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The development of magnetoelectric materials requires chemical design strategies that integrate structural polarity with magnetic lattices capable of supporting competing spin interactions. Here, we demonstrate such an approach in the…

Materials Science · Physics 2026-03-17 Faith O. Adeyemi , Xudong Huai , Mohamed Kandil , Pradip Karki , Wencan Jin , Thao T. Tran

Delafossite PdCrO$_2$ is an intriguing material which displays nearly-free electron and Mott insulating behaviour in different layers. Both angle-resolved photoemission spectroscopy (ARPES) and Compton scattering measurements have…

Strongly Correlated Electrons · Physics 2023-01-06 Alyn D. N. James , David Billington , Stephen B. Dugdale

Multiferroics are compounds in which at least two ferroic orders coexist - typically (anti)ferromagnetism and ferroelectricity. While magnetic order can arise in both insulating and conducting compounds, ferroelectricity is in principle not…

The problem of importance of strong correlations for the electronic structure, transport and magnetic properties of half--metallic ferromagnetic CrO_2 is addressed by performing density functional electronic structure calculations in the…

Strongly Correlated Electrons · Physics 2009-11-10 A. Toropova , G. Kotliar , S. Y. Savrasov , V. S. Oudovenko

We have prepared the complete delafossite solid solution series between diamagnetic CuAlO2 and the t2g^3 frustrated antiferromagnet CuCrO2. The evolution with composition x in CuAl(1-x)Cr(x)O2 of the crystal structure and magnetic…

Materials Science · Physics 2012-10-03 Phillip T. Barton , Ram Seshadri , Andrea Knöller , Matthew J. Rosseinsky

We prepared a powder sample of edwardsite Cd2Cu3(SO4)2(OH)6 4H2O, which is a new candidate compound for the spin-1/2 kagome antiferromagnet, and studied its magnetic properties by magnetic susceptibility and heat capacity measurements.…

Materials Science · Physics 2015-06-15 Hajime Ishikawa , Yoshihiko Okamoto , Zenji Hiroi

Chromium thiophosphate is a long-known material: a layered semiconducting antiferromagnet. Its recently discovered gate-tunable metamagnetic phase transitions, the remarkable positive and oscillating magnetoresistance as a tunnel barrier,…

We have carried out $^{63,65}$Cu NMR spectra measurements in magnetic field up to about 45~T on single crystal of a multiferroic triangular antiferromagnet CuCrO$_2$. The measurements were performed for magnetic fields aligned along the…

Strongly Correlated Electrons · Physics 2016-12-21 Yu. A. Sakhratov , L. E. Svistov , P. L. Kuhns , H. D. Zhou , A. P. Reyes

First-principles density functional calculations show that the $\textrm{SrRuO}_{3}/\textrm{PbTiO}_{3}/\textrm{SrRuO}_{3}$ multiferroic junction with asymmetric (RuO$_{2}$/PbO and TiO$_{2}$/SrO) interfaces has a large ferroelectric…

Materials Science · Physics 2013-12-20 Francesco Ricci , Alessio Filippetti , Vincenzo Fiorentini

We study the emergence of magnetism and its interplay with structural properties in a two dimensional molecular crystal of cyclacenes, using density functional theory (DFT). Isolated cyclacenes with an even number of fused benzenes host two…

Mesoscale and Nanoscale Physics · Physics 2021-07-27 R. Ortiz , J. C. Sancho-García , J. Fernández-Rossier

Electronic structure of ferromagnetic half-metal CrO$_2$ was studied by means of 53Cr nuclear magnetic resonance (NMR) spectroscopy and density functional theory (DFT). The measured NMR spectrum consists of three distinct spectral lines and…

Materials Science · Physics 2025-05-19 Vojtěch Chlan , Anna A. Shmyreva , Helena Štěpánková

Atomically thin materials with coupled magnetic and electric polarization are critical for developing energy-efficient and high-density spintronic devices, yet they remain scarce due to often conflicting requirements of stabilizing both…

Mesoscale and Nanoscale Physics · Physics 2024-12-09 Lihao Zhang , Xiaoyu Wang , Qi Li , Haibo Xie , Liangliang Zhang , Lei Zhang , Jie Pan , Yingchun Cheng , Zhe Wang

We have performed a systematic first-principles investigation to calculate the structural, electronic, and magnetic properties of PbCrO$_{3}$, CrPbO$_{3}$ as well as their equiproportional combination. The local density approximation…

Strongly Correlated Electrons · Physics 2012-01-25 Bao-Tian Wang , Wen Yin , Wei-Dong Li , Fangwei Wang

MCrS2 compounds (M=Li, Na, K, Cu, Ag, and Au) with triangular Cr layers show large variety of magnetic ground states ranging from 120-degree antiferromagnetic order of Cr spins in LiCrS2 to double stripes in AgCrS2, helimagnetic order in…

Materials Science · Physics 2013-01-16 A. V. Ushakov , D. A. Kukusta , A. N. Yaresko , D. I. Khomskii

Below its N\'eel temperature, the frustrated magnet CdCr$_2$O$_4$ exhibits an antiferromagnetic spin-spiral ground state. Such states can give rise to a sizable magnetoelectric coupling. In this report, we measure the electric polarization…

Materials Science · Physics 2020-07-15 L. Rossi , D. Brüning , H. Ueda , Y. Skourski , T. Lorenz , B. Bryant

We report on the magnetic properties of the supra-molecular compound iron(II) phthalocyanine in its alpha-form. dc- and ac-susceptometry measurements and Mossbauer experiments show that the iron atoms are strongly magnetically coupled into…

Condensed Matter · Physics 2007-05-23 M. Evangelisti , J. Bartolome , L. J. de Jongh , G. Filoti

Two-dimensional chromium ditelluride (CrTe2) is a promising ferromagnetic layered material that exhibits long-range ferromagnetic ordering in the monolayer limit. The formation energies of the different possible structural phases (1T, 1H,…

Materials Science · Physics 2023-05-02 Yuhang Liu , Sohee Kwon , George J. de Coster , Roger K. Lake , Mahesh R. Neupane

In two-dimensional van der Waals magnetic materials, the interplay between magnetism and electron correlation can give rise to new ground states and lead to novel transport and optical properties. A fundamental question in these materials…

Sr2Cr3As2O2 is composed of alternating square-lattice CrO2 and Cr2As2 stacking layers, where CrO2 is isostructural to the CuO2 building-block of cuprate high-Tc superconductors and Cr2As2 to Fe2As2 of Fe-based superconductors. Current…

Van der Waals (vdW) ferromagnets are an important class of materials for spintronics applications. The recent discovery of atomically vdW magnets CrI$_3$ and Cr$_2$Ge$_2$Te$_6$ has triggered a renaissance in the area of two-dimensional (2D)…

Strongly Correlated Electrons · Physics 2021-10-22 Yu Liu , Zhixiang Hu , Eli Stavitski , Klaus Attenkofer , C. Petrovic