Related papers: Carbon-Chain Species in Warm-up Models
Small hydrocarbons, such as C2H, C3H and C3H2 are more abundant in photo-dissociation regions (PDRs) than expected based on gas-phase chemical models. To explore the hydrocarbon chemistry further, we observed a key intermediate species, the…
The cosmic abundance of hydrides depends critically on high-energy UV, X-ray, and particle irradiation. Here we study hydrides in star-forming regions where irradiation by the young stellar object can be substantial, and density and…
In an effort to further our interest in understanding basic chemistry of interstellar molecules, we carry out here an extensive investigation of the stabilities of interstellar carbon chains; Cn, H2Cn, HCnN and CnX (X=N, O, Si, S, H, P, H-,…
Helium rich subdwarf O stars (sdOs) are hot compact stars in a pre-white dwarf evolutionary state. Most of them have effective temperatures and surface gravities in the range Teff = 40,000-50,000 K and log g = 5.5-6.0. Their atmospheres are…
This paper presents the third in a series of single-dish studies of molecular abundances in the envelopes around a large sample of 18 low-mass pre- and protostellar objects. It focuses on typical grain mantle products and organic molecules,…
Observations of the atomic and molecular line emission associated with jets and outflows emitted by young stellar objects can be used to trace the various evolutionary stages they pass through as they evolve to become main sequence stars.…
We address disequilibrum abundances of some simple molecules in the atmospheres of solar composition brown dwarfs and self-luminous extrasolar giant planets using a kinetics-based 1D atmospheric chemistry model. Our approach is to use the…
Recent radio astronomical observations have revealed that HC$_{5}$N, the second shortest cyanopolyyne (HC$_{2n+1}$N), is abundant around some massive young stellar objects (MYSOs), which is not predicted by classical carbon-chain chemistry.…
We surveyed 81 dense molecular cores associated with regions of massive star formation and Sgr A in the 5_{05}-4_{04} and 10_{010}-9_{09} lines of HNCO. Line emission was detected towards 57 objects. Selected subsamples were also observed…
We aim to investigate the chemistry and gas phase abundance of HNCO and the variation of the HNCO/CS abundance ratio as a diagnostic of the physics and chemistry in regions of massive star formation. A numerical-chemical model has been…
A new chemical model is presented for the carbon-rich circumstellar envelope of the AGB star IRC+10216. The model includes shells of matter with densities that are enhanced relative to the surrounding circumstellar medium. The chemical…
No statistical study of COMs toward a large sample of high-mass protostars with ALMA has been carried out so far. We aim to study six N-bearing species: CH$_3$CN, HNCO, NH$_2$CHO, C$_2$H$_5$CN, C$_2$H$_3$CN and CH$_3$NH$_2$ in a large…
OH231.8+4.2 is a well studied O-rich CSE around an intermediate-mass evolved star that displays bipolar molecular outflows accelerated up to 400 km/s. OH231 also presents an exceptional molecular richness probably due to shock-induced…
We conducted observations of multiple HC3N (J = 10-9, 12-11, and 16-15) lines and the N2H+ (J = 1-0) line toward a large sample of 61 ultracompact (UC) H II regions, through the Institutde Radioastronomie Millmetrique 30 m and the Arizona…
The observational detection of some metastable isomers in the interstellar medium with abundances comparable to those of the most stable isomer, or even when the stable isomer is not detected, highlights the importance of non-equilibrium…
We study the physical properties and molecular excitation of the different warm gas components found in the protoplanetary nebula CRL 618. We revise our previous Herschel/HIFI observations, which consist of several 12CO and 13CO lines in…
We present ISO observations of several H2 pure-rotational lines (from S(0) to S(5)) towards a sample of 16 molecular clouds distributed along the central ~ 500 pc of the Galaxy. We also present C18O and 13CO J=1->0 and J=2->1 observations…
We report on molecular abundances and distributions in a starless dense core L492. We have found that the abundances of carbon-chain molecules such as CCS, C$_{3}$S, HC$_{3}$N, HC$_{5}$N, and HC$_{7}$N are comparable to those in chemically…
We investigate chemistry in the compression layer behind the interstellar shock waves, where molecular cloud formation starts. We perform three-dimensional magnetohydrodynamics simulations of converging flows of atomic gas with shock…
Our automated reaction discovery program, AutoMeKin, has been utilized to investigate the formation of glycolonitrile (HOCH$_{2}$CN) in the gas phase under the low temperatures of the interstellar medium (ISM). The feasibility of a proposed…