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We present a fast and approximate multifrontal solver for large-scale sparse linear systems arising from finite-difference, finite-volume or finite-element discretization of high-frequency wave equations. The proposed solver leverages the…

Mathematical Software · Computer Science 2021-10-19 Yang Liu , Pieter Ghysels , Lisa Claus , Xiaoye Sherry Li

We model the Hartree-exchange-correlation potential of Kohn-Sham density-functional theory adopting a novel strategy inspired by the strictly-correlated-electrons limit and relying on the exact decomposition of the potential based on the…

Chemical Physics · Physics 2024-09-09 Sara Giarrusso , Federica Agostini

In this work, we have used the exchange-only optimized effective potential in the self-consistent calculations of the density functional Kohn-Sham equations for simple metal clusters in stabilized jellium model with self-compression. The…

Atomic and Molecular Clusters · Physics 2009-11-11 M. Payami

This paper derives and demonstrates a new, purely density-based ab initio approach for calculation of the energies and properties of many-electron systems. It is based upon the discovery of relationships that govern the "mechanics" of the…

Chemical Physics · Physics 2024-09-04 James C. Ellenbogen

We present a real-space formulation for coarse-graining Kohn-Sham Density Functional Theory that significantly speeds up the analysis of material defects without appreciable loss of accuracy. The approximation scheme consists of two steps.…

Computational Physics · Physics 2015-06-11 Phanish Suryanarayana , Kaushik Bhattacharya , Michael Ortiz

Hamiltonian Truncation Methods are a useful numerical tool to study strongly coupled QFTs. In this work we present a new method to compute the exact corrections, at any order, in the Hamiltonian Truncation approach presented by Rychkov et…

High Energy Physics - Theory · Physics 2016-05-25 J. Elias-Miro , M. Montull , M. Riembau

We present an algorithm to reduce the computational effort for the multiplication of a given matrix with an unknown column vector. The algorithm decomposes the given matrix into a product of matrices whose entries are either zero or integer…

Information Theory · Computer Science 2020-02-28 Ralf R. Müller , Bernhard Gäde , Ali Bereyhi

An algorithm for first-principles electronic structure calculations having a computational cost which scales linearly with the system size is presented. Our method exploits the real-space localization of the density matrix, and in this…

mtrl-th · Physics 2016-09-07 E. Hernandez , M. J. Gillan

We devise an efficient practical method for computing the Kohn-Sham exchange-correlation potential corresponding to a Hartree-Fock electron density. This potential is almost indistinguishable from the exact-exchange optimized effective…

Chemical Physics · Physics 2013-07-09 Ilya G. Ryabinkin , Alexei A. Kananenka , Viktor N. Staroverov

We present a new class of exponential integrators for ordinary differential equations. They are locally exact, i.e., they preserve the linearization of the original system at every point. Their construction consists in modifying existing…

Numerical Analysis · Mathematics 2011-04-08 Jan L. Cieśliński

Solving the many-electron problem, even approximately, is one of the most challenging and simultaneously most important problems in contemporary condensed matter physics with various connections to other fields. The standard approach is to…

Strongly Correlated Electrons · Physics 2026-04-10 Jonas B. Profe , Jakša Vučičević , P. Peter Stavropoulos , Malte Rösner , Roser Valentí , Lennart Klebl

The large-$Z$ asymptotic expansion of atomic energies has been useful in determining exact conditions for corrections to the local density approximation in density functional theory. The correction for exchange is fit well with a leading $Z…

Chemical Physics · Physics 2023-04-13 Nathan Argaman , Jeremy Redd , Antonio C. Cancio , Kieron Burke

Semi-local density functionals for the exchange-correlation energy of electrons are extensively used as it produce realistic and accurate results for finite and extended systems. The choice of techniques play crucial role in constructing…

Materials Science · Physics 2017-11-01 Subrata Jana , Prasanjit Samal

Most density functionals have been developed by imposing the known exact constraints on the exchange-correlation energy, or by a fit to a set of properties of selected systems, or by both. However, accurate modeling of the conventional…

Materials Science · Physics 2016-08-24 Jianmin Tao , Yuxiang Mo

We present a novel algorithm which can overcome the drawbacks of the conventional linear scaling method with minimal computational overhead. This is achieved by introducing additional constraints, thus eliminating the redundancy of the…

Materials Science · Physics 2015-06-25 Eiji Tsuchida

We present a fast direct solver for structured linear systems based on multilevel matrix compression. Using the recently developed interpolative decomposition of a low-rank matrix in a recursive manner, we embed an approximation of the…

Numerical Analysis · Mathematics 2014-04-10 Kenneth L. Ho , Leslie Greengard

As a proof of principle, self-consistent Kohn--Sham calculations are performed with the exact exchange-correlation functional. Finding the exact functional for even one trial density requires solving the interacting Schr\"odinger equation…

Chemical Physics · Physics 2014-07-14 Lucas O. Wagner , Thomas E. Baker , E. M. Stoudenmire , Kieron Burke , Steven R. White

We present a new density-functional method of the self-consistent electronic-structure calculation which does not exploit any local density approximations (LDA). We use the exchange-correlation energy which consists of the exact exchange…

Statistical Mechanics · Physics 2009-10-30 Takao Kotani

While several numerical techniques are available for predicting the dynamics of non-Markovian open quantum systems, most struggle with simulations for very long memory and propagation times, e.g., due to superlinear scaling with the number…

Quantum Physics · Physics 2025-05-01 Moritz Cygorek , Jonathan Keeling , Brendon W. Lovett , Erik M. Gauger

It was shown that the conventional Fock matrix calculation, which using stored non-zero two-electron integrals, density prescreening, and data compression methods possesses the linear scaling property with respect to the problem size. This…

Chemical Physics · Physics 2019-11-12 Alexander V. Mitin