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A well-known approach to describe the dynamics of an open quantum system is to compute the master equation evolving the reduced density matrix of the system. This approach plays an important role in describing excitation transfer through…

Quantum Physics · Physics 2022-10-25 Kimara Naicker , Ilya Sinayskiy , Francesco Petruccione

The theory of energy transfer dynamics of a pair of donor and acceptor molecules located in the plasmonic hot spots is developed by means of the master equation approach and the electromagnetic Green's tensor technique. A nonlocal effect…

Optics · Physics 2017-12-29 Jun Ren , Tian Chen , Bo Wang , Xiangdong Zhang

Ultrafast multistage electron transfer (ET) in molecular systems with multiple redox centers is fundamental to photochemical energy conversion, including processes in natural photosynthesis, molecular optoelectronics, and organic…

Chemical Physics · Physics 2025-07-29 Serguei Feskov , Anatoly Ivanov

We develop a framework that provides a few-mode master equation description of the interaction between a single quantum emitter and an arbitrary electromagnetic environment. The field quantization requires only the fitting of the spectral…

An equation based reduced order model applicable to generalized heat equation and thermal simulations of power electronics systems developed in commercial CFD tools, is presented in this work. The model considers the physics of heat…

Numerical Analysis · Mathematics 2024-04-26 Neelakantan Padmanabhan

Efficient transport and harvesting of excitation energy under low light conditions is an important process in nature and quantum technologies alike. Here we formulate a quantum optics perspective to excitation energy transport in…

Quantum Physics · Physics 2024-03-06 Raphael Holzinger , Jonah Peter , Stefan Ostermann , Helmut Ritsch , Susanne Yelin

The optical response of an electronic two-level system (TLS) coupled to an incident continuous wave (cw) electromagnetic (EM) field is simulated explicitly in one dimension by the following five approaches: (i) the coupled Maxwell-Bloch…

Optics · Physics 2019-03-19 Tao E. Li , Hsing-Ta Chen , Joseph E. Subotnik

We present a multi-scale approach to efficiently embed an ab initio correlated chemical fragment described by its energy-weighted density matrices, and entangled with a wider mean-field many-electron system. This approach, first presented…

Strongly Correlated Electrons · Physics 2019-07-24 Edoardo Fertitta , George H. Booth

We describe a method for simulating exciton dynamics in protein-pigment complexes, including effects from charge transfer as well as fluorescence. The method combines the hierarchical equations of motion, which are used to describe quantum…

Chemical Physics · Physics 2022-11-23 Thomas P. Fay , David T. Limmer

The quantum network model with real variables is usually used to describe the excitation energy transfer (EET) in the Fenna-Matthews-Olson(FMO) complexes. In this paper we add the quantum phase factors to the hopping terms and find that the…

Molecular Networks · Quantitative Biology 2015-03-20 Bao-quan Ai , Shi-Liang Zhu

A remarkable amount of theoretical research has been carried out to elucidate the physical origins of the recently observed long-lived quantum coherence in the electronic energy transfer process in biological photosynthetic systems.…

Quantum Physics · Physics 2015-03-19 Sangwoo Shim , Patrick Rebentrost , Stéphanie Valleau , Alan Aspuru-Guzik

Giant strides in ultrashort laser pulse technology have enabled real-time observation of dynamical processes in complex molecular systems. Specifically, the discovery of oscillatory transients in the two-dimensional electronic spectra of…

Chemical Physics · Physics 2021-03-08 Akihito Ishizaki , Graham R. Fleming

We present a Lagrangian-based implementation of Ehrenfest dynamics with nuclear-electronic orbital (NEO) theory and real-time time-dependent density functional theory (RT-TDDFT) for extended periodic systems. In addition to a quantum…

Chemical Physics · Physics 2024-07-29 Jianhang Xu , Ruiyi Zhou , Tao E. Li , Sharon Hammes-Schiffer , Yosuke Kanai

Solving for the time evolution of a many particle system whose dynamics is governed by Lindblad equation is hard. We extend the use of the transfer matrix approach to a class of Lindblad equations that admit a closed hierarchy of two point…

Quantum Physics · Physics 2025-10-02 Junaid Majeed Bhat , Marko Znidaric

Quantum effects in photosynthetic energy transport in nature, especially for the typical Fenna-Matthews-Olson (FMO) complexes, are extensively studied in quantum biology. Such energy transport processes can be investigated as open quantum…

We benchmark a set of quantum-chemistry methods, including multitrajectory Ehrenfest, fewest-switches surface-hopping, and multiconfigurational-Ehrenfest dynamics, against exact quantum-many-body techniques by studying real-time dynamics in…

The energy transition has recently experienced a further acceleration. In order to make the integration of renewable energies as cost-effective, secure and sustainable as possible and to develop new paradigms for the energy system, many…

Systems and Control · Electrical Eng. & Systems 2023-04-13 Béla Wiegel , Tom Steffen , Davood Babazadeh , Christian Becker

We theoretically investigate an electron transfer (ET) process in a dissipative environment by means of two-dimensional (2D) correlation spectroscopy. We extend the reduced hierarchy equations of motion approach to include both overdamped…

Chemical Physics · Physics 2013-10-29 Yoshitaka Tanimura

In this paper, we investigate the energy minimization model of the ensemble Kohn-Sham density functional theory for metallic systems, in which a pseudo-eigenvalue matrix and a general smearing approach are involved. We study the invariance…

Numerical Analysis · Mathematics 2022-01-19 Xiaoying Dai , Stefano de Gironcoli , Bin Yang , Aihui Zhou

The Wigner-Weisskopf-type model developed in [R. Alicki and F. Giraldi, J. Phys. B {\bf 44}, 154020 (2011)] is applied to the biological process of energy transfer from a large peripheral light harvesting antenna to the reaction center.…

Quantum Physics · Physics 2016-08-14 Robert Alicki , Wiesław Miklaszewski