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Related papers: GW approximation with self-screening correction

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We present a method to calculate the electronic charge density of periodic solids in the GW approximation, using the space-time method. We investigate for the examples of silicon and germanium to what extent the GW approximation is…

Condensed Matter · Physics 2009-10-31 Martin M. Rieger , R. W. Godby

The $GW$ approximation is a widely used method for computing electron addition and removal energies of molecules and solids. The computational effort of conventional $GW$ algorithms increases as $O(N^4)$ with the system size $N$, hindering…

Chemical Physics · Physics 2024-09-12 Mia Schambeck , Dorothea Golze , Jan Wilhelm

We describe an implementation of Hedin's GW approximation for molecules and clusters, the complexity of which scales as O(N^3) with the number of atoms. Our method is guided by two strategies: i) to respect the locality of the underlying…

Other Condensed Matter · Physics 2015-05-27 Dietrich Foerster , Peter Koval , Daniel Sánchez-Portal

We check the ab initio GW approximation and Bethe-Salpeter equation (BSE) many-body methodology against the exact solution benchmark of the hydrogen molecule H$_2$ ground state and excitation spectrum, and in comparison with the…

Chemical Physics · Physics 2021-01-27 Jing Li , Valerio Olevano

We present a diagrammatic approach to construct self-energy approximations within many-body perturbation theory with positive spectral properties. The method cures the problem of negative spectral functions which arises from a…

Other Condensed Matter · Physics 2015-06-22 G. Stefanucci , Y. Pavlyukh , A. -M. Uimonen , R. van Leeuwen

A few approximate schemes to solve the Hedin equations self-consistently introduced in (Phys. Rev. B 94, 155101 (2016)) are explored and tested for the 3D electron gas at metallic densities. We calculate one electron spectra, dielectric…

Strongly Correlated Electrons · Physics 2017-07-12 A. L. Kutepov , G. Kotliar

The quasiparticle self-consistent QS$GW$ approach incorporates the corrections of the quasiparticle energies from their Kohn-Sham density functional theory (DFT) eigenvalues by means of an energy independent and Hermitian self-energy matrix…

Materials Science · Physics 2022-06-08 Ozan Dernek , Dmitry Skachkov , Walter R. L. Lambrecht , Mark van Schilfgaarde

We present a new all-electron, augmented-wave implementation of the GW approximation using eigenfunctions generated by a recent variant of the full-potential LMTO method. The dynamically screened Coulomb interaction W is expanded in a mixed…

Materials Science · Physics 2009-11-07 Takao Kotani , Mark van Schilfgaarde

Two self-consistent schemes involving Hedin's $GW$ approximation are studied for a set of sixteen different atoms and small molecules. We compare results from the fully self-consistent $GW$ approximation (SC$GW$) and the quasi-particle…

Materials Science · Physics 2015-06-19 Peter Koval , Dietrich Foerster , Daniel Sánchez-Portal

We report an exhaustive study of the performance of different variants of Green function methods for the spherium model in which two electrons are confined to the surface of a sphere and interact via a genuine long-range Coulomb operator.…

Chemical Physics · Physics 2018-07-23 Pierre-François Loos , Pina Romaniello , J. A. Berger

With the aim of identifying universal trends, we compare fully self-consistent electronic spectra and total energies obtained from the GW approximation with those from an extended GWGamma scheme that includes a nontrivial vertex function…

Materials Science · Physics 2007-05-23 Arno Schindlmayr , Thomas J. Pollehn , R. W. Godby

We present an implementation of the GW approximation for the electronic self-energy within the full-potential linearized augmented-plane-wave (FLAPW) method. The algorithm uses an all-electron mixed product basis for the representation of…

Materials Science · Physics 2010-11-15 Christoph Friedrich , Stefan Blügel , Arno Schindlmayr

The Gutzwiller approximate solution to the Gutzwiller wavefunction yields exact results for the Gutzwiller wavefunction in the infinite dimensional limit. Implicit in the Gutzwiller approximation is an approximate local form of the fermion…

Strongly Correlated Electrons · Physics 2009-07-27 Balazs Hetenyi , Hans Gerd Evertz , Wolfgang von der Linden

Excited-state calculations, notably for quasiparticle band structures, are nowadays routinely performed within the GW approximation for the electronic self-energy. Nevertheless, certain numerical approximations and simplifications are still…

We perform $GW$ calculations on atoms and diatomic molecules at different levels of self-consistency and investigate the effects of self-consistency on total energies, ionization potentials and on particle number conservation. We further…

Other Condensed Matter · Physics 2015-05-13 Adrian Stan , Nils Erik Dahlen , Robert van Leeuwen

In approximate density functional theory (DFT), the self-interaction error is an electron delocalization anomaly associated with underestimated insulating gaps. It exhibits a predominantly quadratic energy-density curve that is amenable to…

Chemical Physics · Physics 2016-12-21 Glenn Moynihan , Gilberto Teobaldi , David D. O'Regan

The GW approximation has been widely accepted as an ab initio tool for calculating defect levels with many-electron effect included. However, the GW simulation cost increases dramatically with the system size, and, unfortunately, large…

Materials Science · Physics 2023-10-04 Du Li , Zhen-Fei Liu , Li Yang

An efficient all-electron G$^0$W$^0$ method and a quasiparticle selfconsistent GW (QSGW) method for molecules are proposed in the molecular orbital space with the full random phase approximation. The convergence with basis set is examined.…

Mesoscale and Nanoscale Physics · Physics 2015-03-17 San-Huang Ke

Self-consistent solutions of Hedin's diagrammatic theory equations (HE) for the two-site Hubbard Model (HM) have been studied. They have been found for three-point vertices of increasing complexity ($\Gamma=1$ (GW approximation),…

Strongly Correlated Electrons · Physics 2016-05-27 A. L. Kutepov

We scrutinize the behaviour of hydrogen atom's eigenvalues in a quantum plasma as it interacts with electric field directed along $\theta=\pi$ and exposed to linearly polarized intense laser field radiation. Using the Kramers-Henneberger…

Quantum Physics · Physics 2016-10-14 Babatunde James Falaye , Guo-Hua Sun , Muhammed S. Liman , K. J. Oyewumi , Shi-Hai Dong