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An exchange-correlation energy functional beyond the local density approximation, based on the exchange-correlation kernel of the homogeneous electron gas and originally introduced by Kohn and Sham, is considered for electronic structure…

Condensed Matter · Physics 2016-08-31 Maurizia Palummo , Giovanni Onida , Rodolfo Del Sole

Presented here are calculations of the distortion of the density of an electron gas due to the electrostatic field of a proton. Several models based upon the local density approximation (LDA) of density functional theory [linear response…

chem-ph · Physics 2009-10-22 Gary G. Hoffman , Lawrence R. Pratt

We derive simple analytical expressions for the particle density $\rho(r)$ and the kinetic energy density $\tau(r)$ for a system of noninteracting fermions in a $d-$dimensional isotropic harmonic oscillator potential. We test the…

Mesoscale and Nanoscale Physics · Physics 2016-08-31 Matthias Brack , Brandon P. van Zyl

An analytical approach has been developed to describe grand canonical equilibrium between a three dimensional (3D) electron system and a two dimensional (2D) one, an energy of which is determined self-consistently with an electron…

Mesoscale and Nanoscale Physics · Physics 2009-11-11 V. G. Popov

Paralleling a previous paper, we examine single- and many-body states of relativistic electrons in an intense, rotating magnetic dipole field. Single-body orbitals are derived semiclassically and then applied to the many-body case via the…

Astrophysics · Physics 2009-10-30 James M. Gelb , Kaundinya S. Gopinath , Dallas C. Kennedy

We investigate the behavior of three-dimensional (3D) exchange-correlation energy functional approximations of density functional theory in anisotropic systems with two-dimensional (2D) character. Using two simple models, quasi-2D electron…

Mesoscale and Nanoscale Physics · Physics 2009-10-31 Yong-Hoon Kim , In-Ho Lee , Satyadev Nagaraja , Jean-Pierre Leburton , Randolph Q. Hood , Richard M. Martin

Using the $\hbar$-expansion of the Green's function of the Hartree-Fock-Bogoliubov equation, we extend the second-order Thomas-Fermi approximation to generalized superfluid Fermi systems by including the density-dependent effective mass and…

Nuclear Theory · Physics 2016-01-29 J. C. Pei , Na Fei , Y. N. Zhang , P. Schuck

We have investigated the attractive Hubbard model in the low density limit for the 2D square lattice using the ladder approximation for the vertex function in a self-consistent, conserving formulation. In the parameter region where the…

Strongly Correlated Electrons · Physics 2009-10-31 M. Letz , R. J. Gooding

We present a constructive solution to the N-representability problem---a full characterization of the conditions for constraining the two-electron reduced density matrix (2-RDM) to represent an N-electron density matrix. Previously known…

Quantum Physics · Physics 2012-07-04 David A. Mazziotti

The self consistent version of the density functional theory is presented, which allows to calculate the ground state and dynamic properties of finite multi-electron systems. An exact functional equation for the effective interaction, from…

Materials Science · Physics 2017-08-23 M. Ya. Amusia , A. Z. Msezane , V. R. Shaginyan

The quantum mechanical ground state of a 2D $N$-electron system in a confining potential $V(x)=Kv(x)$ ($K$ is a coupling constant) and a homogeneous magnetic field $B$ is studied in the high density limit $N\to\infty$, $K\to \infty$ with…

Condensed Matter · Physics 2009-10-28 E. H. Lieb , J. P. Solovej , J. Yngvason

By introducing the self-energy density functionals for the dissipative interactions between the reduced system and its environment, we develop a time-dependent density-functional theory formalism based on an equation of motion for the…

Quantum Physics · Physics 2009-11-13 Xiao Zheng , Fan Wang , Chi Yung Yam , Yan Mo , GuanHua Chen

Density functional theory is currently the most widely applied method in electronic structure theory. The Kohn-Sham method, based on a fictitious system of non-interacting particles, is the work horse of the theory. The particular form of…

Chemical Physics · Physics 2016-06-01 Hubertus J J van Dam

The general procedure underlying Hartree-Fock and Kohn-Sham density functional theory calculations consists in optimizing orbitals for a self-consistent solution of the Roothaan-Hall equations in an iterative process. It is often ignored…

Chemical Physics · Physics 2017-03-16 Alain C. Vaucher , Markus Reiher

Semi-local density functionals for the exchange-correlation energy of electrons are extensively used as it produce realistic and accurate results for finite and extended systems. The choice of techniques play crucial role in constructing…

Materials Science · Physics 2017-11-01 Subrata Jana , Prasanjit Samal

We devise an efficient practical method for computing the Kohn-Sham exchange-correlation potential corresponding to a Hartree-Fock electron density. This potential is almost indistinguishable from the exact-exchange optimized effective…

Chemical Physics · Physics 2013-07-09 Ilya G. Ryabinkin , Alexei A. Kananenka , Viktor N. Staroverov

Orbital-free density functional theory promises to deliver linear-scaling electronic structure calculations. This requires the knowledge of the non-interacting kinetic-energy density functional (KEDF), which should be accurate and must…

Materials Science · Physics 2024-12-12 Michael A. J. Mitchell , Teresa Del Aguila Ferrandis , Stefano Sanvito

The Thomas-Fermi (TF) approximation for the static dielectric constant of a three-dimensional electron liquid can be derived from minimizing the TF local-density approximation for the kinetic-energy functional. Here we show that this…

Materials Science · Physics 2009-11-11 A. P. Favaro , Joao Vitor Batista Ferreira , K. Capelle

We analyzed the Hartree-Fock approximation for an electron system. The interaction between particles is modeled by a non-Coulombian potential. We analyzed both the three-dimensional and two-dimensional systems. We obtained accurate…

Quantum Gases · Physics 2024-08-28 Vlad-Mihai Ene , Ilinca Lianu , Ioan Grosu

Hohenberg and Kohn have proven that the electronic energy and the one-particle electron density can, in principle, be obtained by minimizing an energy functional with respect to the density. While decades of theoretical work have produced…

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