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In quantum mechanics, the Wigner function $\rho_W(\textbf{r},\textbf{p})$ serves as a phase-space representation, capturing information about both the position $\textbf{r}$ and momentum $\textbf{p}$ of a quantum system. The Wigner function…

Quantum Physics · Physics 2024-03-20 Reiko Yamada , Antoine Reserbat-Plantey , Eloy Piñol , Maciej Lewenstein

Tight-binding models for ultracold atoms in optical lattices can be properly defined by using the concept of maximally localized Wannier functions for composite bands. The basic principles of this approach are reviewed here, along with…

Quantum Gases · Physics 2016-03-30 Michele Modugno , Julen Ibañez-Azpiroz , Giulio Pettini

To obtain a local description from highly accurate density functional theory codes that are based on modified plane wave bases, a transformation to a local orthonormal Wannier function basis is required. In order to do so while enforcing…

Materials Science · Physics 2024-03-20 K. Koepernik , O. Janson , Yan Sun , J. van den Brink

The Wannier-Stark ladder (WSL) is a basic concept, supporting periodic oscillation, widely used in many areas of physics. In this paper, we investigate the formations of WSL in generalized systems, including strongly correlated and…

Strongly Correlated Electrons · Physics 2025-01-27 H. P. Zhang , Z. Song

We derive a multi-band formulation of the orbital magnetization in a normal periodic insulator (i.e., one in which the Chern invariant, or in 2d the Chern number, vanishes). Following the approach used recently to develop the single-band…

Materials Science · Physics 2009-11-11 Davide Ceresoli , T. Thonhauser , David Vanderbilt , R. Resta

When the first four spectral moments are considered, spectral features missing in standard Kohn-Sham (KS) density-functional theory (DFT), such as upper and lower Hubbard bands, as well as spectral satellite peaks, can be described, and the…

Strongly Correlated Electrons · Physics 2023-01-13 Frank Freimuth , Stefan Blügel , Yuriy Mokrousov

We present a new scheme for the construction of highly localized lattice Wannier functions. The approach is based on a heuristic criterion for localization and takes the symmetry constraints into account from the start. We compare the local…

Materials Science · Physics 2009-10-31 Jorge Iniguez , Alberto Garcia , J. M. Perez-Mato

In the framework of a recently reported linear-scaling method for density-functional-pseudopotential calculations, we investigate the use of localized basis functions for such work. We propose a basis set in which each local orbital is…

mtrl-th · Physics 2009-10-30 E. Hernandez , M. J. Gillan , C. M. Goringe

Koopmans-compliant functionals provide an orbital-density-dependent framework for an accurate evaluation of spectral properties; they are obtained by imposing a generalized piecewise-linearity condition on the total energy of the system…

Materials Science · Physics 2022-07-06 Riccardo De Gennaro , Nicola Colonna , Edward Linscott , Nicola Marzari

Using the newly developed VASP2WANNIER90 interface we have constructed maximally localized Wannier functions (MLWFs) for the e_g states of the prototypical Jahn-Teller magnetic perovskite LaMnO3 at different levels of approximation for the…

Strongly Correlated Electrons · Physics 2015-06-03 C. Franchini , R. Kovacik , M. Marsman , S. Sathyanarayana Murthy , J. He , C. Ederer , G. Kresse

In pursuit of a minimal basis for systems with non-ideal bond angles, in this work we try to pinpoint the exact orientation of the major overlapping orbitals along the nearest neighbouring coordination segments in a given system such that…

Materials Science · Physics 2022-09-14 Joydev De , Sujith N S , Manoar Hossain , Joydeep Bhattacharjee

Forty-five years after the point de d\'epart [1] of density functional theory, its applications in chemistry and the study of electronic structures keep steadily growing. However, the precise form of the energy functional in terms of the…

Chemical Physics · Physics 2019-10-29 Philippe Blanchard , José M. Gracia-Bondía , Joseph C. Várilly

An ab initio Hartree-Fock approach aimed at directly obtaining the localized orthogonal orbitals (Wannier functions) of a crystalline insulator is described in detail. The method is used to perform all-electron calculations on the ground…

Condensed Matter · Physics 2009-10-30 Alok Shukla , Michael Dolg , Peter Fulde , Hermann Stoll

Modulation spaces were originally introduced by Feichtinger in 1983. Since the 2000s there have been thousands of contributions using them as correct framework; they range from PDEs, pseudodifferential operators, quantum mechanics, signal…

Analysis of PDEs · Mathematics 2024-03-27 Elena Cordero , Gianluca Giacchi

An energy functional for orbital based $O(N)$ calculations is proposed, which depends on a number of non orthogonal, localized orbitals larger than the number of occupied states in the system, and on a parameter, the electronic chemical…

mtrl-th · Physics 2016-09-07 Jeongnim Kim , Francesco Mauri , Giulia Galli

We investigate the localization properties of gapped periodic quantum systems, modeled by a periodic or covariant family of projectors, as e.g. the orthogonal projectors on the occupied orbitals at fixed crystal momentum for a gas of…

Mesoscale and Nanoscale Physics · Physics 2017-01-02 D. Monaco , G. Panati , A. Pisante , S. Teufel

Bands with non-trivial topological indices have a topological obstruction preventing them from being represented by exponentially localized Wannier states. Here, we propose a procedure to construct exponentially localized Wannier functions…

Mesoscale and Nanoscale Physics · Physics 2025-05-29 Trey Cole , David Vanderbilt

An ab initio Wannier-function-based approach to electronic ground-state calculations for crystalline solids is outlined. In the framework of the linear combination of atomic orbitals method the infinite character of the solid is rigorously…

Condensed Matter · Physics 2009-10-31 Martin Albrecht , Alok Shukla , Michael Dolg , Peter Fulde , Hermann Stoll

The Wegner orbital model is a class of random operators introduced by Wegner to model the motion of a quantum particle with many internal degrees of freedom (orbitals) in a disordered medium. We consider the case when the matrix potential…

Mathematical Physics · Physics 2017-09-22 Jeffrey Schenker , Ron Peled , Mira Shamis , Sasha Sodin

The method recently developed to include Van der Waals interactions in the Density Functional Theory by using the Maximally-Localized Wannier functions, is improved and extended to the case of atoms and fragments weakly bonded (physisorbed)…

Other Condensed Matter · Physics 2009-11-13 Pier Luigi Silvestrelli , Karima Benyahia , Sonja Grubisic Francesco Ancilotto , Flavio Toigo