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A major challenge in the molecular simulation of electric double layer capacitors (EDLCs) is the choice of an appropriate model for the electrode. Typically, in such simulations the electrode surface is modeled using a uniform fixed charge…

Computational Physics · Physics 2015-06-22 Zhenxing Wang , Yang Yang , David L. Olmsted , Mark Asta , Brian B. Laird

We formulate and implement Cyclic Density Functional Theory (Cyclic DFT) -- a self-consistent first principles simulation method for nanostructures with cyclic symmetries. Using arguments based on Group Representation Theory, we rigorously…

Materials Science · Physics 2017-03-16 Amartya S. Banerjee , Phanish Suryanarayana

We investigate the two-dimensional Hubbard model using a real-frequency implementation of the TPSC+DMFT approach. This hybrid method combines the nonlocal correlations captured by the Two-Particle Self-Consistent (TPSC) approach with the…

Strongly Correlated Electrons · Physics 2025-04-01 Lei Geng , Jiawei Yan , Philipp Werner

A global hybrid extension of variational two-electron reduced-density matrix (v2RDM)-driven multiconfiguration pair-density functional theory (MCPDFT) is developed. Using a linear decomposition of the electron-electron repulsion term, a…

Chemical Physics · Physics 2019-11-27 Mohammad Mostafanejad , Marcus Dante Liebenthal , A. Eugene DePrince

An investigation is presented of the utility of semiclassical approximations for solving the quantum-impurity problems arising in the dynamical-mean-field approach to the correlated-electron models. The method is based on performing a exact…

Strongly Correlated Electrons · Physics 2009-11-11 Satoshi Okamoto , Andreas Fuhrmann , Armin Comanac , Andrew J. Millis

Hybrid density functional theory (DFT) remains intractable for large periodic systems due to the demanding computational cost of exact exchange. We apply the tensor hypercontraction (THC) (or interpolative separable density fitting)…

Computational Physics · Physics 2023-10-13 Adam Rettig , Joonho Lee , Martin Head-Gordon

The interface electronic structure of correlated LaTiO$_3$/SrTiO$_3$ superlattices is investigated by means of the charge self-consistent combination of the local density approximation (LDA) to density functional theory (DFT) with dynamical…

Strongly Correlated Electrons · Physics 2013-06-07 Frank Lechermann , Lewin Boehnke , Daniel Grieger

The band calculation scheme for $f$ electron compounds is developed on the basis of the dynamical mean field theory (DMFT) and the LMTO method. The auxiliary impurity problem is solved by a method named as NCA$f^{2}$v', which includes the…

Strongly Correlated Electrons · Physics 2009-11-11 O. Sakai , Y. Shimizu , Y. Kaneta

Current-spin density functional theory (CSDFT) provides a framework to describe interacting many-electron systems in a magnetic field which couples to both spin- and orbital-degrees of freedom. Unlike in usual (spin-) density functional…

Materials Science · Physics 2015-06-25 S. Pittalis , S. Kurth , N. Helbig , E. K. U. Gross

We present a lattice formulation of a dynamic self-consistent field (DSCF) theory that is capable of resolving interfacial structure, dynamics and rheology in inhomogeneous, compressible melts and blends of unentangled homopolymer chains.…

Soft Condensed Matter · Physics 2009-11-10 Maja Mihajlovic , Tak Shing Lo , Yitzhak Shnidman

The combination of density functional theory with dynamical mean-field theory (DFT+DMFT) has become a powerful first-principles approach to tackle strongly correlated materials in condensed matter physics. The wide use of this approach…

Strongly Correlated Electrons · Physics 2022-05-10 Xin Qu , Peng Xu , Rusong Li , Gang Li , Lixin He , Xinguo Ren

Using a combined local density functional theory (LDA-DFT) and quantum Monte Carlo (QMC) dynamic cluster approximation approach, the parameter dependence of the superconducting transition temperature Tc of several single-layer hole-doped…

The solution of the mean spherical approximation (MSA) integral equation for isotropic multicomponent dipolar hard sphere fluids without external fields is used to construct a density functional theory (DFT), which includes external fields,…

Statistical Mechanics · Physics 2015-05-28 I. Szalai , S. Dietrich

We present a new charge self-consistent scheme combining Density Functional and Dynamical Mean Field Theory, which uses Green's function of multiple scattering-type. In this implementation the many-body effects are incorporated into the…

Strongly Correlated Electrons · Physics 2017-10-11 A. Östlin , L. Vitos , L. Chioncel

LDA+DMFT is a novel computational technique for ab initio investigations of real materials with strongly correlated electrons, such as transition metals and their oxides. It combines the strength of conventional band structure theory in the…

Strongly Correlated Electrons · Physics 2007-05-23 K. Held , I. A. Nekrasov , G. Keller , V. Eyert , N. Blümer , A. K. McMahan , R. T. Scalettar , T. Pruschke , V. I. Anisimov , D. Vollhardt

We review the basic ideas of the dynamical mean field theory (DMFT) and some of the insights into the electronic structure of strongly correlated electrons obtained by this method in the context of model Hamiltonians. We then discuss the…

Strongly Correlated Electrons · Physics 2007-05-23 G. Kotliar , S. Y. Savrasov

Local density approximation (LDA) to the density functional theory (DFT) has continuous derivative of total energy as a number of electrons function and continuous exchange-correlation potential, while in exact DFT both should be…

Strongly Correlated Electrons · Physics 2010-06-28 V. I. Anisimov , A. V. Kozhevnikov , M. A. Korotin , A. V. Lukoyanov , D. A. Khafizullin

The accurate resolution of the chemical properties of strongly correlated systems, such as biradicals, requires the use of electronic structure theories that account for both multi-reference as well as dynamic correlation effects. A variety…

Chemical Physics · Physics 2023-01-03 Jan-Niklas Boyn , David A. Mazziotti

We develop a self-consistent theory describing the spin and spatial electron diffusion in the impurity band of doped semiconductors under the effect of a weak spin-orbit coupling. The resulting low-temperature spin-relaxation time and…

Disordered Systems and Neural Networks · Physics 2016-11-02 Thomas Wellens , Rodolfo A. Jalabert

The dynamical mean-field theory (DMFT) combined with the fluctuation exchange (FLEX) method, namely FLEX+DMFT, is an approach for correlated electron systems to incorporate both local and non-local long-range correlations in a…

Superconductivity · Physics 2015-08-20 Motoharu Kitatani , Naoto Tsuji , Hideo Aoki