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We study from first principles the magnetism in graphene induced by single carbon atom defects. For two types of defects considered in our study, the hydrogen chemisorption defect and the vacancy defect, the itinerant magnetism due to the…

Materials Science · Physics 2007-05-23 Oleg V. Yazyev , Lothar Helm

A possibility to control magnetic properties by using electric fields is one of the most desirable characteristics for spintronics applications. Finding a suitable material remains an elusive goal, with only a few candidates found so far.…

We have studied magnetization of graphene nanocrystals obtained by sonic exfoliation of graphite. No ferromagnetism is detected at any temperature down to 2 K. Neither do we find strong paramagnetism expected due to the massive amount of…

Mesoscale and Nanoscale Physics · Physics 2010-11-24 M. Sepioni , R. R. Nair , S. Rablen , J. Narayanan , F. Tuna , R. Winpenny , A. K. Geim , I. V. Grigorieva

Magnetic properties of graphene with randomly distributed magnetic defects/vacancies are studied in terms of the Kondo Hamiltonian in the mean field approximation. It has been shown that graphene with defects undergoes a magnetic phase…

Materials Science · Physics 2015-05-27 Y. G. Semenov , J. M. Zavada , K. W. Kim

The pristine graphene is strongly diamagnetic. However, graphene with single carbon atom defects could exhibit paramagnetism with local magnetic moments ~ 1.5 per vacancy1-6. Theoretically, both the electrons and electrons of graphene…

Materials Science · Physics 2017-02-13 Yu Zhang , Si-Yu Li , Wen-Tian Li , Jia-Bin Qiao , Wen-Xiao Wang , Long-Jin Yin , Lin He

The electronic and magnetic properties of graphane with H-vacancies are investigated with the help of quantum-chemistry methods. The hybridization of the edges is found to be absolutely crucial in defining the size of the bandgap, which is…

Materials Science · Physics 2015-05-14 Julia Berashevich , Tapash Chakraborty

Theoretical calculations, based on hybrid exchange density functional theory, are used to show that in graphene a periodic array of defects generates a ferromagnetic ground state at room temperature for unexpectedly large defect…

Materials Science · Physics 2009-11-13 L. Pisani , B. Montanari , N. M. Harrison

The magnetic properties of disordered graphene and irradiated graphite are systematically studied using a combination of mean-field Hubbard model and first-principles calculations. By considering large-scale disordered models of graphene, I…

Materials Science · Physics 2008-07-17 Oleg V. Yazyev

The issue of whether local magnetic moments can be formed by introducing adatoms into graphene is of intense research interest because it opens the window to fundamental studies of magnetism in graphene, as well as of its potential…

Mesoscale and Nanoscale Physics · Physics 2012-06-12 X. Hong , K. Zou , B. Wang , S. -H. Cheng , J. Zhu

Graphene is a model system for the study of electrons confined to a strictly two-dimensional layer1 and a large number of electronic phenomena have been demonstrated in graphene, from the fractional2, 3 quantum Hall effect to…

Mesoscale and Nanoscale Physics · Physics 2015-05-18 Jian-Hao Chen , W. G. Cullen , E. D. Williams , M. S. Fuhrer

Using calculations on defective graphene from first principles, we herein consider the dependence of the properties of the monovacancy of graphene under isotropic strain, with a particular focus on spin moments. At zero strain, the vacancy…

Mesoscale and Nanoscale Physics · Physics 2010-12-16 E. J. G. Santos , S. Riikonen , D. Sanchez-Portal , A. Ayuela

Using first-principles calculations, the effect of magnetic point defects (vacancy and adatom) is investigated in zigzag graphene nanoribbons. The structural, electronic, and spin-transport properties are studied. While pristine ribbons…

Materials Science · Physics 2009-02-19 S. M. -M. Dubois , G. -M. Rignanese , J. -C. Charlier

The phase diagram of graphene decorated with magnetic adatoms distributed either on a single sublattice, or evenly over the two sublattices, is computed for adatom concentrations as low as $\sim1\%$. Within the framework of the $s$-$d$…

Mesoscale and Nanoscale Physics · Physics 2019-01-28 Frederico J. Sousa , B. Amorim , Eduardo V. Castro

Two-dimensional carbon, or graphene, is a semi-metal that presents unusual low-energy electronic excitations described in terms of Dirac fermions. We analyze in a self-consistent way the effects of localized (impurities or vacancies) and…

Strongly Correlated Electrons · Physics 2009-11-11 N. M. R. Peres , F. Guinea , A. H. Castro Neto

Understanding the magnetic properties of graphenic nanostructures is instrumental in future spintronics applications. These magnetic properties are known to depend crucially on the presence of defects. Here we review our recent theoretical…

Mesoscale and Nanoscale Physics · Physics 2013-04-02 Elton J. G. Santos , Andres Ayuela , Daniel Sanchez-Portal

Isolated hydrogen atoms absorbed on graphene are predicted to induce magnetic moments. Here we demonstrate that the adsorption of a single hydrogen atom on graphene induces a magnetic moment characterized by a ~20 meV spin-split state at…

We present ab initio calculations for single-atom vacancies in graphene. In agreement with earlier work, we find that vacancies are responsible for the magnetism recently observed experimentally, creating a center with net spin. For small…

Fluorine adatoms on graphene induce local changes in electronic and magnetic properties, and subtle correlation effects. We investigate the GGA and GGA+U approaches as possible solutions to describe the magnetic moment and electronic band…

Mesoscale and Nanoscale Physics · Physics 2017-09-28 F. Marsusi , M. J. Verstraete

Hydrogen adatoms are shown to generate magnetic moments inside single layer graphene. Spin transport measurements on graphene spin valves exhibit a dip in the non-local spin signal as a function of applied magnetic field, which is due to…

Mesoscale and Nanoscale Physics · Physics 2013-02-06 Kathleen M. McCreary , Adrian G. Swartz , Wei Han , Jaroslav Fabian , Roland K. Kawakami

Vacancy-induced magnetism in graphene bilayers is investigated using spin-polarized density functional theory calculations. One of two graphene layers has a monovacancy. Two atomic configurations for bilayers are considered with respect to…

Other Condensed Matter · Physics 2009-11-13 Sangkook Choi , Byoung Wook Jeong , Seungchul Kim , Gunn Kim
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