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We report on the lattice evolution of BiFeO3 as function of temperature using far infrared emissivity, reflectivity, and X-ray absorption local structure. A power law fit to the lowest frequency soft phonon in the magnetic ordered phase…

The strain dependence of electric and magnetic properties has been widely investigated, both from a fundamental science perspective and an applications point of view. Electromechanical coupling through field-induced polarization rotation…

Materials Science · Physics 2015-06-22 Zhiguang Wang , Yaojin Wang , Haosu Luo , Jiefang Li , D. Viehland

In multiferroic BiFeO3 thin films grown on highly mismatched LaAlO3 substrates, we reveal the coexistence of two differently distorted polymorphs that leads to striking features in the temperature dependence of the structural and…

Transmission electron microscopy study of tetragonal-like BiFeO3 films reveals a hitherto unreported hierarchical nanodomain structure. The 30-50 nm wide stripe domains with {110} domain walls consist of a substructure of lamellar…

Materials Science · Physics 2015-06-03 Yajun Qi , Zuhuang Chen , Lihua Wang , Xiaodong Han , Junling Wang , Thirumany Sritharan , Lang Chen

The structural and ferroelectric domain variants of highly-strained BiFeO3 films grown on vicinal LaSrAlO4 substrates were studied by piezoelectric force microscopy and high-resolution X-ray reciprocal space mapping. Through symmetry…

Materials Science · Physics 2015-06-04 Lu You , Shintaro Yasui , Xi Zou , Hui Ding , Zuhuang Chen , Weigang Chen , Lang Chen , Hiroshi Funakubo , Junling Wang

Al2O3 thin films have been deposited at substrate temperatures between 500{\deg}C to 600{\deg}C by reactive magnetron sputtering using an additional arbitrary substrate bias to tailor the energy distribution of the incident ions. The films…

We present molecular dynamics simulations of a realistic model of an ultrathin film of BaTiO$_3$ sandwiched between short-circuited electrodes to determine and understand effects of film thickness, epitaxial strain and the nature of…

Materials Science · Physics 2009-11-13 Jaita Paul , Takeshi Nishimatsu , Y. Kawazoe , Umesh V. Waghmare

Ba(Fe1-xCox)2As2 superconducting thin films have been grown on SrTiO3, (La,Sr)(Al,Ta)O3, LaAlO3 and YAlO3 (YAO) single crystal substrates by pulsed laser deposition. All the films, except on YAO, have been grown epitaxially without buffer…

Superconductivity · Physics 2009-11-13 K. Iida , J. Haenisch , R. Huehne , F. Kurth , M. Kidszun , S. Haindl , J. Werner , L. Schultz , B. Holzapfel

We present a synchrotron grazing incidence x-ray diffraction analysis of the domain structure and polar symmetry of highly strained BiFeO3 thin films grown on LaAlO3 substrate. We revealed the existence of periodic elastic nanodomains in…

The structural transition at about 1000 {\deg}C, from the hexagonal to the orthorhombic phase of LuFeO3, has been investigated in thin films of LuFeO3. Separation of the two structural phases of LuFeO3 occurs on a length scale of…

Materials Science · Physics 2016-06-13 Shi Cao , Xiaozhe Zhang , Kishan Sinha , Wenbin Wang , Jian Wang , Peter A. Dowben , Xiaoshan Xu

We report the epitaxial growth of BiFeO3 by pulsed electron deposition and the resulting crystal quality, magnetic and nanoscale switching properties. X-ray diffraction shows high quality single phase, epitaxial (001) oriented films grown…

Materials Science · Physics 2015-06-12 Hongxue Liu , Ryan Comes , Yonghang Pei , Jiwei Lu , Stuart Wolf

BiFeO3 (BFO) multiferroic oxide has a complex phase diagram that can be mapped by appropriately substrate-induced strain in epitaxial films. By using Raman spectroscopy, we conclusively show that films of the so-called supertetragonal T-BFO…

Materials Science · Physics 2011-08-16 J. Kreisel , P. Jadhav , O. Chaix-Pluchery , M. Varela , N. Dix , F. Sanchez , J. Fontcuberta

SrTiO$_3$ thin films were used as a model system to study the effects of strain and epitaxial constraint on structural phase transitions of perovskite films. The basic phenomena revealed will apply to a variety of important structural…

Other Condensed Matter · Physics 2007-05-23 Feizhou He , B. O. Wells , S. M. Shapiro

The discovery of high-temperature superconductivity in bulk La$_3$Ni$_2$O$_7$ under high hydrostatic pressure and, more recently, biaxial compression in epitaxial thin films has ignited significant interest in understanding the interplay…

The authors report on the interplay between magnetically ordered phases with temperature and magnetic field across compressively strained interfaces of thin La0.67Sr0.33MnO3 films on LaAlO3 substrates. From the temperature dependence of the…

Applied Physics · Physics 2019-03-04 Arjan A. Burema , Job J. L. van Rijn , Tamalika Banerjee

BiFeO3 thin films with various thicknesses were grown epitaxially on (001) LaSrAlO4 single crystal substrates using pulsed laser deposition. High resolution x-ray diffraction measurements revealed that a tetragonal-like phase with c-lattice…

Materials Science · Physics 2011-01-10 Zuhuang Chen , Lu You , Chuanwei Huang , Yajun Qi , Junling Wang , Thirumany Sritharan , Lang Chen

A thermodynamic theory is developed for dense laminar domain structures in epitaxial ferrolectric films. It is found that, at some critical misfit strain between the film and substrate, the 90 degrees c/a/c/a domain structure becomes…

Materials Science · Physics 2009-10-31 N. A. Pertsev , V. G. Koukhar

The influence of La and Nd co-substitution on the structural and magnetic properties of BiFeO3 (BFO) thin films was examined. Epitaxial thin films of pure and, La and Nd co-doped BFO on the SrRuO3 buffered single crystal SrTiO3 (001)…

Materials Science · Physics 2013-06-19 Anju Ahlawat , S. Satapathy , V. G. Sathe , R. J. Choudhary , M. K. Singh , Ravi Kumar , T. K. Sharma , P. K. Gupta

The ferromagnetic properties of epitaxial La$_{0.5}$Sr$_{0.5}$CoO$_3$ thin films have been studied. The magnetic transition is affected by both strain and finite thickness. We have used a series of films of different thickness and on…

Materials Science · Physics 2009-11-13 Changkun Xie , J. I. Budnick , B. O. Wells , J. C. Woicik

The interrelation between the epitaxial strain and oxygen deficiency in La0.7Ca0.3MnO3-{\delta} thin films was studied in terms of structural and functional properties. The films with a thickness of 1000{\AA} were prepared using a PLD…

Materials Science · Physics 2015-06-23 K. Kawashima , G. Logvenov , G. Christiani , H. -U. Habermeier