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In the presence of a confining potential $V$, the eigenfunctions of a continuous Schr\"odinger operator $-\Delta +V$ decay exponentially with the rate governed by the part of $V$ which is above the corresponding eigenvalue; this can be…

Mathematical Physics · Physics 2021-05-05 Marcel Filoche , Svitlana Mayboroda , Terence Tao

The present contribution concerns the computation of energy eigenvalues of a perturbed anharmonic coulombic potential with irregular singularities using a combination of the Sinc collocation method and the double exponential transformation.…

Numerical Analysis · Mathematics 2019-01-04 M. Essaouini , B. Abouzaid , P. Gaudreau , H. Safouhi

By performing the canonical quantization of the Abelian Chern-Simons model on the light-front (as suggested by Dirac), we clarify some controversies appearing in recent papers that discuss the relation between the existence of excitations…

High Energy Physics - Theory · Physics 2009-10-31 L. R. U. Manssur

In the literature of calculating atomic and molecular structures, most Schrodinger equations are described by Coulomb potential. However, there are also a few literatures that discuss some magnetic correction methods, such as Pauli and…

Quantum Physics · Physics 2023-12-29 Yu-kuo Zhao , Yu-xin Dong

For a given many-electron molecule, it is possible to define a corresponding one-electron Schr\"odinger equation, using potentials derived from simple atomic densities, whose solution predicts fairly accurate molecular orbitals for single-…

Chemical Physics · Physics 2022-05-16 Jerry L. Whitten

We present a self-contained description of the wave-function matching (WFM) method to calculate electronic quantum transport properties of nanostructures using the Landauer-B\"uttiker approach. The method is based on a partition of the…

Mesoscale and Nanoscale Physics · Physics 2019-08-28 Tatiane P. Santos , Leandro R. F. Lima , Caio H. Lewenkopf

Simulating a quantum system is more efficient on a quantum computer than on a classical computer. The time required for solving the Schr\"odinger equation to obtain molecular energies has been demonstrated to scale polynomially with system…

Quantum Physics · Physics 2019-03-27 Hefeng Wang , Sabre Kais , Alán Aspuru-Guzik , Mark R. Hoffmann

The virial theorem is a nice property for the linear Schrodinger equation in atomic and molecular physics as it gives an elegant ratio between the kinetic and potential energies and is useful in assessing the quality of numerically computed…

Analysis of PDEs · Mathematics 2016-08-23 Tai-Chia Lin , Milivoj R. Belic , Milan S. Petrovic , Hichem Hajaiej , Goong Chen

In order to rigorously evaluate the energy and dipole moment of a certain configuration of molecules one needs to solve the Schr\"odinger equation. Repeating this for many different configurations allows one to determine the potential…

Soft Condensed Matter · Physics 2015-06-01 Carlos Vega

In this letter new, closed and compact analytic expressions for the evaluation of resonant energies, resonant bound-states, eigenvalues and eigenfunctions for both scattering and bounded $n$-cell systems are reported. It is shown that for…

Soft Condensed Matter · Physics 2016-08-31 Pedro Pereyra

In this paper, we propose an algorithm to construct coherent states for an exactly solvable position dependent mass Schr\"odinger equation. We use point canonical transformation method and obtain ground state eigenfunction of the position…

Quantum Physics · Physics 2010-03-16 V Chithiika Ruby , M Senthilvelan

We derive a semiclassical expression for an energy smoothed autocorrelation function defined on a group of eigenstates of the Schr\"odinger equation. The system we considered is an energy-conserved Hamiltonian system possessing…

Chaotic Dynamics · Physics 2009-11-07 Baowen Li , Daniel C Rouben

Schr\"odinger equation for two center Coulomb plus harmonic oscillator potential is solved by the method of ethalon equation at large intercenter separations. Asymptotical expansions for energy term and wave function are obtained in the…

Quantum Physics · Physics 2009-10-31 D. Matrasulov

We introduce a machine learning model to predict atomization energies of a diverse set of organic molecules, based on nuclear charges and atomic positions only. The problem of solving the molecular Schr\"odinger equation is mapped onto a…

In this paper, we compute the eigenvalue problem (EVP) for the semiclassical random Schr\"odinger operators, where the random potentials are parameterized by an infinite series of random variables. After truncating the series, we introduce…

Numerical Analysis · Mathematics 2025-02-12 Panchi Li , Zhiwen Zhang

We use the Chapman-Enskog method to derive the Smoluchowski equation from the Kramers equation in a high friction limit. We consider two main extensions of this problem: we take into account a uniform rotation of the background medium and…

Statistical Mechanics · Physics 2009-11-10 Pierre-Henri Chavanis , Philippe Laurencot , Mohammed Lemou

The factorization method of Schrodinger shows us how to determine the energy eigenstates without needing to determine the wavefunctions in position or momentum space. A strategy to convert the energy eigenstates to wavefunctions is well…

Quantum Physics · Physics 2023-12-18 Joseph R. Noonan , Maaz ur Rehman Shah , Luogen Xu , James. K. Freericks

The impact of targeted replacement of individual terms in empirical force fields is quantitatively assessed for pure water, dichloromethane (DCM), and solvated K$^+$ and Cl$^-$ ions. For the electrostatics, point charges (PCs) and machine…

Chemical Physics · Physics 2023-11-13 Mike Devereux , Eric D. Boittier , Markus Meuwly

Exact solution of Schrodinger equation for the pseudoharmonic potential is obtained for an arbitrary angular momentum. The energy eigenvalues and corresponding eigenfunctions are calculated by Nikiforov-Uvarov method. Wavefunctions are…

Quantum Physics · Physics 2008-11-26 Cevdet Tezcan , Metin Aktas , Ozlem Yesiltas Ramazan Sever

We build an efficient and unitary (hence stable) method for the solution of the semi-classical Schr\"odinger equation subject with explicitly time-dependent potentials. The method is based on a combination of the Zassenhaus decomposition…

Numerical Analysis · Mathematics 2016-02-12 Philipp Bader , Arieh Iserles , Karolina Kropielnicka , Pranav Singh