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Motivated by recent experimental suggestions of charge-order-driven ferroelectricity in organic charge-transfer salts, such as $\kappa$-(BEDT-TTF)$_2$Cu[N(CN)$_2$]Cl, we investigate magnetic and charge-ordered phases that emerge in an…

Strongly Correlated Electrons · Physics 2017-10-30 Ryui Kaneko , Luca F. Tocchio , Roser Valentí , Federico Becca

We theoretically investigate the effects of charge order and spin frustration on the spin ordering in TMTTF salts. Using first-principles band calculations, we find that a diagonal inter-chain transfer integral $t_{q1}$, which causes spin…

Strongly Correlated Electrons · Physics 2012-02-06 Kazuyoshi Yoshimi , Hitoshi Seo , Shoji Ishibashi , Stuart E. Brown

Using a combination of Density Functional Theory, mean-field analysis and exact diagonalization calculations we reveal the emergence of a dimerized charge ordered state in TMTTF$_2$-PF$_6$ organic crystal. The interplay between charge and…

Strongly Correlated Electrons · Physics 2015-03-19 Gianluca Giovannetti , Sanjeev Kumar , Jean-Paul Pouget , Massimo Capone

The family of molecular conductors TMTTF/TMTSF-X demonstrates almost all known electronic phases in parallel with a set of weak structural modifications of anion ordering and mysterious structureless transitions. Only in early 2000's their…

Strongly Correlated Electrons · Physics 2007-05-23 Serguei Brazovskii

Charge order affects most of the electronic properties but is believed not to alter the spin arrangement since the magnetic susceptibility remains unchanged. We present electron-spin-resonance experiments on quasi-one-dimensional (TMTTF)2X…

Strongly Correlated Electrons · Physics 2013-03-19 M. Dressel , M. Dumm , T. Knoblauch , B. Köhler , B. Salameh , S. Yasin

(TMTTF)2AsF6 and (TMTTF)2SbF6 are both known to undergo a charge ordering phase transition, though their ground states are different. The ground state of the first is Spin-Peierls, and the second is an antiferromagnet. We study the effect…

Strongly Correlated Electrons · Physics 2009-11-10 W. Yu , F. Zamborszky , B. Alavi , A. Baur , C. A. Merlic , S. E. Brown

Charge-ordering phenomena have been highly topical over the last few years. A phase transition towards a charge ordered state has been observed experimentally in several classes of materials. Among them, many studies have been devoted to…

Strongly Correlated Electrons · Physics 2013-08-01 Mariano de Souza , Jean-Paul Pouget

The quasi-one-dimensional organic conductors (TMTTF)$_2X$ with non-centrosymmetric anions commonly undergo charge- and anion-order transitions upon cooling. While for compounds with tetrahedral anions ($X$ = BF$_4^-$, ReO$_4^-$, and…

Strongly Correlated Electrons · Physics 2021-04-23 Olga Iakutkina , Lena Nadine Majer , Guilherme Gorgen Lesseux , Gabriele Untereiner , Martin Dressel

We have investigated the charge ordering phase of the quasi one dimensional quantum antiferromagnet (TMTTF)$_2X$ ($X=$ SbF$_6$, AsF$_6$ and PF$_6$) using high fields/frequencies electron paramagnetic resonance. In addition to the uniform…

Strongly Correlated Electrons · Physics 2021-05-07 C-E Dutoit , A. Stepanov , J. VanTol , M. Orio , S. Bertaina

Using one- and two-dimensional NMR spectroscopy applied to $^{13}$C spin-labeled (TMTTF)$_2$AsF$_6$ and (TMTTF)$_2$PF$_6$, we demonstrate the existence of an intermediate charge-ordered phase in the TMTTF family of charge-transfer salts. At…

Strongly Correlated Electrons · Physics 2009-10-31 D. S. Chow , F. Zamborszky , B. Alavi , D. J. Tantillo , A. Baur , C. A. Merlic , S. E. Brown

We examine the various instabilities of quarter-filled strongly correlated electronic chains in the presence of a coupling to the underlying lattice. To mimic the physics of the (TMTTF)$_2$X Bechgaard-Fabre salts we also include…

Strongly Correlated Electrons · Physics 2009-11-07 Jose Riera , Didier Poilblanc

High-resolution thermal expansion measurements have been performed for exploring the mysterious "structureless transition" in (TMTTF)$_{2}$X (X = PF$_{6}$ and AsF$_{6}$), where charge ordering at $T_{CO}$ coincides with the onset of…

Strongly Correlated Electrons · Physics 2008-11-24 M. de Souza , P. Foury-Leylekian , A. Moradpour , J. -P. Pouget , M. Lang

By applying measurements of the dielectric constants and relative length changes to the dimerized molecular conductor $\kappa$-(BEDT-TTF)$_2$Hg(SCN)$_2$Cl, we provide evidence for order-disorder type electronic ferroelectricity which is…

We study effects of an external magnetic field on charge ordering in the one-dimensional extended Hubbard model at quarter filling by means of the quantum Monte Carlo method. We find that the Zeeman coupling enhances the charge order…

Strongly Correlated Electrons · Physics 2014-08-08 Yuichi Otsuka , Hitoshi Seo , Yukitoshi Motome

The magnetic structure of antiferromagnetically ordered phases of quasi-one-dimensional organic conductors is studied theoretically at absolute zero based on the mean field approximation to the quarter-filled band with on-site and…

Strongly Correlated Electrons · Physics 2009-10-30 Hitoshi Seo , Hidetoshi Fukuyama

Low-dimensional organic conductors show a rich phase diagram, which has, despite all efforts, still some unexploed regions. Charge ordered phases present in many compounds of the (TMTTF)$_2 X$ family are typically studied with their unique…

Neutron diffraction measurements on multiferroic LuFe2O4 show changes in the antiferromagnetic (AFM) structure characterized by wavevector q = (1/3 1/3 1/2) as a function of electric field cooling procedures. The increase of intensity from…

Strongly Correlated Electrons · Physics 2011-11-09 A. M. Mulders , M. Bartkowiak , J. R. Hester , E. Pomjakushina , K. Conder

Motivated by the co-existing charge and spin order found in strongly correlated ladder systems, we study an effective pseudospin model on a coupled two-leg ladder. A bosonisation analysis yields a rich phase diagram showing Wigner/Peierls…

Strongly Correlated Electrons · Physics 2007-05-23 Siddhartha Lal , Mukul S. Laad

Based on Monte-Carlo simulations, the stable magnetization configurations of an antiferromagnet on a quasiperiodic tiling are derived theoretically. The exchange coupling is assumed to decrease exponentially with the distance between…

Disordered Systems and Neural Networks · Physics 2007-05-23 E. Y. Vedmedenko , U. Grimm , R. Wiesendanger

Electronic properties of molecular conductors exhibiting antiferromagnetic (AFM) spin order and charge order (CO) owing to electron correlation are studied using first-principles density functional theory calculations. We investigate two…

Strongly Correlated Electrons · Physics 2024-11-21 Takao Tsumuraya , Tsuyoshi Miyazaki , Hitoshi Seo
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