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Wake-up effect is still an obstacle in the commercialization of hafnia-based ferroelectric thin films. In this work, we investigate the effect of defects, controlled by ozone dosage, on the field cycling behavior of the atomic layer…

Materials Science · Physics 2020-09-11 Alireza Kashir , Seungyeol Oh , Hyunsang Hwang

By employing a mixed SnO$_2$+Sn source, we demonstrate suboxide molecular beam epitaxy growth of phase-pure single crystalline metastable SnO(001) thin films at a growth rate of ~1.0nm/min without the need for additional oxygen. These films…

Photoinduced reductions in the oxygen vacancy concentration were leveraged to increase the ferroelectric phase fraction of $\mathrm{Hf_{0.5}Zr_{0.5}O_2}$ (HZO) thin-films. Modest ($\sim 0.02-0.77~\mathrm{mJ/\mu m^2}$) laser doses of visible…

Memristive switching devices, candidates for resistive random access memory technology, have been shown to switch off through a progression of states with quantized conductance and subsequent non-integer conductance (in terms of conductance…

Mesoscale and Nanoscale Physics · Physics 2016-11-23 Xiaoliang Zhong , Ivan Rungger , Peter Zapol , Olle Heinonen

We discuss the environmental instability of amorphous indium oxide (InOx)-based thin-film transistors (TFTs) in terms of the excess oxygen in the semiconductor films. A comparison between amorphous InOx doped with low and high…

Materials Science · Physics 2015-05-14 Shinya Aikawa , Nobuhiko Mitoma , Takio Kizu , Toshihide Nabatame , Kazuhito Tsukagoshi

We investigate the complex relationship between the growth conditions and the structural and transport properties of $\mathrm{Ti_xO_y}$ thin films grown by molecular beam epitaxy. Transport properties ranging from metallicity to…

Natural 12CaO$\cdot$7Al$_2$O$_3$ (C12A7) is a wide bandgap insulator, but conductivity can be realized by introducing oxygen deficiency. Currently, there are two competing models explaining conductivity in oxygen-deficient C12A7, one…

On highly oxygen deficient thin films of hafnium oxide (hafnia, HfO$_{2-x}$) contaminated with adsorbates of carbon oxides, the formation of hafnium carbide (HfC$_x$) at the surface during vacuum annealing at temperatures as low as 600…

Materials Science · Physics 2016-06-28 C. Rodenbücher , E. Hildebrandt , K. Szot , S. U. Sharath , J. Kurian , P. Komissinskiy , U. Breuer , R. Waser , L. Alff

Mn doped GaAs thin films were grown using molecular beam epitaxy at high and low substrate temperatures. The elemental concentration depth profiles in the thin films were determined by using Auger electron spectroscopy combined with ion…

Mesoscale and Nanoscale Physics · Physics 2015-06-24 J. F. Xu , P. M. Thibado , C. Awo-Affouda , R. Moore , V. P. LaBella

Transparent conducting oxides (TCOs) represent a remarkable class of materials that possess both excellent electrical conductivity and high optical transparency, which are typically considered mutually exclusive in traditional materials. In…

Materials Science · Physics 2024-10-22 Jarnail Singh , Pankaj Bhardwaj

Thin p-type Sb-doped ZnO films were grown by filtered vacuum arc deposition (FVAD), on untreated glass samples. The arc cathode was prepared by dissolving Sb into molten Zn. The deposition was performed with 200 A arc current, running for…

Materials Science · Physics 2009-09-29 T. David , S. Goldsmith , R. L. Boxman

We report on the characterization of Pt-YBa$_2$Cu$_3$O$_{7-\delta}$ interfaces, focusing on how oxygen vacancies content ($\delta$) affects electrical transport mechanisms. Our study examines four Pt-YBa$_2$Cu$_3$O$_{7-\delta}$ samples with…

Disordered Systems and Neural Networks · Physics 2025-01-28 C. Acha , A. Camjayi , T. Vaimala , H. Huhtinen , P. Paturi

We have investigated the electronic and optical properties of epitaxial La1-xSrxFeO3 for x from 0 to 1 prepared by molecular beam epitaxy. Core-level and valence-band x-ray photoemission features monotonically shift to lower binding energy…

The quantum Hall conductance in monolayer graphene on an epitaxial SrTiO3 (STO) thin film is studied to understand the role of oxygen vacancies in determining the dielectric properties of STO. As the gate voltage sweep range is gradually…

Materials Science · Physics 2017-05-17 Kyeong Tae Kang , Haeyong Kang , Jeongmin Park , Dongseok Suh , Woo Seok Choi

We have successfully fabricated the nitrogen-doped cuprous oxide thin films on the amorphous standard soda-lime glass by reactive high-power impulse magnetron sputtering. The energy of film-forming particles was controlled by the value of…

While pyrochlore iridate thin films are theoretically predicted to possess a variety of emergent topological properties, experimental verification of these predictions can be obstructed by the challenge in thin film growth. Here we report…

We use first-principles calculations to investigate the stability of bi-axially strained \textit{Pnma} perovskite CaMnO$_3$ towards the formation of oxygen vacancies. Our motivation is provided by promising indications that novel material…

Materials Science · Physics 2013-08-28 Ulrich Aschauer , Reto Pfenninger , Sverre M. Selbach , Tor Grande , Nicola A. Spaldin

We report on the optical properties of magnetic cobalt-doped anatase phase titanium dioxide Ti_{1-x}Co_{x}O_{2-d} films for low doping concentrations, 0 <= x <= 0.02, in the spectral range 0.2 to 5 eV. For well oxygenated films (d << 1) the…

Strongly Correlated Electrons · Physics 2013-05-29 J. R. Simpson , H. D. Drew , S. R. Shinde , R. J. Choudhary , S. B. Ogale , T. Venkatesan

Copper-doped zinc sulphide (ZnS:Cu) thin films were synthesized through pulsed laser ablation in an inert background gas on stationary and rotating substrates, and a comprehensive opto-electrical characterisation is presented. The…

Although defects on graphene can degrade electron transport and its ability for use as a protection layer, they can also be helpful to tailor the local properties or activate new sites for particular adsorbates. Here, carbon vacancy defects…

Materials Science · Physics 2018-05-23 Tianbai Li , Jory A. Yarmoff