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In this article we extend the theory of ultra-long-range giant dipole molecules, formed by an atom in a giant dipole state and a ground-state alkali atom, by angular-momentum couplings known from recent works on Rydberg molecules. In…

Atomic Physics · Physics 2018-02-14 Thomas Stielow , Stefan Scheel , Markus Kurz

We investigate the impact of combined electric and magnetic fields on the structure of ultralong-range polar Rydberg molecules. Our focus is hereby on the parallel as well as the crossed field configuration taking into account both the…

Atomic Physics · Physics 2014-09-11 Markus Kurz , Peter Schmelcher

We investigate the electronic structure of a triatomic Rydberg molecule formed by a Rydberg atom and two neutral ground-state atoms. Taking into account the $s$-wave and $p$-wave interactions we perform electronic structure calculations and…

Atomic Physics · Physics 2016-06-22 Javier Aguilera Fernández , Peter Schmelcher , Rosario González-Férez

We theoretically investigate the properties of highly polar diatomic molecules containing $^2S$-state transition-metal atoms. We calculate potential energy curves, permanent electric dipole moments, spectroscopic constants, and leading…

Atomic Physics · Physics 2021-02-16 Michał Śmiałkowski , Michał Tomza

We investigate the impact of an electric field on the structure of ultralong-range polar diatomic Rydberg molecules. Both the s-wave and p-wave interactions of the Rydberg electron and the neutral ground state atom are taken into account.…

Atomic Physics · Physics 2015-06-15 Markus Kurz , Peter Schmelcher

Doubly polar molecules, possessing an electric dipole moment and a magnetic dipole moment, can strongly couple to both an external electric field and a magnetic field, providing unique opportunities to exert full control of the system…

Atomic Physics · Physics 2019-11-06 Hui Li , Goulven Quéméner , Jean-François Wyart , Olivier Dulieu , Maxence Lepers

The internal electric field of a Rydberg atom electron can bind a polar molecule to form a giant ultralong-range stable polyatomic molecule. Such molecules not only share their properties with Rydberg atoms, they possess huge permanent…

Atomic Physics · Physics 2015-05-27 Seth T. Rittenhouse , M. Mayle , P. Schmelcher , H. R. Sadeghpour

We consider ultralong-range polyatomic Rydberg molecules formed by combining a Rydberg cesium atom and a ground-state RbCs molecule. We explore the regime where the charge-dipole interaction due to the Rydberg electron with the diatomic…

We investigate theoretically the long-range electrostatic interactions between a ground-state homonuclear alkali-metal dimer and an excited alkali-metal atom taking into account its fine-structure. The interaction involves the combination…

Chemical Physics · Physics 2017-09-13 Maxence Lepers , Olivier Dulieu

Multi-electron giant dipole resonances of atoms in crossed electric and magnetic fields are investigated. Stationary configurations corresponding to a highly symmetric arrangement of the electrons on a decentered circle are derived, and a…

Atomic Physics · Physics 2011-02-24 Sascha Zoellner , Hans-Dieter Meyer , Peter Schmelcher

We show that the dipole-dipole interaction between two Rydberg atoms can give rise to long range molecules. The binding potential arises from two states that converge to different separated atom asymptotes. These states interact weakly at…

Atomic Physics · Physics 2015-06-05 Martin Kiffner , Hyunwook Park , Wenhui Li , Tom F. Gallagher

We show that the electric dipole-dipole interaction between a pair of polar molecules undergoes an all-out transformation when superimposed by a far-off resonant optical field. The combined interaction potential becomes tunable by variation…

Atomic Physics · Physics 2015-05-30 Mikhail Lemeshko , Bretislav Friedrich

A scheme for non-conditional generation of long-living maximally entangled states between two spatially well separated atoms is proposed. In the scheme, $\Lambda$-type atoms pass a resonator-like equipment of dispersing and absorbing…

Quantum Physics · Physics 2016-08-16 Özgür Çakir , Ho Trung Dung , Ludwig Knöll , Dirk-Gunnar Welsch

We predict that ultralong-range Rydberg bi-molecules form in collisions between polar molecules in cold and ultracold settings. The collision of $\Lambda$-doublet nitric oxide (NO) with long-lived Rydberg NO($nf$, $ng$) molecules forms…

Atomic Physics · Physics 2021-02-03 Rosario Gonzalez-Ferez , Janine Shertzer , H. R. Sadeghpour

We explore the external electric field control of a species of ultralong-range molecules that emerge from the interaction of a ground state polar molecule with a Rydberg atom. The external field mixes the Rydberg electronic states and…

Atomic Physics · Physics 2012-06-01 M. Mayle , S. T. Rittenhouse , P. Schmelcher , H. R. Sadeghpour

Multi-electron giant dipole resonances of atoms in crossed electric and magnetic fields are investigated. Stationary configurations corresponding to a highly symmetric arrangement of the electrons on a decentered circle are derived, and a…

Atomic Physics · Physics 2011-02-24 S. Zöllner , H. -D. Meyer , P. Schmelcher

In this study, we investigate the structure of the polar alkali-Strontium diatomic molecules as possible candidates for the realization of samples of new species of ultracold polar molecules. Using a quantum chemistry approach based on…

Atomic and Molecular Clusters · Physics 2015-05-19 Romain Guérout , Mireille Aymar , Olivier Dulieu

Up to date, the life time of experimentally demonstrated entangled states has been limited, due to their fragility under decoherence and dissipation. Therefore, they are created under strict isolation conditions. In contrast, new approaches…

Quantum Physics · Physics 2013-05-29 Christine A. Muschik , Eugene S. Polzik , J. Ignacio Cirac

The discrete and charge-separated nature of matter - electrons and nuclei - results in local electrostatic fields that are ubiquitous in nanoscale structures and are determined by their shape, material, and environment. Such fields are…

We investigate theoretically the combination of first-order quadrupole-quadrupole and second-order dipole-dipole effects on the long-range electrostatic interactions between a ground-state homonuclear alkali-metal dimer and an excited…

Quantum Physics · Physics 2017-04-19 Maxence Lepers , Olivier Dulieu
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