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Highly-strained BiFeO3 exhibits a "tetragonal-like, monoclinic" crystal structure found only in epitaxial films (with an out-of-plane lattice parameter exceeding the in-plane value by >20%). Previous work has shown that this phase is…

Materials Science · Physics 2011-08-17 Wolter Siemons , Michael D. Biegalski , Joong Hee Nam , Hans M. Christen

Through powder x-ray diffraction we have investigated the structural behavior of SmVO3, in which orbital and magnetic degrees of freedom are believed to be closely coupled to the crystal lattice. We have found, contrary to previous reports,…

We investigate the structural and magnetic phase transitions in EuTi1-xNbxO3 with synchrotron powder X-ray diffraction (XRD), resonant ultrasound spectroscopy (RUS), and magnetization measurements. Upon Nb-doping, the Pm-3m to I4/mcm…

The continuous displacive phase transition in SrTiO$_3$ near $T_c \approx 105$ K features a central elastic peak in neutron scattering investigations at temperatures above $T_c$, i.e., before the corresponding soft phonon mode is overdamped…

The effect of Sr doping in BaTiO3 (BTO) with nominal compositions Ba0.80Sr0.20TiO3 (BSTO) have been explored in its structural, lattice vibration, dielectric, ferroelectric and electrocaloric properties. The temperature dependent dielectric…

Materials Science · Physics 2020-03-02 Satish Yadav , Mohit Chandra , R. Rawat , Vasant Sathe , A. K. Sinha , Kiran Singh

The synthesis, structural, magnetic, thermal and transport properties are reported for polycrystalline PrIr3. At room temperature PrIr3 displays the rhombohedral space group R-3m and a PuNi3- type structure. At around 70 K a phase…

The structural properties of the SrFe2As2 and CaFe2As2 compounds have been extensively analyzed by transmission electron microscopy (TEM) from room temperature down to 20K. The experimental results demonstrate that the SrFe2As2 crystal, in…

Superconductivity · Physics 2013-05-29 C. Ma , H. X. Yang , H. F. Tian , H. L Shi , J. B. Lu , Z. W. Wang , L. J. Zeng , G. F. Chen , N. L. Wang , J. Q. Li

SrTiO3 plays a central role in oxide electronics. It is the substrate of choice for functional oxide heterostructures based on perovskite-structure thin-film stacks, and its surface or interface with a polar oxide such as LaAlO3 can become…

Materials Science · Physics 2016-10-12 J. M. D. Coey , M Venkatesan , P Stamenov

The limited operational range of phase transition-based luminescence thermometers necessitates the exploration of new host materials exhibiting first-order structural phase transitions to broaden the applicability of this approach.…

Materials Science · Physics 2025-04-03 M. Tahir Abbas , M. Szymczak , V. Kinzhybalo , D. Szymanski , M. Drozd , L. Marciniak

Group theoretical aspects of the three temperature-dependent and temperature-reversible experimentally observed phase transitions in the KNbO3 crystal (cubic-tetragonal, tetragonal-orthorhombic, orthorhombic-rhombohedral) in the framework…

Materials Science · Physics 2024-11-05 R. A. Evarestov , Yu. E. Kitaev , S. S. Novikov

We present the results of calculations of surface relaxations, energetics, and bonding properties for CaTiO3 (001) and (011) surfaces using a hybrid B3PW description of exchange and correlation. We consider both CaO and TiO2 terminations of…

Materials Science · Physics 2009-11-13 R. I. Eglitis , David Vanderbilt

Temperature dependent electrical resistivity, crystal structure and heat capacity measurements reveal a resistivity drop and metal to semiconductor transition corresponding to first order structural phase transition near 400 K in Ca3Co4O9.…

Materials Science · Physics 2012-04-17 Tao Wu , Trevor A. Tyson , Haiyan Chen , Jianming Bai , Hsin Wang , Cherno Jaye

SrTiO$_3$ thin films were used as a model system to study the effects of strain and epitaxial constraint on structural phase transitions of perovskite films. The basic phenomena revealed will apply to a variety of important structural…

Other Condensed Matter · Physics 2007-05-23 Feizhou He , B. O. Wells , S. M. Shapiro

Measurements of the resistive properties and the lattice parameters of a (LaVO3)[6 unit cells]/(SrVO3)[1 unit cell] superlattice between 10K and room temperature are presented. A low temperature metallic phase compatible with a Fermi liquid…

Strongly Correlated Electrons · Physics 2015-05-28 A. David , R. Frésard , Ph. Boullay , W. Prellier , U. Lüders , P. -E. Janolin

Oxide heterointerfaces constitute a rich platform for realizing novel functionalities in condensed matter. A key aspect is the strong link between structural and electronic properties, which can be modified by interfacing materials with…

Materials Science · Physics 2021-07-09 T. C. van Thiel , J. Fowlie , C. Autieri , N. Manca , M. Šiškins , D. Afanasiev , S. Gariglio , A. D. Caviglia

A detailed elastic neutron scattering study of the structural and magnetic phase transitions in single-crystal SrFe$_2$As$_2$ reveals that the orthorhombic (O)-tetragonal (T) and the antiferromagnetic transitions coincide at $T_\texttt{O}$…

A detailed elastic neutron scattering study of the structural and magnetic phase transitions in single-crystal SrFe$_2$As$_2$ reveals that the orthorhombic (O)-tetragonal (T) and the antiferromagnetic transitions coincide at $T_\texttt{O}$…

We have systematically investigated the annealing effect on the structure and composition of the polar surface of SrTiO3 (111), starting with an ex-situ chemical etch. The relative surface concentration between Ti and Sr strongly depends on…

Materials Science · Physics 2016-03-14 Mohammad Saghayezhian , Lina Chen , Gaomin Wang , Hangwen Guo , E. W. Plummer , Jiandi Zhang

We discuss the origin of the temperature dependence of resistivity observed in highly oriented LaNiO_3 thin films (of thickness d) grown on SrTiO_3 substrate by a pulsed laser deposition technique. All the experimental data are found to…

Materials Science · Physics 2015-12-31 S Sergeenkov , L Cichetto , M Zampieri , E Longo , F M Araujo-Moreira

RuP single crystals of MnP-type orthorhombic structure were synthesized by the Sn flux method. Temperature-dependent x-ray diffraction measurements reveal that the compound experiences two structural phase transitions, which are further…

Strongly Correlated Electrons · Physics 2015-03-06 R. Y. Chen , Y. G. Shi , P. Zheng , L. Wang , T. Dong , N. L. Wang