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We explore the elastic behavior of a wormlike chain under compression in terms of exact solutions for the associated probability densities. Strikingly, the probability density for the end-to-end distance projected along the applied force…

Soft Condensed Matter · Physics 2019-11-11 Christina Kurzthaler , Thomas Franosch

Using a finite size scaling form for reunion probability, we show numerically the existence of a binding-unbinding transition for Directed polymers with random interaction. The cases studied are (A1) two chains in 1+1 dimensions, (A2) two…

Condensed Matter · Physics 2009-10-28 Sutapa Mukherji , Somendra M. Bhattacharjee , A. Baumgärtner

The influence of monomer-monomer interactions on the scaling exponents and shape characteristics of a single polymer chain in a selective solvent is investigated using Langevin dynamics simulations. By systematically increasing the…

Soft Condensed Matter · Physics 2025-04-01 K. Haydukivska

When the local intrinsic stiffness of a polymer chain varies over a wide range, one can observe both a crossover from rigid-rod-like behavior to (almost) Gaussian random coils and a further crossover towards self-avoiding walks in good…

Soft Condensed Matter · Physics 2015-03-17 Hsiao-Ping Hsu , Wolfgang Paul , Kurt Binder

Although both RNA and proteins have densely packed native structures, chain organizations of these two biopolymers are fundamentally different. Motivated by the recent discoveries in chromatin folding that interphase chromosomes have…

Soft Condensed Matter · Physics 2016-12-28 Lei Liu , Changbong Hyeon

The adsorption of polydisperse ideal polymer chains is shown to be sensitive to the large N tail of the distribution of chains. If and only if the number of chains decays more slowly than exponentially then there is an adsorption transition…

Soft Condensed Matter · Physics 2009-10-31 Richard P. Sear

Polymer chains with hard-core interaction on a two-dimensional lattice are modeled by directed random walks. Two models, one with intersecting walks (IW) and another with non-intersecting walks (NIW) are presented, solved and compared. The…

Condensed Matter · Physics 2016-08-31 G. Forgacs , K. Ziegler

We present Monte Carlo simulations of semidilute solutions of long self-attracting chain polymers near their Ising type critical point. The polymers are modeled as monodisperse self-avoiding walks on the simple cubic lattice with attraction…

Soft Condensed Matter · Physics 2009-10-30 H. Frauenkron , P. Grassberger , HLRZ Juelich , Germany

Through extensive Monte Carlo simulations, we systematically study the effect of chain stiffness on the packing ability of linear polymers composed of hard spheres in extremely confined monolayers, corresponding effectively to 2D films.…

We investigate mutual local chain order in systems of fully flexible polymer melts in a simple generic bead-spring model. The excluded-volume interaction together with the connectivity leads to local ordering effects which are independent…

Soft Condensed Matter · Physics 2015-06-25 Roland Faller , Mathias Puetz , Florian Mueller-Plathe

We present a new simulation technique to study systems of polymers functionalized by reactive sites that bind/unbind forming reversible linkages. Functionalized polymers feature self-assembly and responsive properties that are unmatched by…

Soft Condensed Matter · Physics 2018-04-18 Bernardo Oyarzún , Bortolo Matteo Mognetti

The interplay of topological constraints, excluded volume interactions, persistence length and dynamical entanglement length in solutions and melts of linear chains and ring polymers is investigated by means of kinetic Monte Carlo…

Statistical Mechanics · Physics 2009-10-31 M. Mueller , J. P. Wittmer , J. -L. Barrat

The conformational and dynamical properties of active ring polymers are studied by numerical simulations. The two-dimensionally confined polymer is modeled as a closed bead-spring chain, driven by tangential forces, put in contact with a…

Soft Condensed Matter · Physics 2024-06-03 A. Lamura

Solutions of semiflexible polymers confined by repulsive planar walls are studied by density functional theory and Molecular Dynamics simulations, to clarify the competition between the chain alignment favored by the wall and the depletion…

Soft Condensed Matter · Physics 2016-05-25 Sergei A. Egorov , Andrey Milchev , Peter Virnau , Kurt Binder

The paper presents a short overview of the theoretical, numerical and experimental works on the critical behavior of a dilute polymer solution of long-flexible polymer chains confined in semi-infinite space restricted by a surface or in a…

Soft Condensed Matter · Physics 2018-01-08 Zoryana Usatenko , Krzysztof S. Danel

Confined in two dimensional planes, polymer chains comprising dense monolayer solution are segregated from each other due to topological interaction. Although the segregation is inherent in two dimensions (2D), the solution may display…

Soft Condensed Matter · Physics 2022-09-26 Lei Liu , Changbong Hyeon

Evaluating accessible conformational space is computationally expensive and thermal motions are partly neglected in computer models of molecular interactions. This produces error into the estimates of binding strength. We introduce a method…

Quantitative Methods · Quantitative Biology 2016-12-13 Riku Hakulinen , Santeri Puranen

Mean-field techniques provide a rather accurate description of single-chain conformations in spatially inhomogeneous polymer systems containing interfaces or surfaces. Intermolecular correlations, however, are not described by the…

Soft Condensed Matter · Physics 2009-11-13 Martin Hömberg , Marcus Müller

A model of two interacting polymer chains has been proposed to study the effect of penetration of one chain in to the other. We show that small chain penetrates more in comparison to the long chain. We also find a condition in which both…

Statistical Mechanics · Physics 2009-10-31 Sanjay Kumar

We study the behavior of self avoiding polymers in a background of vertically aligned rods that are either frozen into random positions or free to move horizontally. We find that in both cases the polymer chains are highly elongated, with…

Soft Condensed Matter · Physics 2009-11-10 J. M. Deutsch , M. Warkentin