluctuations of thermodynamic quantities become non-negligible and play an important role when the system size is small. We develop finite-time thermodynamics of fluctuations in microscopic heat engines whose environmental temperature and…

Statistical Mechanics · Physics 2022-02-16 Gentaro Watanabe , Yuki Minami

We present a systematic and consistent construction of geometrothermodynamics by using Riemannian contact geometry for the phase manifold and harmonic maps for the equilibrium manifold. We present several metrics for the phase manifold that…

General Relativity and Quantum Cosmology · Physics 2015-05-20 Hernando Quevedo , Alberto Sanchez , Safia Taj , Alejandro Vazquez

Optimality principles in nonequilibrium transport networks are linked to a thermodynamic formalism based on generalized transport potentials endowed with Legendre duality and related contact structure. This allows quantifying the distance…

Statistical Mechanics · Physics 2025-06-23 Amilcare Porporato , Shashank Kumar Anand , Salvatore Calabrese , Luca Ridolfi , Lamberto Rondoni

This work focuses on the response to an external field of a Brownian particle submerged in an Ohmic quantum thermal bath. The field only affects the dynamics of the central particle without affecting the thermal reservoir. The thermodynamic…

Quantum Physics · Physics 2019-11-12 Pedro J. Colmenares

In systems with detailed balance, the stationary distribution and the equilibrium distribution are identical, creating a clear connection between energetic and entropic quantities. Many driven systems violate detailed balance and still pose…

Statistical Mechanics · Physics 2025-01-22 Markus Hofer , Jan Korbel , Rudolf Hanel , Stefan Thurner

The earliest molecular dynamics simulations relied on solving the Newtonian or equivalently the Hamiltonian equations of motion for a system. While pedagogically very important as the total energy is preserved in these simulations, they…

Computational Physics · Physics 2020-06-04 M Sri Harish , Puneet Kumar Patra

Small thermodynamic systems exhibit peculiar behavior different from that observed in long-scale systems. Non-equilibrium processes taking place in those systems are strongly influenced by the presence of fluctuations which can be large.…

Statistical Mechanics · Physics 2007-05-23 J. M. Rubi

Identifying optimal thermodynamical processes has been the essence of thermodynamics since its inception. Here, we show that differentiable programming (DP), a machine learning (ML) tool, can be employed to optimize finite-time…

Quantum Physics · Physics 2022-03-24 Ilia Khait , Juan Carrasquilla , Dvira Segal

We discuss the relevance of geometric concepts in the theory of stochastic differential equations for applications to the theory of non-equilibrium thermodynamics of small systems. In particular, we show how the Eells-Elworthy-Malliavin…

Statistical Mechanics · Physics 2015-06-11 Paolo Muratore-Ginanneschi

Thermodynamics can be formulated in either of two approaches, the phenomenological approach, which refers to the macroscopic properties of systems, and the statistical approach, which describes systems in terms of their microscopic…

Quantum Physics · Physics 2019-05-01 Mirjam Weilenmann , Lea Krämer Gabriel , Philippe Faist , Renato Renner

The thermodynamic formalism, which was first developed for dynamical systems and then applied to discrete Markov processes, turns out to be well suited for continuous time Markov processes as well, provided the definitions are interpreted…

Statistical Mechanics · Physics 2009-11-13 Vivien Lecomte , Cecile Appert-Rolland , Frederic Van-Wijland

Nonequilibrium thermal machines under cyclic driving generally outperform steady-state counterparts. However, there is still lack of coherent understanding of versatile transport and fluctuation features under time modulations. Here, we…

Statistical Mechanics · Physics 2024-08-06 Zi Wang , Jie Ren

Numerical computations have become a pillar of all modern quantitative sciences. Any computation involves modeling--even if often this step is not made explicit--and any model has to neglect details while still being physically accurate.…

Statistical Mechanics · Physics 2022-11-08 Thomas Speck

The thermodynamic formalism allows one to access the chaotic properties of equilibrium and out-of-equilibrium systems, by deriving those from a dynamical partition function. The definition that has been given for this partition function…

Statistical Mechanics · Physics 2011-11-29 Vivien Lecomte , Cécile Appert-Rolland , Frédéric van Wijland
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