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The Jarzynski equality allows the calculation of free-energy differences using values of work measured from nonequilibrium trajectories. The number of trajectories required to accurately estimate free-energy differences in this way grows…

Statistical Mechanics · Physics 2025-05-13 Stephen Whitelam

Using methods of phenomenological non-equilibrium thermodynamics, the proof is performed that Jarzynski's equality is only valid in the reversible limit and that a conclusion to non-equilibrium inequalities concerning free energy and work…

Mathematical Physics · Physics 2013-07-02 Wolfgang Muschik

We show that the general two-variable Langevin equations with inhomogeneous noise and friction can generate many different forms of power-law distributions. By solving the corresponding stationary Fokker-Planck equation, we can obtain a…

Statistical Mechanics · Physics 2015-08-10 Jiulin Du

Brownian dynamics simulations are used to study the detachment of a particle from a substrate. Although the model is simple and generic, we attempt to map its energy, length and time scales onto a specific experimental system, namely a bead…

Soft Condensed Matter · Physics 2021-01-08 Emma Hodges , B. M. Cooke , E. M. Sevick , Debra J. Searles , B. Duenweg , J. Ravi Prakash

We show how Jarzynski relation can be exploited to analyze the nature of order-disorder and a bifurcation type dynamical transition in terms of a response function derived on the basis of work distribution over non-equilibrium paths between…

Chemical Physics · Physics 2015-06-05 Pulak Kumar Ghosh , Deb Shankar Ray

We study nonequilibrium work relations for a space-dependent field with stochastic dynamics (Model A). Jarzynski's equality is obtained through symmetries of the dynamical action in the path integral representation. We derive a set of exact…

Statistical Mechanics · Physics 2011-02-18 Kirone Mallick , Moshe Moshe , Henri Orland

The dynamical property of the Tsallis distribution is studied from a Fokker-Planck equation. For the Langevin dynamical system with an arbitrary potential function, Markovian friction and Gaussian white noise, we show that no possible…

Statistical Mechanics · Physics 2015-08-19 Jiulin Du

We give a quantum version of the Jarzynski relation between the distribution of work done over a certain time-interval on a system and the difference of equilibrium free energies. The main new ingredient is the identification of work…

Condensed Matter · Physics 2015-05-26 Wojciech De Roeck , Christian Maes

We show that work distributions and non-equilibrium work fluctuation theorems can be measured in optical spectra for a wide class of quantum systems. We consider systems where the absorption or emission of a photon corresponds to the sudden…

Statistical Mechanics · Physics 2012-07-10 Markus Heyl , Stefan Kehrein

Fluctuation theorems, such as the Jarzynski equality and the Crooks relation, are effective tools connecting non-equilibrium work statistics and equilibrium free energy differences. However, detailed hands-on, reproducible protocols for…

We develop a method using a coarse graining of the energy fluctuations of an equilibrium quantum system which produces simple parameterizations for the behaviour of the system. As an application, we use these methods to gain more…

Statistical Mechanics · Physics 2007-05-23 Jani Lukkarinen

In this note we review recent progress about fluctuation relations and their applicability to free energy recovery in single molecule experiments. We underline the importance of the operational definition for the mechanical work and the…

Statistical Mechanics · Physics 2015-05-27 Anna Alemany , Marco Ribezzi , Felix Ritort

In this paper we investigate the applicability of non-equilibrium statistical mechanics to non-equilibrium damage phenomena. As an example, a fiber-bundle model with thermal noise and a fiber-bundle model with decay of fibers are…

Statistical Mechanics · Physics 2009-05-25 S. G. Abaimov

We calculate the fluctuation of the energy of a system in Tsallis statistics following the finite heat bath canonical ensemble approach. We obtain this fluctuation as the second derivative of the logarithm of the partition function plus an…

Statistical Mechanics · Physics 2009-11-07 F. Q. Potiguar , U. M. S. Costa

The Jarzynski equality and the fluctuation theorem relate equilibrium free energy differences to non-equilibrium measurements of the work. These relations extend to single-molecule experiments that have probed the finite-time thermodynamics…

Statistical Mechanics · Physics 2008-08-30 Paul Maragakis , Felix Ritort , Carlos Bustamante , Martin Karplus , Gavin E. Crooks

We derive the nonequilibrium transient state work fluctuation theorem and also the Jarzynski equality for a classical harmonic oscillator linearly coupled to a harmonic heat bath, which is dragged by an external agent. Coupling with the…

Statistical Mechanics · Physics 2012-07-09 Rajarshi Chakrabarti

We consider classical, interacting particles coupled to a thermal reservoir and subject to a local, time-varying potential while undergoing hops on a lattice. We impose detailed balance on the hopping rates and map the dynamics to the Fock…

Statistical Mechanics · Physics 2024-05-08 Andrew J. Baish , Benjamin P. Vollmayr-Lee

The past twenty years have seen a resurgence of interest in nonequilibrium thermodynamics, thanks to advances in the theory of stochastic processes and in their thermodynamic interpretation. Fluctuation theorems provide fundamental…

Statistical Mechanics · Physics 2017-11-16 Robert Marsland , Jeremy England

We identify the conditions under which a stochastic driving inducing energy changes on a system coupled to a thermal bath can be treated as a work source. When these conditions are met, the work statistics satisfies the Crooks fluctuation…

Statistical Mechanics · Physics 2015-06-18 Gatien Verley , Christian Van den Broeck , Massimiliano Esposito

Starting out from the recently established quantum correlation function expression of the characteristic function for the work performed by a force protocol on the system [cond-mat/0703213] the quantum version of the Crooks fluctuation…

Statistical Mechanics · Physics 2007-06-21 Peter Talkner , Peter Hanggi
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