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Bulk-heterojunction (BHJ) non-fullerene organic solar cells prepared from sequentially deposited donor and acceptor layers (sq-BHJ) have recently been promising to be highly efficient, environmentally friendly, and compatible with large…

Photoionization by high-energy photons creates nonthermal electrons with a broad range of energies that heat and chemically transform the atmospheres of planets. The specifics of the interactions are notably different when the gas is atomic…

Earth and Planetary Astrophysics · Physics 2025-06-17 Antonio García Muñoz , Ewan Bataille

Carrier multiplication by singlet exciton fission enhances photovoltaic conversion efficiencies in organic solids. This decay of one singlet exciton into two triplet states promises to overcome the Shockley-Queisser limit as up to two…

Materials Science · Physics 2016-12-16 K. Kolata , S. Marquardt , N. W. Rosemann , A. Mager , A. Hansmann , U. Höfer , R. Berger , T. Breuer , G. Witte , S. Chatterjee

By means of first-principles methods we analyze the optical response of transparent dense sodium as a function of applied pressure. We discover an unusual kind of charge-transfer exciton that proceeds from the interstitial distribution of…

Materials Science · Physics 2015-05-18 Matteo Gatti , Ilya V. Tokatly , Angel Rubio

F\"orster theory describes electronic exciton energy migration in molecular assemblies as an incoherent hopping process between donor and acceptor molecules. The rate is expressed in terms of the overlap integral between donor fluorescence…

Chemical Physics · Physics 2018-10-17 Marco Schröter , Tõnu Pullerits , Oliver Kühn

We present a detailed model study of exciton transfer processes in donor-bridge-acceptor (DBA) systems. Using a model which includes the intermolecular Coulomb interaction and the coupling to a dissipative environment we calculate the phase…

Strongly Correlated Electrons · Physics 2009-11-11 Sabine Tornow , Ning-Hua Tong , Ralf Bulla

Unravelling the nature of energy transport in multi-chromophoric photosynthetic complexes is essential to extract valuable design blueprints for light-harvesting applications. Long-range exciton transport in such systems is facilitated by a…

Apparent recombination orders exceeding the value of two expected for bimolecular recombination have been reported for organic solar cells in various publications. Two prominent explanations are bimolecular losses with a carrier…

Soft Condensed Matter · Physics 2012-08-23 D. Rauh , C. Deibel , V. Dyakonov

A one-dimensional many-body model is established to mimic the charge distribution and dynamics in nonfullerene organic solar cells. Two essential issues are taken into account in the model: The alternating donor and acceptor structure and…

Materials Science · Physics 2018-12-05 Yao Yao

The Coulomb gap in a donor-acceptor model with finite charge transfer energy $\Delta$ describing the electronic system on the dielectric side of the metal-insulator transition is investigated by means of computer simulations on two- and…

Condensed Matter · Physics 2009-10-31 S. A. Basylko , P. J. Kundrotas , V. A. Onischouk , E. E. Tornau , A. Rosengren

We study the radiative decay, or fluorescence, of excitons in organic solar cells as a function of its geometrical parameters. Contrary to their non-radiative counterpart, fluorescence losses strongly depend on the environment. By properly…

Applied Physics · Physics 2017-10-04 Blaise Godefroid , Gregory Kozyreff

Coulomb bound electron-hole pairs, excitons, govern the optical properties of semi-conducting transition metal dichalcogenides like MoS$_2$ and WSe$_2$. We study optical transitions at the K-point for 2H homobilayer MoS$_2$ in Density…

Since the discovery of semiconducting monolayer transition metal dichalcogenides, a variety of experimental and theoretical studies have been carried out seeking to understand the intrinsic exciton population decay and valley relaxation…

Mesoscale and Nanoscale Physics · Physics 2016-05-04 Galan Moody , John Schaibley , Xiaodong Xu

Actively tunable photonic devices are vital for next-generation optoelectronics requiring rapid switching and high bandwidth. Although organic optoelectronic devices have found wide application, their use as optical modulators has been…

We discuss coherent exciton-polariton states in long molecular chains that are formed due to the interaction of molecular excitations with both vacuum photons and surface excitations of the neighboring reflecting substrate. The resonance…

Other Condensed Matter · Physics 2009-11-13 Yu. N. Gartstein , V. M. Agranovich

The high flexibility of organic molecules offers great potential for designing the optical properties of light-active materials for the next generation of optoelectronic and photonic applications. However, despite successful implementations…

Despite the weak, van-der-Waals interlayer coupling, photoinduced charge transfer vertically across atomically thin interfaces can occur within surprisingly fast, sub-50fs timescales. Early theoretical understanding of the charge transfer…

We investigate electron transfer processes in donor-acceptor systems with a coupling of the electronic degrees of freedom to a common bosonic bath. The model allows to study many-particle effects and the influence of the local Coulomb…

Strongly Correlated Electrons · Physics 2007-05-23 Sabine Tornow , Ning-Hua Tong , Ralf Bulla

Lateral heterostructures built of monolayers of transition metal dichalcogenides (TMDs) are characterized by a thin 1D interface exhibiting a large energy offset. Recently, the formation of spatially separated charge-transfer (CT) excitons…

Mesoscale and Nanoscale Physics · Physics 2025-09-03 Roberto Rosati , Sai Shradha , Julian Picker , Andrey Turchanin , Bernhard Urbaszek , Ermin Malic

Hot carrier solar cells promise theoretical power conversion efficiencies far beyond the single junction limit. However, practical implementations of hot carrier solar cells have lagged far behind those theoretical predictions. Reciprocity…