Related papers: The PAH hypothesis after 25 years
Astronomical mid-IR spectra show two minor PAH features at 5.25 and 5.7 $\mu$m (1905 and 1754 cm$^{\rm - 1}$) that hitherto have been little studied, but contain information about the astronomical PAH population that complements that of the…
Polycyclic aromatic hydrocarbon (PAH) molecules have been long considered promising candidates for the carriers of the diffuse interstellar bands (DIBs). The PAH-DIB hypothesis, however, raises two major issues. First, the number of…
The mid-IR spectra of six large, irregular PAHs with formulae (C84H24 - C120H36) have been computed using Density Functional Theory (DFT). Trends in the dominant band positions and intensities are compared to those of large, compact PAHs as…
It has been an unanswered question how many dusty galaxies have been undetected from the state-of-the-art observational surveys. JWST enables us to detect faint IR galaxies that have prominent polycyclic aromatic hydrocarbon (PAH) features…
We present 10-15 micron spectra of a sample of H II regions, YSOs and evolved stars that show strong unidentified infrared emission features, obtained with the ISO/SWS spectrograph on-board ISO. These spectra reveal a plethora of emission…
A family of unidentified infrared emission (UIE) bands has been observed throughout the Universe. The current observed spectral properties of the UIE bands are summarized. These properties are discussed in the frameworks of different models…
Polycyclic Aromatic Hydrocarbon (PAH) molecules have been long proposed to be a major carrier of 'Unidentified Infrared' (UIR) emission bands that have been observed ubiquitously in various astrophysical environments. These molecules can…
Low spectral resolution (delta lambda/lambda ~ 50) mid-infrared observations with high angular resolution (0.3--0.5'') using the Long Wavelength Spectrometer on the Keck I Telescope are reported of the nuclei of five highly luminous…
Here we report our discovery of a band of blue luminescence (BL) in the Red Rectangle (RR) nebula. This enigmatic proto-planetary nebula is also one of the brightest known sources of extended red emission as well as of unidentified…
Up to now, no laboratory-based study has investigated polycyclic aromatic hydrocarbon (PAH) species as potential carriers of both the diffuse interstellar bands (DIBs) and the 2175 A UV bump. We examined the proposed correlation between…
We present $Spitzer$/IRS mid-infrared spectral maps of the Galactic star-forming region M17 as well as IRSF/SIRIUS Br$\gamma$ and Nobeyama 45-m/FOREST $^{13}$CO ($J$=1--0) maps. The spectra show prominent features due to polycyclic aromatic…
We present mid-infrared spectra of sixteen optically faint sources with 70 micron fluxes in the range 19-38mJy. The sample spans a redshift range of 0.35<z<1.9, with most lying between 0.8<z<1.6, and has infrared luminosities of 10^{12} -…
The unidentified infrared bands (UIBs) have been observed in virtually every dusty astrophysical environment investigated. The UIB carrier must be abundant and ubiquitous. Strong evidence points to polycyclic aromatic hydrocarbons (PAHs) as…
We decompose the observed 7.7 $\mu$m polycyclic aromatic hydrocarbon (PAH) emission complexes in a large sample of over 7000 mid-infrared spectra of the interstellar medium (ISM) using spectral cubes observed with the Spitzer/IRS-SL…
The so-called unidentified infrared emission (UIE) features at 3.3, 6.2, 7.7, 8.6, and 11.3 micrometer are ubiquitously seen in a wide variety of astrophysical regions. The UIE features are characteristic of the stretching and bending…
We present a systematic study of mid-infrared spectra of galaxies including star-forming galaxies and Active Galactic Nuclei observed with JWST MIRI-MRS and NIRSpec-IFU. We focus on the relative variations of the 3.3, 6.2, 7.7, 11.3, 12.7…
For star-forming galaxies, we investigate a global relation between polycyclic aromatic hydrocarbon (PAH) emission luminosity at 3.3 um, L_PAH3.3, and infrared (8-1000 um) luminosity, L_IR, to understand how the PAH 3.3 um feature relates…
We introduce a novel model to spectroscopically constrain the mid-infrared (MIR) extinction/attenuation curve from 3--17 um, using Polycyclic Aromatic Hydrocarbon (PAH) emission drawn from an AKARI-Spitzer extragalactic cross-archival…
Polycyclic aromatic hydrocarbons (PAHs) are of great astrochemical and astrobiological interest due to their potential to form prebiotic molecules. We analyse the 7.7 and 8.6 ${\mu}$m PAH bands in 126 predominantly starburst-dominated…
We present ISOCAM 15 micron and MIPS 24 micron photometry of a sample of 16 distant Luminous Infrared Galaxies (LIRGs) characterized by a median luminosity L(IR) 2x10^11 Lsol and redshift z = 0.7 (distributed from z = 0.1 to 1.2). While…