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Wave packet propagation succeeding electron transfer (ET) from alizarin dye molecules into the nanocrystalline TiO2 semiconductor has been studied by ultrafast transient absorption spectroscopy. Due to the ultrafast time scale of the ET…

Chemical Physics · Physics 2016-07-20 Robert Huber , Lars Dworak , Jacques E. Moser , Michael Grätzel , Josef Wachtveitl

We assess how quantum-mechanical effects associated with high-frequency chromophore vibrations influence excitation energy transfer in biological light-harvesting complexes. We begin with a mixed quantum-classical theory that combines a…

Chemical Physics · Physics 2025-01-07 Johan E. Runeson , David E. Manolopoulos

The dynamics of the excitation energy transfer (EET) in photosynthetic complexes is an interesting question both from the perspective of fundamental understanding and the research in artificial photosynthesis. Challenges persist in…

Chemical Physics · Physics 2024-06-25 Amartya Bose , Peter L. Walters

We theoretically investigate an exciton-coupled electron transfer (XCET) process that is conversion of an exciton into a charge transfer state. This conversion happens in an exciton transfer (XT) process, and the electron moves away in an…

Quantum Physics · Physics 2017-11-03 Souichi Sakamoto , Yoshitaka Tanimura

We provide physically intuitive mechanisms for the effect of noise on excitation energy transfer (EET) in networks. Using these mechanisms of dephasing-assisted transport (DAT) in a hybrid basis of both excitons and sites, we develop a…

Quantum Physics · Physics 2015-05-14 Alex W. Chin , Animesh Datta , Filippo Caruso , Susana F. Huelga , Martin B. Plenio

In the Review we discuss anomalous aspects of superconductivity (SC) and normal state, as well as formation of inhomogeneous (droplet-like or cluster-like) states in electron systems with attraction. We consider both the models with the…

Superconductivity · Physics 2025-08-26 M. Yu. Kagan , A. V. Krasavin , R. Sh. Ikhsanov , E. A. Mazur , A. P. Menushenkov

Two-dimensional optical spectroscopy experiments have shown that exciton transfer pathways in the Fenna-Matthews-Olson (FMO) photosynthetic complex differ drastically under reduced and oxidised conditions, suggesting a functional role for…

We simulate the long-range inter-complex electronic energy transfer in Photosystem II -- from the antenna complex, via a core complex, to the reaction center -- using a non-Markovian (ZOFE) quantum master equation description that allows us…

Chemical Physics · Physics 2016-07-27 Jan J. J. Roden , Doran I. G. Bennett , K. Birgitta Whaley

A first-principles coupled electron-nuclear dynamics simulation based on real-time, time-dependent density functional theory and Ehrenfest dynamics quantitatively repro-duces bimodal translational energy loss and angular distributions…

Chemical Physics · Physics 2025-12-05 Jialong Shi , Lingjun Zhu , Florian Nitz , Oliver Bünermann , Alec M. Wodtke , Hua Guo , Bin Jiang

Inclusive electron scattering off 4He is investigated for low and medium energy and momentum transfers. The final state interaction, given by the simple semirealistic Malfliet-Tjon potential, is treated rigorously applying the Lorentz…

Hydrogen-release by photoexcitation, excited-state- hydrogen-transfer (ESHT), is one of the important photo- chemical processes that occur in aromatic acids and is responsible for photoprotection of biomolecules. The mecha- nism is…

We investigate the effect of coherence to the excitation transfer efficiency (ETE) in photosynthetic bacteria Chlorobium Tepidum. We have modeled the monomer of Fenna-Matthews-Olson (FMO) complex as consisting of eight bacteriochlorophyll-a…

Biological Physics · Physics 2018-01-26 Davinder Singh , Shubhrangshu Dasgupta

In a disordered mesoscopic system, the typical spacing between the peaks and the valleys of the conductance as a function of Fermi energy $E_F$ is called the conductance energy correlation range $E_c$. Under the ergodic hypothesis, the…

Mesoscale and Nanoscale Physics · Physics 2009-10-31 Božidar Jovanović , Ziqiang Wang

The phenomenon of coherent energetic pulse propagation in exciton-phonon molecular chains such as $\alpha$-helix protein is studied using an ODE system model of Davydov-Scott type, both with numerical studies using a new unconditionally…

Biological Physics · Physics 2015-06-12 Brenton LeMesurier

We theoretically investigate the nonlinear optical response of a heterodimer comprising a semiconductor quantum dot strongly coupled to a metal nanoparticle. The quantum dot is considered as a three-level ladder system with ground,…

Mesoscale and Nanoscale Physics · Physics 2016-12-20 Bintoro S. Nugroho , Alexander A. Iskandar , Victor A. Malyshev , Jasper Knoester

A theory of electronic transport through molecular wires is applied to analyze characteristics of a long-range electron transfer (ET) through molecular bridges in macromolecules with complex donor/acceptor subsystems. Assuming a coherent…

Soft Condensed Matter · Physics 2007-05-23 Natalya A. Zimbovskaya

It is often intriguing experimentally to take stock of how conformational changes in the device configuration may impact the overall charge transport behavior of single-molecule junctions. Based on the allied approach of density functional…

Mesoscale and Nanoscale Physics · Physics 2020-02-06 Talem Rebeda Roy , Arijit Sen

Transition-metal nanoclusters exhibit structural and electronic properties that depend on their size, often making them superior to bulk materials for heterogeneous catalysis. However, their performance can be limited by sulfur poisoning.…

The Q-cycle mechanism plays an important role in the conversion of the redox energy into the energy of the proton electrochemical gradient across the biomembrane. The bifurcated electron transfer reaction, which is built into this…

Biological Physics · Physics 2013-03-19 Anatoly Yu. Smirnov , Franco Nori

We propose a scheme to simulate the exciton energy transfer (EET) of photosynthetic complexes in a quantum superconducting circuit system. Our system is composed of two pairs of superconducting charge qubits coupled to two separated high-Q…

Quantum Physics · Physics 2020-08-28 Ming-Jie Tao , Ming Hua , Na-Na Zhang , Wan-Ting He , Qing Ai , Fu-Guo Deng