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We present the rare existence of d5 off-centering, weak ferroelectric polarization and demonstrate its correlation with observed magnetoelectric (ME) properties in the G type (TN~210 K) antiferromagnet Fe2TeO6 (FTO) compound. The origin of…

We report on optical spectroscopy on the lacunar spinels GaV$_4$S$_8$ and GeV$_4$S$_8$ in the spectral range from 100 to 23000 cm$^{-1}$ and for temperatures from 5 to 300 K. These multiferroic spinel systems reveal Jahn-Teller driven…

Strongly Correlated Electrons · Physics 2017-10-06 S. Reschke , F. Mayr , Zhe Wang , P. Lunkenheimer , W. Li , D. Szaller , S. Bordács , I. Kézsmárki , V. Tsurkan , A. Loidl

CaFe2O4 is a highly anisotropic antiferromagnet reported to display two spin arrangements with up-up-down-down (phase A) and up-down-up-down (phase B) configurations. The relative stability of these phases is ruled by the competing…

Materials Science · Physics 2020-09-01 Silvia Damerio , Pavan Nukala , Jean Juraszek , Pim Reith , Hans Hilgenkamp , Beatriz Noheda

By means of density-functional simulations for half-doped manganites, such as pseudocubic Pr0.5Ca0.5MnO3 and bilayer PrCa2Mn2O7, we discuss the occurrence of ferroelectricity and we explore its crucial relation to the crystal structure and…

Strongly Correlated Electrons · Physics 2013-10-07 Kunihiko Yamauchi , Silvia Picozzi

The dimensionality of the electronic and magnetic structure of a given material is generally predetermined by its crystal structure. Here, using elastic and inelastic neutron scattering combined with magnetization measurements, we find…

There has been tremendous research activity in the field of magneto-electric (ME) multiferroics after Kimura et al. [1] showed that antiferromagnetic and ferroelectric order coexist in orthorhom- bically distorted perovskite TbMnO3 and are…

The Raman spectra of single crystals of NiFe2O4 were studied in various scattering configurations in close comparison with the corresponding spectra of Ni0.7Zn0.3Fe2O4 and Fe3O4. The number of experimentally observed Raman modes exceeds…

Materials Science · Physics 2015-05-19 V. G. Ivanov , M. V. Abrashev , M. N. Iliev , M. M. Gospodinov , J. Meen , M. I. Aroyo

Different configurations of magnetic orders and cation distributions for NiFe2O4 are studied by the density functional based methods with the possible inclusion of the on-site Coulomb interaction U. The lowest energy state is an inverse…

Materials Science · Physics 2011-05-10 Ching Cheng

We review the phenomenology of coupled magnetic and electric order parameters for systems in which ferroelectric and incommensurate magnetic order occur simultaneously. We discuss the role that such materials might play in fabricating novel…

Materials Science · Physics 2007-05-23 A. B. Harris , G. Lawes

The spinel vanadates have become a model family for exploring orbital order on the frustrated pyrochlore lattice, and recent debate has focused on the symmetry of local crystal fields at the cation sites. Here, we present neutron scattering…

Strongly Correlated Electrons · Physics 2014-06-10 G. J. MacDougall , I. Brodsky , A. A. Aczel , V. O. Garlea , G. E. Granroth , A. D. Christianson , T. Hong , H. D. Zhou , S. E. Nagler

The multiferroic ferrimagnet Cu$_2$OSeO$_3$ with a chiral crystal structure attracted a lot of recent attention due to the emergence of magnetic skyrmion order in this material. Here, the topological properties of its magnon excitations are…

Neutron diffraction measurements on multiferroic LuFe2O4 show changes in the antiferromagnetic (AFM) structure characterized by wavevector q = (1/3 1/3 1/2) as a function of electric field cooling procedures. The increase of intensity from…

Strongly Correlated Electrons · Physics 2011-11-09 A. M. Mulders , M. Bartkowiak , J. R. Hester , E. Pomjakushina , K. Conder

"Magnetic ferroelectric" has been found in a wide range of spiral magnets. However, these materials all suffer from low critical temperatures, which are usually below 40 K, due to strong spin frustration. Recently, CuO has been found to be…

Materials Science · Physics 2012-05-08 Guangxi Jin , Kun Cao , Guang-Can Guo , Lixin He

At room temperature, the normal oxide spinels NiCr_2O_4 and CuCr_2O_4 are tetragonally distorted and crystallize in the I4_1/amd space group due to cooperative Jahn-Teller ordering driven by the orbital degeneracy of tetrahedral Ni$^{2+}$…

Materials Science · Physics 2012-09-11 Matthew R. Suchomel , Daniel P. Shoemaker , Lynn Ribaud , Moureen C. Kemei , Ram Seshadri

Ferroelectric and ferromagnetic materials possess spontaneous electric and magnetic order, respectively, which can be switched by the corresponding applied electric and magnetic fields. Multiferroics combine these properties in a single…

Strongly Correlated Electrons · Physics 2012-11-27 J. Lee , S. A. Trugman , C. D. Batista , C. L. Zhang , D. Talbayev , X. S. Xu , S. --W. Cheong , D. A. Yarotski , A. J. Taylor , R. P. Prasankumar

Two magnetic ordering transitions are found in InMnO3, the paramagnetic to antiferromagnetic transition near ~118 K and a lower possible spin rotation transition near ~42 K. Multiple length scale structural measurements reveal enhanced…

Materials Science · Physics 2015-06-22 T. Yu , T. A. Tyson , P. Gao , T. Wu , X. Hong , S. Ghose , Y. -S. Chen

Using first principles calculations, we study the microscopic origin of ferroelectricity (FE) induced by magnetic order in the orthorhombic HoMnO3. We obtain the largest ferroelectric polarization observed in the whole class of improper…

Materials Science · Physics 2009-11-13 Silvia Picozzi , Kunihiko Yamauchi , Biplab Sanyal , Ivan A. Sergienko , Elbio Dagotto

In this work, fabrication and characterization of magnetic properties of EuFe2As2 and EuRbFe4As4 single crystals is reported. Magnetization measurements of samples with well defined thin film geometry and crystal orientation demonstrate a…

CoSeO$_4$ has a structure consisting of edge-sharing chains of Co$^{2+}$ octahedra which are held together by SeO$_4^{2-}$ tetrahedra via shared oxygen atoms at the edges of the octahedra. DC magnetization measurements indicate a transition…

X-ray diffraction pressure studies at room temperature demonstrate that the spinel FeAl$_{2}$O$_{4}$ transforms to a tetragonal phase at ~18 GPa. This tetragonal phase has a highly irregular unit-cell volume versus pressure dependence up to…

Strongly Correlated Electrons · Physics 2018-09-26 W. M. Xu , G. R. Hearne , S. Layek , D. Levy , M. P. Pasternak , G. Kh. Rozenberg , E. Greenberg