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Ferroelectric materials are characterized by a spontaneous polar distortion. The behavior of such distortions in the presence of free charge is the key to the physics of metallized ferroelectrics in particular, and of structurally-polar…

We propose a theoretical and computational approach to investigate temporal behavior of a nonlinear polarization in perturbative regime induced by an intense and ultrashort pulsed electric field. First-principles time-dependent density…

Optics · Physics 2019-03-27 Mitsuharu Uemoto , Yuki Kuwabara , Shunsuke A. Sato , Kazuhiro Yabana

We present an approach to electronic polarization in molecular solids treated as a set of quantum systems interacting classically. Individual molecules are dealt with rigorously as quantum-mechanical systems subject to classical external…

Condensed Matter · Physics 2009-11-07 E. V. Tsiper , Z. G. Soos

Density functional theory (DFT) is used to rationalize magnetic parameters of hydrated electron trapped in alkaline glasses as observed using Electron Paramagnetic Resonance (EPR) and Electron Spin Echo Envelope Modulation (ESEEM)…

General Physics · Physics 2016-09-28 I. A. Shkrob

Thin films of aluminum hafnium nitride (Al$_{1-x}$Hf$_{x}$N) were synthesized via reactive magnetron sputtering for Hf contents up to $x$ = 0.13. X-ray diffraction showed a single $c$-axis oriented wurtzite phase for all films. Hard X-ray…

We discuss a non-perturbative, technically straightforward, easy-to-use, and computationally affordable method, based on polarization theory, for the calculation of the electronic dielectric constant of insulating solids at the first…

Materials Science · Physics 2009-10-31 Fabio Bernardini , Vincenzo Fiorentini

The method has been developed to calculate effects of polarization not only for a atomic core in a field of valent electron, but also polarization of atom as a whole in the electron-hole formalism. A secondary quantized density matrix for…

Quantum Physics · Physics 2007-05-23 Halina V. Grushevskaya , Leonid I. Gurskii

Polarization arising from non-centrosymmetric wurtzite lattice underpins the physics and functionality of gallium nitride (GaN)-the most produced semiconductor materials second only to silicon. However, recent direct experimental…

Materials Science · Physics 2024-07-25 Ding Wang , Danhao Wang , Samuel Yang , Zetian Mi

Ion clustering has been proposed as a mechanism leading to the peculiar 'anomalous underscreening' phenomenon seen for electrostatic interactions between charge surfaces immersed in concentrated electrolytes. These interactions have been…

Soft Condensed Matter · Physics 2025-12-01 Clifford E. Woodward , David Ribar , Jan Forsman

The technique of polarized neutron scattering is reviewed with emphasis on applications. Many examples of the usefulness of the method in various fields of physics are given like the determination of spin density maps, measurement of…

Strongly Correlated Electrons · Physics 2007-05-23 B. Roessli , P. Böni

By means of ab initio calculations within the density functional theory (DFT) electronic and magnetic properties of BaTiO3/LaMnO3 interface were investigated. An impact of ferroelectric overlayer thickness onto the interface properties was…

Materials Science · Physics 2022-06-07 Irina Piyanzina , Rinat Mamin

Recent studies highlight the scientific importance and broad application prospects of two-dimensional (2D) sliding ferroelectrics, which prevalently exhibit vertical polarization with suitable stackings. It is crucial to understand the…

Materials Science · Physics 2024-07-23 Shihan Deng , Hongyu Yu , Junyi Ji , Changsong Xu , Hongjun Xiang

Practical density functional theory (DFT) owes its success to the groundbreaking work of Kohn and Sham that introduced the exact calculation of the non-interacting kinetic energy of the electrons using an auxiliary mean-field system.…

Chemical Physics · Physics 2023-11-17 P. del Mazo-Sevillano , J. Hermann

The spontaneous polarization of wurtzite III-V nitrides XN (X=Al, Ga, In) and II-VI oxides YO (Y=Be, Zn) is investigated via first-principles computational methods. The modern treatment defines this quantity as the polarization difference…

We investigate the polarization properties of emission associated with the magnetic dipole and electric dipole transitions of europium(III) coupled to an anisotropic dielectric metasurface with polarization-engineered electric and magnetic…

The dielectric properties of molecules or nanostructures are usually modified in a complex manner, when assembled into a condensed phase. We propose a first-principles method to compute polarizabilities of sub-entities of solids and…

Chemical Physics · Physics 2018-09-10 Ding Pan , Marco Govoni , Giulia Galli

Electric field noise in proximity to metallic surfaces is a poorly understood phenomenon that appears in different areas of physics. Trapped ion quantum information processors are particular susceptible to this noise, leading to motional…

Quantum Physics · Physics 2015-05-07 Philipp Schindler , Dylan J Gorman , Nikos Daniilidis , Hartmut Häffner

Electronic density of states (DOS) is a key factor in condensed matter physics and material science that determines the properties of metals. First-principles density-functional theory (DFT) calculations have typically been used to obtain…

Materials Science · Physics 2019-04-12 Byung Chul Yeo , Donghun Kim , Chansoo Kim , Sang Soo Han

Dynamical Mean-Field Theory (DMFT) has established itself as a reliable and well-controlled approximation to study correlation effects in bulk solids and also two-dimensional systems. In combination with standard density-functional theory…

Atomic and Molecular Clusters · Physics 2015-05-30 V. Turkowski , A. Kabir , N. Nayyar , Talat S. Rahman

Density-functional Theory (DFT) approaches have recently been used to judge the topological order of various materials despite its well-known band gap underestimation. Use of the more accurate quasi-particle GW approach reveals here few…

Materials Science · Physics 2015-05-27 Julien Vidal , Xiuwen Zhang , Liping Yu , Jun-Wei Luo , Alex Zunger