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Electrochemical insertion-deintercalation reactions are typically associated with significant change of molar volume of the host compound. This strong coupling between ionic currents and strains underpins image formation mechanisms in…

Materials Science · Physics 2015-05-18 A. N. Morozovska , E. A. Eliseev , N. Balke , S. V. Kalinin

Electrochemistry is the underlying mechanism in a variety of energy conversion and storage systems, and it is well known that the composition, structure, and properties of electrochemical materials near active interfaces often deviates…

Materials Science · Physics 2018-02-07 Ahmad Eshghinejad , Ehsan Nasr Esfahani , Chihou Lei , Jiangyu Li

Dynamic Electrochemical Strain Microscopy (ESM) response of mixed ionic-electronic conductors is analysed in the framework of the Thomas-Fermi screening theory and Vegard law with accounting of the steric effects. The emergence of dynamic…

Materials Science · Physics 2014-11-05 O. V. Varenyk , M. V Silibin , D. A Kiselev , E. A. Eliseev , S. V. Kalinin , A. N. Morozovska

The three scanning electron microscope diffraction based techniques of electron channelling patterns (ECPs), electron channelling contrast imaging (ECCI), and electron back scatter diffraction (EBSD) are reviewed. The dynamical diffraction…

Materials Science · Physics 2019-04-12 AJ Wilkinson , PB Hirsch

Electromechanical response of solids underpins image formation mechanism of several scanning probe microscopy techniques including the piezoresponse force microscopy (PFM) and electrochemical strain microscopy (ESM). While the theory of…

Electromechanical coupling is ubiquitous in nature and underpins the functionality of materials and systems as diverse as ferroelectric and multiferroic materials, electrochemical devices, and biological systems, and strain-based scanning…

Materials Science · Physics 2014-04-10 Qian Nataly Chen , Yun Ou , Feiyue Ma , Jiangyu Li

A universal challenge facing the development of electrochemical materials is our lack of understanding of physical and chemical processes at local length scales in 10-100 nm regime, and acquiring this understanding requires a new generation…

Mesoscale and Nanoscale Physics · Physics 2017-10-31 Ehsan Nasr Esfahani , Ahmad Eshghinejad , Yun Ou , Jinjin Zhao , Stuart Adler , Jiangyu Li

Scanning transmission electron microscopy (STEM) has advanced rapidly in the last decade thanks to the ability to correct the major aberrations of the probe forming lens. Now atomic-sized beams are routine, even at accelerating voltages as…

Electronic conduction pathways in dielectric thin films are explored using automated experiments in scanning probe microscopy (SPM). Here, we use large field of view scanning to identify the position of localized conductive spots and…

Coherent spin resonance methods, such as nuclear magnetic resonance and electron spin resonance spectroscopy, have led to spectrally highly sensitive, non-invasive quantum imaging techniques. Here, we propose a pump-probe spin resonance…

Quantum Physics · Physics 2024-12-02 Philipp Haslinger , Stefan Nimmrichter , Dennis Rätzel

The electrochemical processes in energy storage materials are generally linked with changes of molar volume of the host compound. Here, the frequency dependent strain response of 1D electrochemically active systems to periodic electric bias…

Materials Science · Physics 2015-05-18 A. N. Morozovska , E. A. Eliseev , S. V. Kalinin

Electron spin resonance (ESR) spectroscopy in scanning tunneling microscopy (STM) has enabled probing the electronic structure of single magnetic atoms and molecules on surfaces with unprecedented energy resolution, as well as demonstrating…

The integration of scanning tunneling microscopy (STM) and electron spin resonance (ESR) spectroscopy has emerged as a powerful and innovative tool for discerning spin excitations and spin-spin interactions within atoms and molecules…

Mesoscale and Nanoscale Physics · Physics 2024-11-04 Lyuzhou Ye , Xiao Zheng , Xin Xu

Scanning Transmission Electron Microscopy (STEM) has become the main stay for materials characterization on atomic level, with applications ranging from visualization of localized and extended defects to mapping order parameter fields. In…

Instrumentation and Detectors · Physics 2019-01-15 Xin Li , Ondrej Dyck , Sergei V. Kalinin , Stephen Jesse

Scanning electron microscopy (SEM), a century-old technique, is today a ubiquitous method of imaging the surface of nanostructures. However, most SEM detectors simply count the number of secondary electrons from a material of interest, and…

Piezoresponse Force Microscopy (PFM) and Electrochemical Strain Microscopy (ESM) are two related techniques that have had considerable success in nano-scale probing of functional material properties. Both measure the strain of the sample in…

Mesoscale and Nanoscale Physics · Physics 2015-06-18 Roger Proksch

Strong coupling among external voltage, electrochemical potentials, concentrations of electronic and ionic species, and strains is a ubiquitous feature of solid state mixed ionic-electronic conductors (MIECs), the materials of choice in…

Materials Science · Physics 2015-05-20 A. N. Morozovska , E. A. Eliseev , A. K. Tagantsev , S. L. Bravina , Long-Qing Chen , S. V. Kalinin

Reading and manipulating the spin status of single magnetic molecules is of paramount importance both for applicative and fundamental purposes. The possibility to combine Electron Spin Resonance (ESR) and Scanning Tunnelling Microscopy…

Instrumentation and Detectors · Physics 2016-11-15 Paolo Messina , Paolo Sigalotti , Lorenzo Lenci , Matteo Mannini , Stefano Prato , Paolo Pittana , Dante Gatteschi

The rapid development of nanoscience and nanotechnology in the last two decades was stimulated by the emergence of scanning probe microscopy (SPM) techniques capable of accessing local material properties, including transport, mechanical,…

Despite the widespread use of Scanning Transmission Electron Microscopy (STEM) for observing the structure of materials at the atomic scale, a detailed understanding of some relevant electron beam damage mechanisms is limited. Recent…

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