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We investigated the growth of titanium oxide two-dimensional (2D) nanostructures on Au(111), produced by Ti evaporation and post-deposition oxidation. Scanning tunneling microscopy and spectroscopy (STM and STS) and low-energy electron…

Materials Science · Physics 2016-12-21 F. Tumino , P. Carrozzo , L. Mascaretti , C. S. Casari , M. Passoni , S. Tosoni , C. E. Bottani , A. Li Bassi

Plastic deformation mechanisms have been investigated in the MAX phase Ti2AlN. Nanoindentation has been used to induce plastic deformation in a single grain, and a Transmission Electron Microscopy (TEM) lamella has been extracted in cross…

Carbon can exist as isolated dumbbell, one-dimensional (1D) chain, 2D plane, and 3D network in carbon solids or carbon-based compounds, which attributes to its rich chemical binding way, including sp-, sp2-, and sp3-hybridized bonds. Sp2…

Superconductivity · Physics 2014-10-28 Yan-Ling Li , Wei Luo , Zhi Zeng , Hai-Qing Lin , Ho-kwang Mao , Rajeev Ahuja

We study the pressure-induced structural transformation of Ge$_{136}$ clathrate by ab initio molecular dynamics and metadynamics. The system under pressure first undergoes amorphization followed by an ultrafast recrystallization to the…

Materials Science · Physics 2022-04-28 Marián Ryník , Stefano Leoni , Roman Martoňák

We studied the crystal and magnetic structure of Ca2RuO4 by different diffraction techniques under high pressure. The observed first order phase transition at moderate pressure (0.5 GPa) between the insulating phase and the metallic high…

Strongly Correlated Electrons · Physics 2009-11-11 P. Steffens , O. Friedt , P. Alireza , W. G. Marshall , W. Schmidt , F. Nakamura , S. Nakatsuji , Y. Maeno , R. Lengsdorf , M. M. Abd-Elmeguid , M. Braden

We use powder x-ray diffraction to study the effect of pressure on the crystal structure of the honeycomb rhodate Li$_2$RhO$_3$. We observe low-pressure ($P$$<$$P_{c1}$ = 6.5 GPa) and high-pressure ($P$$>$$P_{c2}$ = 14 GPa) regions…

Strongly Correlated Electrons · Physics 2019-08-30 V. Hermann , S. Biswas , J. Ebad-Allah , F. Freund , A. Jesche , A. A. Tsirlin , M. Hanfland , D. Khomskii , P. Gegenwart , R. Valentí , C. A. Kuntscher

We studied the crystal structure of TiOCl up to pressures of $p$=25~GPa at room temperature by x-ray powder diffraction measurements. Two pressure-induced structural phase transitions are observed: At $p_{c1}$$\approx$15~GPa emerges an…

Strongly Correlated Electrons · Physics 2015-05-20 J. Ebad-Allah , A. Schönleber , S. van Smaalen , M. Hanfland , M. Klemm , S. Horn , S. Glawion , M. Sing , R. Claessen , C. A. Kuntscher

We investigate the low temperature structural and electronic properties of the type-I clathrate Eu8Ga16Ge30 under pressure using x-ray powder diffraction (XRD), x-ray absorption near-edge structure (XANES) and x-ray magnetic circular…

Materials Science · Physics 2014-02-03 J. R. L. Mardegan , G. Fabbris , L. S. I. Veiga , C. Adriano , M. A. Avila , D. Haskel , C. Giles

Pressure-induced superconductivity and its relation to corresponding Hall coefficient (RH) have been reported for Bi2Te3, one of known topological insulators. A full phase diagram is presented which shows a complex dependence of the…

Superconductivity · Physics 2015-05-20 Chao Zhang , Liling Sun , Zhaoyu Chen , Xingjiang Zhou , Qi Wu , Wei Yi , Jing Guo , Xiaoli Dong , Zhongxian Zhao

Topological superconductivity with Majorana bound states, which are critical to implement nonabelian quantum computation, may be realized in three-dimensional semimetals with nontrivial topological feature, when superconducting transition…

In this work, we report evidence of pressure-induced changes in the crystal structure of Sr(IO3)2HIO3 connected to changes the coordination of the iodine atom and the of the configuration of HIO3 and IO3 units. The changes favor iodine…

We employ classical molecular dynamics simulations to investigate the molecular-level structure of water during the isothermal compression of hexagonal ice (I$h$) and low-density amorphous (LDA) ice at low temperatures. In both cases, the…

Chemical Physics · Physics 2018-07-11 Fausto Martelli , Nicolas Giovambattista , Salvatore Torquato , Roberto Car

Layered transition-metal trichalcogenides have become one of the research frontiers as two-dimensional magnets and candidate materials used for phase-change memory devices. Herein we report the high-pressure synchrotron X-ray diffraction…

Strongly Correlated Electrons · Physics 2019-06-03 Zhenhai Yu , Wei Xia , Kailang Xu , Ming Xu , Hongyuan Wang , Xia Wang , Na Yu , Zhiqiang Zou , Jinggeng Zhao , Lin Wang , Xiangshui Miao , Yanfeng Guo

The structural properties of Na2RuO3 under pressure are studied using density functional theory within the generalized gradient approximation (GGA). We found that one may expect a structural transition at ~ 3 GPa. This structure at the…

Strongly Correlated Electrons · Physics 2018-05-04 D. D. Gazizova , A. V. Ushakov , S. V. Streltsov

Understanding various macroscopic pressure-volume-temperature properties of materials on the atomistic level has always been an ambition for physicists and material scientists. Particularly, some materials such as zirconium tungstate…

Materials Science · Physics 2022-11-23 Ri He , Hongyu Wu , Yi Lu , Zhicheng Zhong

Much attention has been devoted to understanding the microscopic pathways of phase transition between two equilibrium condensed phases (such as liquids and solids). However, the microscopic pathways between non-equilibrium, non-diffusive…

Chemical Physics · Physics 2024-02-27 Gadha Ramesh , Ved Mahajan , Debasish Koner , Rakesh S. Singh

Polymers containing nitrogen have attracted much attention in connection with their application to high energy density materials (HEDMs), in which energy is inherent in the triple bond. It is an interesting question whether such polymerized…

Materials Science · Physics 2023-05-04 Peng Song , Mari Kawaguchi , Yuji Masubuchi , Kenji Oqmhula , Kousuke Nakano , Ryo Maezono , Kenta Hongo

Pressure not only provides a powerful way to tune the crystal structure of transition metal dichalcogenides (TMDCs) but also promotes the discovery of exotic electronic states and intriguing phenomena. Structural transitions from the…

Superconductivity · Physics 2026-01-13 Feng Xiao , Wen Lei , Wei Wang , Carmine Autieri , Xiaojun Zheng , Xing Ming , Jianlin Luo

Studying the effect of high pressure (exceeding 10 kbar) on the structure of solids allows to gain deeper insight in the mechanism governing crystal structure stability. Here we report a study on the high-pressure behaviour of zinc…

Materials Science · Physics 2020-04-08 Dominik Kurzydłowski , Anna Oleksiak , Sharad Babu Pillai , Prafulla K. Jha

Combining first-principles density functional method and crystal structure prediction techniques, we report a series of hexagonal two-dimensional (2D) transition metal borides (TMBs) including Sc2B2, Ti2B2, V2B2, Cr2B2, Y2B2, Zr2B2, and…

Materials Science · Physics 2018-10-17 Tao Bo , Peng-Fei Liu , Juping Xu , Junrong Zhang , Fangwei Wang , Bao-Tian Wang