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We combine density functional theory within the local density approximation, the quasiharmonic approximation, and vibrational density of states to calculate single crystal elastic constants, and bulk and shear moduli of diamond at…

Materials Science · Physics 2015-06-05 M. Núñez Valdez , K. Umemoto , R. M. Wentzcovitch

A first-principles method is presented to calculate elastic constants up to the fourth order of crystals with the cubic and hexagonal symmetries. The method relies on the numerical differentiation of the second Piola-Kirchhoff stress tensor…

Materials Science · Physics 2023-05-03 Abhiyan Pandit , Angelo Bongiorno

We present ab-initio calculations of the quasi-harmonic temperature dependent elastic constants. The isothermal elastic constants are calculated at each temperature as second derivatives of the Helmholtz free energy with respect to strain…

Materials Science · Physics 2021-09-29 Cristiano Malica , Andrea Dal Corso

A method is presented to calculate from first principles the higher-order elastic constants of a solid material. The method relies on finite strain deformations, a density functional theory approach to calculate the Cauchy stress tensor,…

Materials Science · Physics 2025-10-08 Ruvini Attanayake , Umesh C. Roy , Abhiyan Pandit , Angelo Bongiorno

We investigate the elastic and isotropic aggregate properties of ferromagnetic bcc iron as a function of temperature and pressure by computing the Helmholtz free energies for the volume-conserving strained structures using the…

Materials Science · Physics 2009-11-11 Xianwei Sha , R. E. Cohen

we present the temperature-dependent elastic constants of two ductile rare-earth intermetallic compounds YAg and YCu with CsCl-type B2 structure by using a first-principles approach. The elastic moduli as a function of temperature are…

Materials Science · Physics 2011-04-28 Wang Rui , Wang Shaofeng , Wu Xiaozhi , Yao Yin

We calculate the thermomechanical properties of $\alpha$-iron, and in particular its isothermal and adiabatic elastic constants, using first-principles total-energy and lattice-dynamics calculations, minimizing the quasi-harmonic…

Materials Science · Physics 2015-06-23 Daniele Dragoni , Davide Ceresoli , Nicola Marzari

We have investigated the finite temperature elastic properties of AlRE (RE=Y, Tb, Pr, Nd, Dy) with B2-type structures from first principles. The phonon free energy and thermal expansion is obtained from the quasiharmonic approach based on…

Materials Science · Physics 2011-11-08 Rui Wang , Shaofeng Wang , Xiaozhi Wu

This work represents the first chapter of a project on the foundations of first-principle calculations of the electron transport in crystals at finite temperatures. We are interested in the range of temperatures, where most electronic…

Computational Physics · Physics 2018-04-04 Thomas D. Kühne , Emil Prodan

Conventional methods to calculate the thermodynamics of crystals evaluate the harmonic phonon spectra and therefore do not work in frequent and important situations where the crystal structure is unstable in the harmonic approximation, such…

Statistical Mechanics · Physics 2009-11-13 P. Souvatzis , O. Eriksson , M. I. Katsnelson , S. P. Rudin

We calculate the temperature-dependent elastic constants of palladium, platinum, copper and gold within the quasi-harmonic approximation using a first-principles approach and evaluating numerically the second derivatives of the Helmholtz…

Materials Science · Physics 2021-09-22 Cristiano Malica , Andrea Dal Corso

We present a theoretical scheme to calculate the elastic constants of magnetic materials in the high-temperature paramagnetic state. Our approach is based on a combination of disordered local moments picture and ab initio molecular dynamics…

Materials Science · Physics 2016-08-24 Elham Mozafari , Nina Shulumba , Peter Steneteg , Björn Alling , Igor A. Abrikosov

Available information concerning the elastic moduli of refractory carbides at temperatures (T) of relevance for practical applications is sparse and/or inconsistent. We carry out ab initio molecular dynamics (AIMD) simulations at T = 300,…

Materials Science · Physics 2021-03-09 D. G. Sangiovanni , F. Tasnádi , T. Harrington , K. S. Vecchio , I. A. Abrikosov

Based on extended free energy of soft-matter quasicrystals and the variation principle on thermodynamic stability, this study reports the results on stability of the first kind of soft-matter quasicrystals. They are dependent only upon the…

Soft Condensed Matter · Physics 2019-11-26 Tian-You Fan , Zhi-Yi Tang

A tight-binding model is fit to first-principles calculations for copper that include structures distorted according to elastic constants and high-symmetry phonon modes. With the resulting model the first-principles-based phonon dispersion…

Materials Science · Physics 2009-11-07 Sven P. Rudin , M. D. Jones , C. W. Greeff , R. C. Albers

A general procedure to investigate the elastic response and calculate the elastic constants of stressed and unstressed materials through continuum field modeling, particularly the phase field crystal (PFC) models, is presented. It is found…

Materials Science · Physics 2018-05-09 Zi-Le Wang , Zhi-Feng Huang , Zhirong Liu

Using positional data from video-microscopy of a two-dimensional colloidal system and from simulations of hard discs we determine the wave-vector-dependent normal mode spring constants in the supercooled fluid and glassy state,…

Soft Condensed Matter · Physics 2012-10-26 Christian L. Klix , Florian Ebert , Fabian Weysser , Matthias Fuchs , Georg Maret , Peter Keim

A recent tight-binding scheme provides a method for extending the results of first principles calculations to regimes involving $10^2 - 10^3$ atoms in a unit cell. The method uses an analytic set of two-center, non-orthogonal tight-binding…

mtrl-th · Physics 2008-02-03 Michael J. Mehl , Dimitrios A. Papaconstantopoulos

We investigate the equation of state and elastic properties of nonmagnetic hcp iron at high pressures and high temperatures using the first principles linear response linear-muffin-tin-orbital method in the generalized-gradient…

Other Condensed Matter · Physics 2007-08-02 Xianwei Sha , R. E. Cohen

First principles calculations have given a new insight into the energies of point defects in many different materials, information which cannot be readily obtained from experiment. Most such calculation are done at zero Kelvin, with the…

Materials Science · Physics 2011-05-16 G. J. Ackland , T. P. C. Klaver , D. J. Hepburn
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