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We compare the ability of four popular hybrid density functionals (B3LYP, B3PW91, HSE, and PBE0) for predicting band gaps of semiconductors and insulators over a large benchmark set using a consistent methodology. We observe no significant…

Materials Science · Physics 2016-10-07 Alejandro J. Garza , Gustavo E. Scuseria

Hybrid density functional (HDF) approximations usually deliver higher accuracy than local and semilocal approximations to the exchange-correlation functional, but this comes with drastically increased computational cost. Practical…

Materials Science · Physics 2022-10-12 Yuyang Ji , Peize Lin , Xinguo Ren , Lixin He

We present a systematic study that clarifies validity and limitation of current hybrid functionals in density functional theory for structural and electronic properties of various semiconductors and insulators. The three hybrid functionals,…

Materials Science · Physics 2015-03-19 Yu-ichiro Matsushita , Kazuma Nakamura , Atsushi Oshiyama

The properties of many intrinsic defects in the wide band gap semiconductor LaAlO3 are studied using the screened hybrid functional of Heyd, Scuseria, and Ernzerhof (HSE). As in pristine structures, exact exchange included in the screened…

Materials Science · Physics 2015-06-17 Fedwa El-Mellouhi , Edward N. Brothers , Melissa J. Lucero , Gustavo E. Scuseria

Hybrid functionals, which mix a fraction of Hartree-Fock (HF) exchange with local or semilocal exchange, have become increasingly popular in quantum chemistry and computational materials science. Here, we assess the accuracy of the…

Materials Science · Physics 2018-10-19 Mauricio A. Flores , Walter Orellana , Eduardo Menéndez-Proupin

The Heyd-Scuseria-Ernzerhof (HSE) density functionals are popular for their ability to improve the accuracy of standard semilocal functionals such as Perdew-Burke-Ernzerhof (PBE), particularly for semiconductor band gaps. They also have a…

Materials Science · Physics 2025-10-07 Jonathan E. Moussa , Peter A. Schultz , James R. Chelikowsky

We present an implementation of the Heyd-Scuseria-Ernzerhof (HSE) hybrid functional within the full-potential linearized augmented-plane-wave (FLAPW) method. Pivotal to the HSE functional is the screened electron-electron interaction, which…

Materials Science · Physics 2011-11-11 Martin Schlipf , Markus Betzinger , Christoph Friedrich , Marjana Ležaić , Stefan Blügel

We propose a range-separated hybrid exchange-correlation functional to calculate solid-state material properties. The functional mixes Hartree-Fock exchange with the semilocal exchange of the meta-generalized gradient approximation…

Materials Science · Physics 2025-02-27 Subrata Jana , Abhishek Bhattacharjee , Suman Mahakal , Szymon Smiga , Prasanjit Samal

The Heyd-Scuseria-Ernzerhof (HSE) hybrid functional has become a widely used tool for theoretical calculations of point defects in semiconductors. It generally offers a satisfactory qualitative description of defect properties, including…

A meta generalized gradient level screened range-separated hybrid functional is developed for solid-state electronic structure theory. Assessment of the present range-separated hybrid functional for solid-state lattice constants and band…

Materials Science · Physics 2018-03-13 Subrata Jana , Abhilash Patra , Prasanjit Samal

Hybrid semiconductor-ferromagnetic insulator heterostructures are interesting due to their tunable electronic transport, self-sustained stray field and local proximitized magnetic exchange. In this work, we present lattice matched hybrid…

In the density-functional studies of materials with localized electronic states, the local/semilocal exchange-correlation functionals are often either combined with a Hubbard parameter $U$ as in the LDA+$U$ method or mixed with a fraction…

Materials Science · Physics 2014-07-24 Mehmet Aras , Çetin Kılıç

Accurately modeling the electronic structure of materials is a persistent challenge to high-throughput screening. A promising means of balancing accuracy against computational cost are non-self-consistent calculations with hybrid…

Materials Science · Physics 2020-05-04 Jonathan M. Skelton , David S. D. Gunn , Sebastian Metz , Stephen C. Parker

We present a systematic and comparative study of the structural and electronic properties of Cu-based ternary and quaternary semiconductors using first-principles electronic structure approaches. The important role that Cu d electrons play…

Materials Science · Physics 2015-05-28 Yubo Zhang , Xun Yuan , Xiudong Sun , Bi-Ching Shih , Peihong Zhang , Wenqing Zhang

We perform hybrid functional and quasi-particle band structure calculations with spin-orbit interaction to investigate the band structures of Mg2Si, Mg2Ge, and Mg2Sn. For all Mg2X materials, where X = Si, Ge, and Sn, the characteristics of…

Materials Science · Physics 2019-07-24 Byungki Ryu , Sungjin Park , Eun-Ae Choi , Johannes de Boor , Pawel Ziolkowski , Jaywan Chung , SuDong Park

BAs is III-V semiconductor with ultra-high thermal conductivity, but many of its electronic properties are unknown. This work applies predictive atomistic calculations to investigate the properties of BAs heterostructures, such as strain…

Materials Science · Physics 2019-09-05 Kyle Bushick , Sieun Chae , Zihao Deng , John Heron , Emmanouil Kioupakis

We present a detailed study of common intrinsic defects in CuInS$_2$ and CuGaS$_2$ using the Heyd, Scuseria and Ernzerhof (HSE) hybrid functional scheme. The impact of the two HSE parameters, $\alpha$ and $\omega$ on the band gap and…

Materials Science · Physics 2026-01-16 Henry Phillip Fried , Daniel Barragan-Yani , Ludger Wirtz

Double half-heusler alloys are the new class of compounds which can be seen as transmuted version of two single half-heusler with higher flexibility of tuning their properties. Here, we report a detailed study of thermoelectric (TE)…

Materials Science · Physics 2025-03-05 Bhawna Sahni , Aftab Alam

Recent research has delved into advanced designs for reconfigurable intelligent surfaces (RIS) with integrated sensing functions. One promising concept is the hybrid RIS (HRIS), which blends sensing and reflecting meta-atoms. This enables…

Signal Processing · Electrical Eng. & Systems 2025-09-01 Amarilton L. Magalhães , André L. F. de Almeida

We demonstrate the accuracy of the hybrid functional HSE06 for computing band offsets of semiconductor alloy heterostructures. The highlight of this study is the computation of conduction band offsets with a reliability that has eluded…

Materials Science · Physics 2015-05-19 Amita Wadehra , Jeremy W. Nicklas , John W. Wilkins
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