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Strong coupling among external voltage, electrochemical potentials, concentrations of electronic and ionic species, and strains is a ubiquitous feature of solid state mixed ionic-electronic conductors (MIECs), the materials of choice in…

Materials Science · Physics 2015-05-20 A. N. Morozovska , E. A. Eliseev , A. K. Tagantsev , S. L. Bravina , Long-Qing Chen , S. V. Kalinin

Mixed ionic-electronic conductors host tightly coupled interactions among mobile ions, electronic charges, and the polymer matrix, giving rise to complex multimodal responses spanning electrical, mechanical, and morphological…

In this paper we develop an analytical framework for the study of electrochemical impedance of mixed ionic and electronic conductors (MIEC). The framework is based on first-principles and it features the coupling of electrochemical…

Chemical Physics · Physics 2017-08-23 Francesco Ciucci , Yong Hao , David G. Goodwin

Dynamic Electrochemical Strain Microscopy (ESM) response of mixed ionic-electronic conductors is analysed in the framework of the Thomas-Fermi screening theory and Vegard law with accounting of the steric effects. The emergence of dynamic…

Materials Science · Physics 2014-11-05 O. V. Varenyk , M. V Silibin , D. A Kiselev , E. A. Eliseev , S. V. Kalinin , A. N. Morozovska

The response of ionic solutions to time-varying electric fields, quantified by a frequency-dependent conductivity, is essential in many electrochemical applications. Yet, it constitutes a challenging problem due to the combined effect of…

Soft Condensed Matter · Physics 2026-04-15 Haggai Bonneau , Yael Avni , David Andelman , Henri Orland

I present a theory of electron dynamics in semiconductors with slowly varying composition. I show that the frequency-dependent conductivity, required for the description of transport and optical properties, can be obtained from a knowledge…

Condensed Matter · Physics 2016-08-31 Michael R. Geller

We use a frequency-dependent electro-optic technique to measure the hole mobility in small molecule organic semiconductors, such as 6,13 bis(triisopropylsilylethynyl)-pentacene. Measurements are made on semiconductor films in bottom gate,…

Materials Science · Physics 2012-12-20 Emily G. Bittle , Joseph W. Brill , Joseph P. Straley

A simple model to describe Mixed Ionic Electronic Conductors (MIEC) in terms of standard semiconductor physics is described. This model allows to understand defect equilibrium and charge transport at ideal heterojunctions between materials…

Materials Science · Physics 2013-07-26 J. Roqueta , A. Apostolidis , J. Chaigneau , R. Moreno , J. Zapata , M. Burriel , J. Santiso

We report the theory of the \emph{dynamical response of current fluctuations} of a photo-excited conductor. We have performed the calculation for a coherent conductor described by arbitrary energy-dependent transmissions and for arbitrary…

Mesoscale and Nanoscale Physics · Physics 2011-11-10 Julien Gabelli , Bertrand Reulet

We observed qualitatively dissimilar frequency dependence of negative capacitive response under high charge injection in two sets of junction diodes which are functionally different from each other i.e. electroluminescent diodes and…

Mesoscale and Nanoscale Physics · Physics 2014-09-29 Kanika Bansal , Mohamed Henini , Marzook S. Alshammari , Shouvik Datta

Results of DC and frequency dependent conductivity in the quantum limit, i.e. hw > kT, for a broad range of dopant concentrations in nominally uncompensated, crystalline phosphorous doped silicon and amorphous niobium-silicon alloys are…

Disordered Systems and Neural Networks · Physics 2009-11-10 E. Helgren , N. P. Armitage , G. Gruner

Electric field dynamics at a positive ion imbedded in an electron gas is considered using a semiclassical description. The dependence of the field autocorrelation function on charge number is studied for strong ion-electron coupling via MD…

Statistical Mechanics · Physics 2009-11-07 James Dufty , Ilya Pogorelov , Bernard Talin , Annette Calisti

The interplay between electrochemical surface charges and bulk ferroelectricity in thin films gives rise to a continuum of coupled ferro-ionic states. These states are exquisitely sensitive to chemical and electric conditions at the…

Materials Science · Physics 2017-05-24 Anna N. Morozovska , Eugene A. Eliseev , Nicholas V. Morozovsky , Sergei V. Kalinin

Dynamic conductivity of the one-dimensional ion conductor is investigated at different values of the interaction constant between particles and the modulating field. The consideration is based on the hard-core boson lattice model.…

Strongly Correlated Electrons · Physics 2017-02-13 I. V. Stasyuk , R. Ya. Stetsiv

Functional properties of mixed ionic electronic conductors (MIECs) can be radically modified by (de)insertion of mobile charged defects. A complete control of this dynamic behaviour has multiple applications in a myriad of fields including…

The coloration mechanisms in electrochromic (EC) systems can be probed by comparing the dynamics of the electrical and optical responses. In this paper, the linear frequency-dependent electrical and optical responses of an amorphous…

Applied Physics · Physics 2021-02-02 Edgar A. Rojas-González , Gunnar A. Niklasson

The dielectric response and structural properties of finite-temperature electron liquids are central to accurately describing the physical behavior of electronic systems. This study presents a robust analytical model for the static…

Plasma Physics · Physics 2026-03-19 Chengliang Lin , Yong Hou , Jianmin Yuan , Yong Wu , Jianguo Wang

The frequency-dependent shot noise in long and narrow mesoscopic diffusive contacts is numerically calculated. The case of arbitrarily strong electron-electron scattering and zero temperature of electrodes is considered. For all voltages,…

Mesoscale and Nanoscale Physics · Physics 2009-10-31 K. E. Nagaev

Pattern forming instabilities induced by ultralow frequency sinusoidal voltages were studied in a rod-like nematic liquid crystal by microscopic observations and simultaneous electric current measurements. Two pattern morphologies,…

Soft Condensed Matter · Physics 2014-09-04 Peter Salamon , Nandor Eber , Alexei Krekhov , Agnes Buka

The transient behaviour of organic electrochemical transistors (OECT) is complex due to mixed ionic-electronic properties that play a central role in bioelectronics, sensing and neuromorphic applications. We investigate the impedance…

Materials Science · Physics 2024-08-06 Juan Bisquert , Scott T. Keene
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